Review
Chemistry, Multidisciplinary
Miaomiao Jiang, Yuanyuan Ma, Junliang Chen, Wan Jiang, Jianping Yang
Summary: The exploration of electrode materials has a crucial impact on the development of lithium-ion batteries, with challenges in conductivity and volume change hindering commercial application. Carbon-matrix composite anodes have been identified as an effective strategy, with recent advances focusing on regulating carbon distribution. This review provides insights into future trends in carbon-matrix electrode design for LIBs.
Article
Chemistry, Physical
Qiuyan Li, Ran Yi, Yaobin Xu, Xia Cao, Chongmin Wang, Wu Xu, Ji-Guang Zhang
Summary: This study focuses on the design and failure analysis of a silicon (Si) anode for lithium-ion batteries (LIBs). The volumetric energy density of the Si anode depends heavily on factors such as Si/C loading, anode calendering density, first-cycle coulombic efficiency, and anode capacity density. Stable Si/C electrode structure is crucial for long-term cycling, and the degree of prelithiation needs to be balanced with cycle life.
JOURNAL OF POWER SOURCES
(2022)
Article
Materials Science, Multidisciplinary
Juntao Du, Jiangkai Ma, Zetao Liu, Wenchao Wang, Huina Jia, Minxin Zhang, Yi Nie
Summary: Efficient management of the carbon structure is achieved in silicon/carbon anodes for lithium-ion batteries through the unique arrangement of the turbostratic carbon layer texture in the Si@MCMB composite. This arrangement provides space for silicon volume expansion, ion/electron diffusion channels, and mechanical strength, resulting in good cycle life and rate capability.
Article
Chemistry, Physical
Penghu Niu, Yu Zhou, Zhonghua Li, Yuyang Xiao, Mingru Su, Shuai Zhou, Xiaochuan Hou, Yunjian Liu
Summary: A coralline-like Si/Ni/C anode material was proposed by utilizing a metal-organic framework as the metal and carbon source. The in situ formed interlayer of NiSi2 at the interface of the carbon skeleton and Si nanoparticles improved the compatibility and gradient interface between them. The composite demonstrated excellent reversible capacity and rate capability due to the synergistic effects of stable structural integrity and good interface stability.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Multidisciplinary
Hao Tian, Huajun Tian, Wu Yang, Fan Zhang, Wang Yang, Qiaobao Zhang, Yong Wang, Jian Liu, S. Ravi P. Silva, Hao Liu, Guoxiu Wang
Summary: Silicon suboxide has shown potential as an anode material for high-energy-density lithium-ion batteries, but issues with electronic conductivity and Coulombic efficiency have hindered its practical application. By designing hollow-structured SiOx@CNTs/C architectures, these issues have been successfully addressed, paving the way for developing high-energy-density LIBs based on SiOx.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Review
Chemistry, Multidisciplinary
Md Mokhlesur Rahman, Irin Sultana, Ye Fan, Baozhi Yu, Tao Tao, Chunping Hou, Ying Chen
Summary: This review article summarizes battery research based on a wide range of nanomaterials over the last decade, highlighting strategies to tackle problems associated with electrode materials and approaches for improving electrochemical performance. Discussions on various design and synthesis strategies for high performance rechargeable batteries are included, with suggestions for future research directions.
MATERIALS CHEMISTRY FRONTIERS
(2021)
Article
Electrochemistry
Xiaohua Huang, Renqing Guo, Yan Lin, Yiqi Cao, Jianbo Wu
Summary: Si/SiC/C in-situ composite microspindles were fabricated using Zn2SiO4/C nanowire bundles obtained from hydrothermal synthesis and magnesiothermic reduction. SiC and C components were uniformly distributed at the nanoscale level within the microspindle particle, strengthening the structure. As an anode material for lithium-ion batteries, the Si/SiC/C composite microspindles exhibited excellent cyclic and rate performances, outperforming pure Si microspindles.
