期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 8, 期 39, 页码 14985-14995出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.0c05265
关键词
lead-free; niobite-based; dielectric properties; ultrahigh energy storage; pulsed charge-discharge
资金
- Natural Science Foundation of China [11664008, 61761015]
- Natural Science Foundation of Guangxi [2018GXNSFFA050001, 2017GXNSFDA198027, 2017GXNSFFA198011]
- Innovation Project of Guangxi Graduate Education [YCSW2020166]
- High Level Innovation Team and Outstanding Scholar Program of Guangxi Institutes
Lead-free ceramic capacitors are widely applied for novel pulse power supply systems owing to their environmental friendliness, high power density, and fast charge-discharge characteristics. Nevertheless, the simultaneous achievement of a higher recoverable energy storage density (W-rec) and efficiency (eta) is still challenging and must be investigated. To obtain a dielectric capacitor with a high W-rec and eta, the energy storage characteristics can be improved by reducing the residual polarization and increasing the breakdown strength. In this work, the doping modification of the NaNbO3 (NN) ceramics is used to produce a local random field to improve the electrical breakdown strength, obtaining a lead-free dielectric capacitor with high energy storage characteristics. According to this strategy, Bi(Ni0.67Ta0.33)O-3 is added to NN, and an ultrahigh Eb is obtained so that the ceramics have ideal W-rec and eta values. 0.85NN-0.15Bi(Ni0.67Ta0.33)O-3 has a very high W-rec (5.53 J cm(-3)) and eta (82.0%) at 575 kV cm(-1). Furthermore, the energy storage characteristics of the ceramics exhibit good thermal stability and frequency stability that are superior to those of most of the lead-free dielectric capacitors reported to date. In particular, the 0.85NN-0.15 Bi0.5Na0.5TiO3 (0.85NN-0.15BNT) ceramic also allows an ultrafast discharge time (t(0.9) = 27.5 ns), large current density (C-D = 506.42 A cm(-2)), and higher power density (P-D = 35.45 mW cm(-3)). These results indicate that (1- x)NN-xBNT ceramics are promising for applications in lead-free dielectric ceramic capacitors with a high energy storage density and conversion efficiency.
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