Article
Chemistry, Physical
Jing Guo, Shi-Yong Zhang, Cheng-Hui Zeng, Zhong-Gao Zhou, Miao Xie, Zi-Yi Du, Chun-Ting He, Wei-Xiong Zhang, Xiao-Ming Chen
Summary: Free accessible confined space and loose interaction can be achieved in an ionic crystal (HMIm)(3)[La(NO3)(6)], which is composed of near-spherical anions and disc-shaped ammonium cations. The confined space of (HMIm)(+) ions can be finely tuned over a broad temperature range, allowing modulation of dipolar polarization. Small-scale substitution of (HMIm)(+) ions and fine-tuning of doping ratio in the molecular solid solutions further regulate the dipole motion in the crystalline environment.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2023)
Article
Chemistry, Inorganic & Nuclear
Saul H. Lapidus, Peter W. Stephens, Maria Fumanal, Jordi Ribas-Arino, Juan J. Novoa, Jack G. DaSilva, Arnold L. Rheingold, Joel S. Miller
Summary: The genesis of magnetic behaviors for different polymorphs of [FeCp*(2)][TCNQ] was identified through determination of low temperature structures using high-resolution synchrotron powder diffraction data. Analysis revealed that the polymorphs do not thermally interconvert, and structural differences between them were characterized. Computational analysis of spin couplings indicated strong intrachain magnetic interactions, with changes leading to different magnetic ground states.
DALTON TRANSACTIONS
(2021)
Article
Multidisciplinary Sciences
Yuki Hagiwara, Shodai Hasebe, Hiroki Fujisawa, Junko Morikawa, Toru Asahi, Hideko Koshima
Summary: This paper reports the high-speed bending of anisole crystals using natural vibration induced by the photothermal effect. The bending behavior is greatly amplified through resonance to achieve high frequency, large bending, and high energy conversion efficiency. Any light-absorbing crystal can be actuated by the photothermally induced natural vibration. This versatile crystal actuation method can contribute to the development of soft robots with high-speed and high-efficiency actuation capabilities.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Jun-Chao Liu, Yong Ai, Qin Liu, Yi-Piao Zeng, Xiao-Gang Chen, Hui-Peng Lv, Ren-Gen Xiong, Wei-Qiang Liao
Summary: This article presents a solid-liquid crystal biphasic ferroelectric material, cholestanyl 4-X-benzoate (4X-CB, X = Cl, Br, and I), that exhibits biferroelectricity in both the solid and liquid crystal phases. The liquid crystal phase of 4X-CB is identified as a cholesteric phase with a helical structure, different from the ordinary chiral smectic ferroelectric liquid crystal phase. Furthermore, the spontaneous polarization of 4X-CB in both phases can be regulated by different halogen substitutions. It is suggested that 4X-CB is the first ferroelectric material with tunable biferroelectricity, providing a feasible case for the performance optimization of solid-liquid crystal biphasic ferroelectrics.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Yuan-Yuan Tang, Jun-Chao Liu, Yu-Ling Zeng, Hang Peng, Xue-Qin Huang, Meng-Juan Yang, Ren-Gen Xiong
Summary: The successful synthesis of an organic photochromic ferroelectric material capable of reversible switching of dielectric permittivity and spontaneous polarization through photoinduced structural phase transition opens up possibilities for photocontrolled smart materials and biomechanical applications in the future.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Multidisciplinary
Guo-Hao Ni, Ying-Xi Sun, Cui-Xian Ji, Ya-Wei Jin, Meng-Yuan Liu, Jiong-Peng Zhao, Fu-Chen Liu
Summary: This article presents a new molecular ionic complex composed of iron and pyrimidinium ions, which exhibits reversible plasticity and ferroelasticity transition near room temperature.