ELECTROCHIMICA ACTA
(2022)
Article
Chemistry, Physical
Haofeng Shi, Wenyuan Zhang, Jiashuai Wang, Donghua Wang, Chengdeng Wang, Zhihao Xiong, Jun Wu, Zhiming Bai, Xiaoqin Yan
Summary: The authors synthesized a copper-doped silicon/carbon porous composite, which significantly improved the electronic conductivity of the material. By adjusting the copper content, the initial coulombic efficiency was greatly increased. The optimized anode exhibited excellent rate capability and cycle stability, indicating its potential for commercial application.
APPLIED SURFACE SCIENCE
(2023)
Article
Chemistry, Physical
Jian Yu, Chaoran Zhang, Weidong Wu, Yuankun Cai, Yafei Zhang
Summary: Silicon has garnered attention for its high specific capacity and abundant reserves, but its volumetric changes during charging and discharging processes have hindered industrial utilization. This study introduces a novel hybrid anode material, Si@void/CNF, designed with a nodes-connected structure that provides both a conductive reticulation for silicon nanoparticles and addresses volume variation. By adjusting the mass ratio of silicon to PMMA, an optimal structure was achieved, demonstrating excellent electrochemical performance with high specific capacity and cycling stability. The electrospun structure of nodes-connected Si@void/CNF offers a promising method for fabricating advanced silicon-based anode materials.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Physical
Xiao Bai, Hui Zhang, Junpin Lin
Summary: This study explores the use of conducting polymers as both a conductive agent and binder in silicon anodes. By utilizing polyaniline (PANI) as a three-dimensional bridge, it is possible to maintain constant electric connectivity with silicon, even during long-term cycling. The research also demonstrates the improvement of Li-ion diffusion kinetics and cycling properties through low-temperature sintering of double-protected silicon nanoparticles (SiNPs) without damaging the PANI conductive skeleton. The novel composite material, Si@C/PANI-CNT, exhibits excellent discharge capacity and stability over multiple cycles.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Materials Science, Ceramics
Puhua Ouyang, Chenxin Jin, Guojun Xu, Xixi Yang, Kaijie Kong, Bobo Liu, Jianglei Dan, Jun Chen, Zhihao Yue, Xiaomin Li, Fugen Sun, Xilian Sun, Lang Zhou
Summary: The SiOx/Ag/C composite material was synthesized with improved electronic conductivity and lithium ion diffusion coefficient by using Ag nanoparticles and a carbon layer, inhibiting volume expansion. It exhibits excellent cycling performance and higher capacity compared to other materials.
CERAMICS INTERNATIONAL
(2021)
Review
Chemistry, Multidisciplinary
Alireza Fereydooni, Chenghao Yue, Yimin Chao
Summary: This review provides a brief history of Si-NPs' usage in LIBs and discusses strategies employed to overcome their drawbacks, aiming to inspire and offer valuable insights for future research endeavors.
Article
Nanoscience & Nanotechnology
Xu Liu, Huitian Liu, Yuhao Cao, Xiaochen Wu, Zhongqiang Shan
Summary: Chemical-expanded graphite (CEG) is used as a carbon matrix to form Si@CEG/C composites with an embedded structure, effectively addressing the challenges posed by volume change and electrochemical interface of Si anode. The embedded structure enables better cycling performance and rate capability for Si@CEG/C.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Energy & Fuels
Zhenwei Li, Meisheng Han, Peilun Yu, Quan Wu, Yuanbo Zhang, Jie Yu
Summary: Si/C anode with homogeneously deposited Si-C nanolayers on graphite armored with N-doped porous flexible vertical graphene sheets (VGSs) exhibits improved cycling stability and fast-charging capability. Si-C nanolayers contain sub-nanometer Si particles in 3D carbon skeleton, effectively alleviating volume change of Si and accelerating electron and Li-ion transport. N-doped VGSs provide rational space for Si volume change, buffer stress, increase electrical contact points, and accelerate Li-ion transport.
JOURNAL OF ENERGY STORAGE
(2023)
Article
Chemistry, Physical
Changsheng Song, Baoxun Zhao, Siyu Chen, Jinyang Ma, Hongbin Du
Summary: A new method for preparing silicon-nickel-carbon composites with high mechanical strength and ion diffusivity has been developed, improving the performance of lithium-ion batteries. The composites show stable performance during long-term cycling and exhibit better capacity retention compared to conventional materials.