4.8 Article

Correlation between the static and dynamic responses of organic single-crystal field-effect transistors

期刊

NATURE COMMUNICATIONS
卷 11, 期 1, 页码 -

出版社

NATURE PORTFOLIO
DOI: 10.1038/s41467-020-18616-0

关键词

-

资金

  1. PRESTO-JST Molecular Technology and Creation of New Functions [JPMJPR13K5]
  2. JSPS KAKENHI [JP26105008, JP17H06123, JP17H06200, 20H00387]
  3. Grants-in-Aid for Scientific Research [20H00387] Funding Source: KAKEN

向作者/读者索取更多资源

Transistors, the most important logic elements, are maintained under dynamic influence during circuit operations. Practically, circuit design protocols and frequency responsibility should stem from a perfect agreement between the static and dynamic properties. However, despite remarkable improvements in mobility for organic semiconductors, the correlation between the device performances achieved under static and dynamic circumstances is controversial. Particularly in the case of organic semiconductors, it remains unclear whether parasitic elements that relate to their unique molecular aggregates may violate the radiofrequency circuit model. Thus, we herein report the manufacture of micrometre-scale transistor arrays composed of solution-processed organic semiconductors, which achieve near very high-frequency band operations. Systematic investigations into the device geometrical factors revealed that the radiofrequency circuit model established on a solid-state continuous medium is extendable to organic single-crystal field-effect transistors. The validity of this radiofrequency circuit model allows a reliable prediction of the performances of organic radiofrequency devices. Though literature reports improvements in organic electronic device performance, understanding the correlation between static and dynamic device responses remains a challenge. Here, the authors correlate static and dynamic parameters in organic transistors by using the radiofrequency circuit model.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.8
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Multidisciplinary

Surface Doping of Organic Single-Crystal Semiconductors to Produce Strain-Sensitive Conductive Nanosheets

Shun Watanabe, Ryohei Hakamatani, Keita Yaegashi, Yu Yamashita, Han Nozawa, Mari Sasaki, Shohei Kumagai, Toshihiro Okamoto, Cindy G. Tang, Lay-Lay Chua, Peter K. H. Ho, Jun Takeya

Summary: A highly periodic electrostatic potential is crucial for coherent band electron systems in van der Waals bonded organic crystals. Impurity doping faces difficulties in molecular crystals due to the destruction of ordered molecular frameworks, but a versatile strategy allows for the creation of coherent 2D electronic carriers at the surface of organic semiconductor crystals while preserving precise molecular structures. By forming redox-active molecular dopants on a molecularly flat crystalline surface through a simple solution process, efficient chemical doping and high carrier density can be achieved at room temperature, resulting in excellent carrier transport properties and piezoresistive effects similar to those in bulk crystals.

ADVANCED SCIENCE (2021)

Article Chemistry, Physical

Role of Perfluorophenyl Group in the Side Chain of Small-Molecule n-Type Organic Semiconductors in Stress Stability of Single-Crystal Transistors

Shohei Kumagai, Craig P. Yu, Shunsuke Nakano, Tatsuro Annaka, Masato Mitani, Masafumi Yano, Hiroyuki Ishii, Jun Takeya, Toshihiro Okamoto

Summary: The operational stability of organic thin-film transistors (OTFTs) is crucial, and by replacing phenyl with perfluorophenyl groups, especially bias stress stability can be greatly enhanced in n-channel single-crystal OTFTs.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2021)

Article Chemistry, Multidisciplinary

Electronic excitation spectra of organic semiconductor/ionic liquid interface by electrochemical attenuated total reflectance spectroscopy

Ichiro Tanabe, Iroha Imoto, Daijiro Okaue, Masaya Imai, Shohei Kumagai, Tatsuyuki Makita, Masato Mitani, Toshihiro Okamoto, Jun Takeya, Ken-ichi Fukui

Summary: This study introduces a novel spectroscopic setup (EC-ATR-UV) to investigate the spectral properties of ionic liquid/organic films interfaces under an electric field. By analyzing the interfacial area, the researchers were able to correlate the spectral changes of organic semiconductors with gate voltage application and IL species, providing insights for electrochemical device development. Additionally, the study detected Stark shifts in both the organic semiconductor and IL on the organic semiconductor films, offering a new method that can be applied to other electrochemical devices such as organic thin film solar cells.

