4.4 Article

Response surface methodology modeling for methylene blue removal by chemically modified porous carbon: Adsorption mechanism and role of surface functional groups

期刊

SEPARATION SCIENCE AND TECHNOLOGY
卷 56, 期 13, 页码 2232-2242

出版社

TAYLOR & FRANCIS INC
DOI: 10.1080/01496395.2020.1820523

关键词

Methylene blue; modified porous carbon; response surface methodology; functional groups; adsorption mechanism

资金

  1. Foundation for Science and Technology Development Nguyen Tat Thanh University [2020.01.149/HD-KHCN]

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This study utilized chemically modified porous carbon as a robust adsorbent for methylene blue treatment, achieving high removal efficiency and adsorption capacity under optimized conditions. The role of surface functional groups in the adsorption mechanism was elaborately explained in the research.
The present study utilized chemically modified porous carbon (CMPC) as a robust adsorbent for MB treatment. The characteristic findings revealed the existence of many functional groups (C-O/C = O, C-C/C = C, C-OH, - COOH, C-C = O, etc.) on the surface of the high-defect structure of CMPC. Additionally, influential factors: methylene blue (MB) concentration (116-284 mg/L), CMPC dosage (0.16-1.84 g/L), and pH (3.6-10.4) were assessed by response surface methodology. By applying optimized conditions, the highest MB removal and adsorption capacity were confirmed at 90% and 181.82 mg/g, respectively. Role of surface functional groups in adsorption mechanisms was meticulously explained.

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