CRYSTAL GROWTH & DESIGN
(2022)
Article
Chemistry, Multidisciplinary
Magdalena Rok, Marcin Moskwa, Joanna Hetmanczyk, Lukasz Hetmanczyk, Grazyna Bator
Summary: We have synthesized and characterized two new organic-inorganic hybrid crystals: AZECr and AZEFe. Thermal analysis results indicate that both compounds undergo a structural phase transition during cooling. Crystal structure analysis shows that AZECr and AZEFe are isomorphous in the high-temperature phase, but differ in the low-temperature phase. Infrared spectroscopy and dielectric measurements confirm the existence of this transition.
Article
Chemistry, Multidisciplinary
Tomohiro Seki, Daiki Korenaga
Summary: A chloroplatinum complex was arylated to obtain stimuli-responsive molecular crystals that showed polymorph-dependent emission, mechano- and thermochromic luminescence, as well as comproportionation and π-bridged dimerization. Simple mixing of structurally similar arylplatinum complexes at room temperature resulted in the transfer of their aryl groups (comproportionation), allowing the tuning of their mechanochromic profiles. Recrystallization of the complex resulted in a dimerized product with a very short Pt-Pt distance bridged by aryl groups.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Norihisa Hoshino, Tomoyuki Akutagawa
Summary: The reduction in thermal conductivity and improvement in conversion efficiency of thermoelectric materials can be achieved by using vibrating or disordered counter ions. In this study, the effect of counter ions on the order-disorder transitions in thermal conductivity and thermoelectric figure of merit was investigated. The results showed that salts with order-disorder transitions displayed significantly lower thermal conductivities compared to salts without any transitions. Additionally, vibrating counter cations were found to improve the conversion efficiency.
CRYSTAL GROWTH & DESIGN
(2022)
Article
Chemistry, Multidisciplinary
Przemyslaw Szklarz, Vasyl Kinzhybalo, Grazyna Bator
Summary: This study investigates the temperature-dependent polar properties of the novel single-component molecular ferroelectric single crystal of 1,3,5-trimethylnitrobenzene (TMNB). Three solid-state phases of TMNB have been identified, with phase III exhibiting ferroelectricity along the c-axis. The origin of spontaneous polarization in this crystal is attributed to the flexibility of the C-H···π hydrogen bonds in the molecular joints. The phase transitions in TMNB are governed by the dynamics of the NO2 groups and the flexibility of the C-H···π dimer.
Article
Environmental Sciences
Shengjie Hu, Zhenlei Yang, Sergio Torres, Zipeng Wang, Ling Li
Summary: Power law size distribution is associated with fractal, self-organized behaviors in complex systems, including natural lakes. However, the driving mechanism for this distribution in lake systems is unclear. Based on observations and simulations, a conceptual model for lake systems in China was established, revealing the underlying driving mechanism and the three components of the lake size distribution.
WATER RESOURCES RESEARCH
(2023)
Article
Chemistry, Multidisciplinary
Haruka Kubo, Ryusei Oketani, Ichiro Hisaki
Summary: The quasi single-crystal-to-single-crystal transformation of a hydrogen-bonded organic framework (HOF) was accurately revealed in this study, with the proposed mechanism indicating the involvement of Br/π interaction. This interaction allowed for the successful resolution of the intermediate phase of the crystal structure.
CHEMICAL COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Hiroshi Matsui, Kakeru Fukuda, Saki Takano, Yuka Ikemoto, Takahiko Sasaki, Yasumitsu Matsuo
Summary: The difference in antiferro-electric ordering mechanisms below 50 and 168 K in Cs3H(SeO4)(2) and Cs3D(SeO4)(2) respectively was elucidated through measuring wide ranges of absorbance spectra. The presence of deuterons at 610 cm(-1) exhibited a significant isotope effect, indicating different dominations of deuteron and proton hopping in Cs3D(SeO4)(2) and Cs3H(SeO4)(2) respectively. The distinct ordering mechanism in Cs3D(SeO4)(2) is enhanced by the phonon-assisted deuteron hopping associated with 310 cm(-1) def(bend).