COMMUNICATIONS CHEMISTRY (2021)

Review Chemistry, Multidisciplinary

Nitrogen-Containing Perylene Diimides: Molecular Design, Robust Aggregated Structures, and Advances in n-Type Organic Semiconductors

Shohei Kumagai, Hiroyuki Ishii, Go Watanabe, Craig P. Yu, Shun Watanabe, Jun Takeya, Toshihiro Okamoto

Summary: Organic semiconductors (OSCs) have potential applications in flexible and printed electronic devices, but the practical use of Organic thin-film transistors (OTFTs) is limited by lower carrier mobilities. N-type OSCs lag behind p-type OSCs in carrier mobility due to difficulties in achieving compatibility between aggregated structures and electron affinity. Rational molecular design principles are still needed for high-end device applications.

ACCOUNTS OF CHEMICAL RESEARCH (2022)

Article Chemistry, Multidisciplinary

Strong and Atmospherically Stable Dicationic Oxidative Dopant

Tadanori Kurosawa, Toshihiro Okamoto, Yu Yamashita, Shohei Kumagai, Shun Watanabe, Jun Takeya

Summary: This study demonstrates a new strong and atmospherically stable p-dopant for semiconducting polymers, TAB-2TFSI, which can achieve high electrical conductivity and enhanced crystallinity. The concept of utilizing charged molecules as dopants is highly versatile and may accelerate the development of strong and stable dopants.

ADVANCED SCIENCE (2021)

Article Chemistry, Multidisciplinary

Approaching isotropic charge transport of n-type organic semiconductors with bulky substituents

Craig P. Yu, Naoya Kojima, Shohei Kumagai, Tadanori Kurosawa, Hiroyuki Ishii, Go Watanabe, Jun Takeya, Toshihiro Okamoto

Summary: By synthesizing BQQDI derivatives with different substituents, the researchers demonstrated distinct molecular assemblies and charge-transport capabilities for these two organic semiconductors.

COMMUNICATIONS CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Regioselective Functionalization of Nitrogen-Embedded Perylene Diimides for High-Performance Organic Electron-Transporting Materials

Shohei Kumagai, Takeru Koguma, Tatsuro Annaka, Chizuru Sawabe, Yukio Tani, Hiroki Sugiura, Tetsuya Watanabe, Daisuke Hashizume, Jun Takeya, Toshihiro Okamoto

Summary: Functionalization of pi-conjugated compounds is an important strategy for developing high-performance organic optoelectronic materials. In this study, the regioselective dibromination of a nitrogen-embedded perylene diimide analogue was achieved through palladium(II)-catalyzed oxidation and dicyanation. The resulting compound exhibited a deep lowest-unoccupied molecular orbital and good redox stability, leading to high electron mobility in transistors.

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN (2022)

Article Chemistry, Physical

Naphthobispyrazine Bisimide: A Strong Acceptor Unit for Conjugated Polymers Enabling Highly Coplanar Backbone, Short π - π Stacking, and High Electron Transport

Tsubasa Mikie, Kenta Okamoto, Yuka Iwasaki, Tomoyuki Koganezawa, Masatomo Sumiya, Toshihiro Okamoto, Itaru Osaka

Summary: This study developed and synthesized a novel acceptor unit for conjugated polymers. The resulting polymer showed significantly improved electron and hole mobilities compared to its predecessor, likely due to the highly coplanar and rigid backbone. Furthermore, the incorporation of fluorine atoms as conformation-directing groups resulted in higher solubility and regular backbone structure for the polymer.

CHEMISTRY OF MATERIALS (2022)

Article Chemistry, Multidisciplinary

Mixed-Orbital Charge Transport in N-Shaped Benzene- and Pyrazine-Fused Organic Semiconductors

Craig P. Yu, Shohei Kumagai, Tomokatsu Kushida, Masato Mitani, Chikahiko Mitsui, Hiroyuki Ishii, Jun Takeya, Toshihiro Okamoto

Summary: This study demonstrates the influence of occupied molecular orbitals on charge transport in high-performance organic semiconductors. A novel molecular design is introduced to induce more pronounced mixed-orbital charge transport, leading to a high hole mobility.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Article Nanoscience & Nanotechnology

π-Extended Zigzag-Shaped Diphenanthrene-Based p-Type Semiconductors Exhibiting Small Effective Masses

Masato Mitani, Shohei Kumagai, Craig P. Yu, Ayako Oi, Masakazu Yamagishi, Shuhei Nishinaga, Hiroki Mori, Yasushi Nishihara, Daisuke Hashizume, Tadanori Kurosawa, Hiroyuki Ishii, Nobuhiko Kobayashi, Jun Takeya, Toshihiro Okamoto

Summary: This study reported a new zigzag-shaped sulfur-bridged pi-electron core and its derivative, investigated their molecular design strategy and their impact on organic semiconductor performance through single-crystal structural analysis and band calculation.