JOURNAL OF CHEMICAL PHYSICS
(2022)
Article
Chemistry, Inorganic & Nuclear
Hao-Fei Ni, Jia-He Lin, Chang-Feng Wang, Qing-Feng Luo, Pei-Zhi Huang, Zhi-Xu Zhang, Da-Wei Fu, Yi Zhang
Summary: This study achieves the coexistence of multiple ferroic ordering in (imidazolium)3PbBr5 by utilizing ingenious molecular orientation dynamics, offering instructive clues for designing multiple ferroic orderings in a single material.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Inorganic & Nuclear
Jun-Chao Liu, Fang-Fang Di, Yi-Piao Zeng, Wu-Jia Chen, Xiao-Yun Huang, Yan-Ling Luo, Xuan Zhu, Lin Zhou, Yuan-Yuan Tang
Summary: In this study, an above-room-temperature host-guest inclusion ferroelastic crystal was successfully designed and the phase transition temperature and type were effectively controlled by replacing the anion. The ferroelastic domains of this crystal can be switched under thermal stimulus as well as rapidly switched in situ under external stress, suggesting its potential in dual-channel switches.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Chemistry, Inorganic & Nuclear
Gabriella Bombieri, Roberto Artali, Sax A. Mason, Garry J. McIntyre, Armando Mortillaro, Silvio Aime
INORGANICA CHIMICA ACTA
(2018)
Article
Materials Science, Ceramics
Youshuang Yu, Guochu Deng, Yiming Cao, Garry J. McIntyre, Rubin Li, Ning Yuan, Zhenjie Feng, Jun-Yi Ge, Jincang Zhang, Shixun Cao
CERAMICS INTERNATIONAL
(2019)
Article
Physics, Condensed Matter
Guochu Deng, Youshuang Yu, Yiming Cao, Zhenjie Feng, Wei Ren, Shixun Cao, Andrew J. Studer, James R. Hester, Yousef Kareri, Clemens Ulrich, Garry J. McIntyre
JOURNAL OF PHYSICS-CONDENSED MATTER
(2019)
Article
Chemistry, Multidisciplinary
Teng Lu, Ye Tian, Andrew Studer, Narendirakumar Narayanan, Qian Li, Ray Withers, Li Jin, Y. Mendez-Gonzalez, A. Pelaiz-Barranco, Dehong Yu, Garry J. McIntyre, Zhuo Xu, Xiaoyong Wei, Haixue Yan, Yun Liu
Article
Chemistry, Multidisciplinary
Katharina Edkins, Garry J. McIntyre, Clive Wilkinson, Volker Kahlenberg, Daniel Toebbens, Ulrich J. Griesser, Juergen Bruening, Martin U. Schmidt, Jonathan W. Steed
CRYSTAL GROWTH & DESIGN
(2019)
Article
Instruments & Instrumentation
Guochu Deng, Garry J. McIntyre
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT
(2020)
Article
Materials Science, Multidisciplinary
N. Narayanan, Q. Lou, A. Rawal, T. Lu, Z. Liu, J. Chen, J. Langley, H. Chen, J. Hester, N. Cox, H. Fuess, G. J. McIntyre, G. Li, D. Yu, Y. Liu
PHYSICAL REVIEW MATERIALS
(2020)
Article
Chemistry, Multidisciplinary
Giulia Novelli, Charles J. McMonagle, Florian Kleemiss, Michael Probert, Horst Puschmann, Simon Grabowsky, Helen E. Maynard-Casely, Garry J. McIntyre, Simon Parsons
Summary: The crystal structure of the monoclinic polymorph of l-histidine has been determined for the first time using single-crystal neutron diffraction, while the orthorhombic polymorph has been reinvestigated to improve experimental precision and accuracy. The study reveals differences in hydrogen bond energy and geometry between the two polymorphs, with molecular packing interpreted by intermolecular interaction energies calculated using the Pixel method. The precision and accuracy of the new Hirshfeld atom refinement method implemented in NoSpherA2 were probed, showing good agreement with neutron structural models.