ADVANCED ELECTRONIC MATERIALS (2022)

Article Chemistry, Multidisciplinary

Electron-Deficient Benzo[de]isoquinolino[1,8-gh]quinoline Diamide pi-Electron Systems

Craig P. Yu, Akito Yamamoto, Shohei Kumagai, Jun Takeya, Toshihiro Okamoto

Summary: In this work, a benzo[de]isoquinolino[1,8-gh]quinoline diamide (BQQDA) pi-electron system was reported. The use of an electron-rich condensed amide instead of the usually employed imide provided suitable electronic features for chemical versatility in tailoring the BQQDA pi-electron system. Chemical modifications allowed for selective functionalization of the bay positions of the pi-skeleton. Furthermore, thionation of BQQDA was achieved under mild conditions. The resulting cyanated BQQDA organic semiconductor exhibited a high air-stable electron-carrier mobility.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

Article Chemistry, Multidisciplinary

Untangling the Fundamental Electronic Origins of Non-Local Electron-Phonon Coupling in Organic Semiconductors

Peter A. A. Banks, Gabriele D'Avino, Guillaume Schweicher, Jeff Armstrong, Christian Ruzie, Jong Won Chung, Jeong-Il Park, Chizuru Sawabe, Toshihiro Okamoto, Jun Takeya, Henning Sirringhaus, Michael T. T. Ruggiero

Summary: A study demonstrates the mechanism of electron-phonon coupling and the impact of molecular design on organic semiconductor materials. It reveals the effects of less commonly studied molecular vibrations and provides insights for creating improved materials.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Chemistry, Physical

Individual and synergetic charge transport properties at the solid and electrolyte interfaces of a single ultrathin single crystal of organic semiconductors

Taehyun Won, Shohei Kumagai, Naotaka Kasuya, Yu Yamashita, Shun Watanabe, Toshihiro Okamoto, Jun Takeya

Summary: The chemical structures and morphologies of organic semiconductors (OSCs) and gate dielectrics were studied to improve the electrical performances of organic thin-film transistors (OTFTs). The charge transport properties at individual interfaces between the OSC surface and different gate dielectrics were investigated using solid and ionic gel gate dielectrics on the lower and upper surfaces of OSCs. The dual-gate transistor operation with solid/ionic gel gate exhibited improved hole mobility, attributed to the electric double layer formed at the ionic gel/uniform crystal surface.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2023)

Article Chemistry, Multidisciplinary

Crown ether salt-doped ladder-type conducting polymers for air-stable n-type thermoelectric materials

Ryoto Yura, Shohei Kumagai, Kiyohiro Adachi, Daisuke Hashizume, Toshihiro Okamoto, Yoshiyuki Nonoguchi

Summary: This study demonstrates that supramolecular salt-functionalized n-doped ladder-type conducting polymers exhibit excellent stability in the presence of dry air.

CHEMICAL COMMUNICATIONS (2023)

Article Materials Science, Multidisciplinary

Supramolecular cocrystals built through redox-triggered ion intercalation in π-conjugated polymers

Yu Yamashita, Junto Tsurumi, Tadanori Kurosawa, Kan Ueji, Yukina Tsuneda, Shinya Kohno, Hideto Kempe, Shohei Kumagai, Toshihiro Okamoto, Jun Takeya, Shun Watanabe

Summary: Molecular doping of pi-conjugated semiconducting polymers can increase charge carrier density by forming intercalated compounds composed of layered polymers and guest intercalants. The multi-layer stacked nature of semicrystalline polymers allows the inclusion of various functional molecules. Intercalation cocrystal nature gives the best achievable doping level in semicrystalline polymers and excellent environmental stability.

COMMUNICATIONS MATERIALS (2021)

暂无数据