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Giulia Novelli, Konstantin Kamenev, Helen E. Maynard-Casely, Simon Parsons, Garry J. McIntyre
Summary: When studying a sample under high pressure, collecting single-crystal X-ray and neutron diffraction data using separate samples can lead to inconsistent pressure results. This study collected X-ray and neutron diffraction data on the same sample under the same conditions, and combined the two data sets for structure refinement, resulting in a 50% improvement in precision.
Editorial Material
Chemistry, Multidisciplinary
Louise N. Dawe, Juan Manuel Garcia-Ruiz, Janos Hadju, Garry J. McIntyre, Flora Meilleur, Lisa Stephenson
JOURNAL OF APPLIED CRYSTALLOGRAPHY
(2022)
Article
Materials Science, Multidisciplinary
C. B. Larsen, E. Canevet, D. G. Mazzone, Ch. Ruegg, B. Fak, D. F. McMorrow, E. Ressouche, G. J. McIntyre, S. L. Bud'ko, P. C. Canfield, O. Zaharko
Summary: The magnetic behavior of YbAgGe was studied, revealing multiple magnetic phase transitions, non-Fermi liquid states, and a possible quantum critical point. Different magnetic phases were observed under varying external magnetic fields, with structural refinements showing strong modulation of magnetic moment amplitudes. While the ordered moments are primarily aligned in the hexagonal plane, there is also a significant out-of-plane component and a ferromagnetic contribution above 2 T. Further research is needed to better understand the microscopic interactions in this material.
Article
Chemistry, Multidisciplinary
Yichen Liu, Jack Yang, Yang Liu, Jian Zheng, Wen Lee, Junjie Shi, Jonathan Horlyck, Jiangzhou Xie, Yee Yan Tay, Thiam Teck Tan, Dehong Yu, Richard Mole, Garry McIntyre, Changyong Zhang, Cui Ying Toe, T. David Waite, Jason Scott, Yu Wang, Tom Wu, Shenghao Han, Sean Li
ENERGY & ENVIRONMENTAL SCIENCE
(2020)
Article
Materials Science, Multidisciplinary
N. Narayanan, A. Senyshyn, D. Mikhailova, T. Faske, T. Lu, Z. Liu, B. Weise, H. Ehrenberg, R. A. Mole, W. D. Hutchison, H. Fuess, G. J. McIntyre, Y. Liu, D. Yu
Article
Materials Science, Multidisciplinary
Guochu Deng, Yiming Cao, Wei Ren, Shixun Cao, Andrew J. Studer, Nicolas Gauthier, Michel Kenzelmann, Gene Davidson, Kirrily C. Rule, Jason S. Gardner, Paolo Imperia, Clemens Ulrich, Garry J. McIntyre
Article
Materials Science, Multidisciplinary
Guochu Deng, Dehong Yu, Richard Mole, Ekaterina Pomjakushina, Kazimierz Conder, Michel Kenzelmann, Shin-ichiro Yano, Chin-Wei Wang, Kirrily C. Rule, Jason S. Gardner, Huiqian Luo, Shiliang Li, Clemens Ulrich, Paolo Imperia, Wei Ren, Shixun Cao, Garry J. McIntyre
Article
Chemistry, Multidisciplinary
Abu Talha Aqueel Ahmed, Sankar Sekar, Shubhangi S. Khadtare, Nurul Taufiqu Rochman, Bathula Chinna, Abu Saad Ansari
Summary: In this study, MnCo2S4 nanosheet catalyst was successfully synthesized and found to exhibit superior performance in hydrogen evolution. Compared to MnCo2S4, MnCo2S4 showed low overpotentials, moderate Tafel slope, and excellent sustainability. The outstanding performance can be attributed to the increased number of electrochemically active sites and enhanced electronic conductivity on the catalyst surface.
Article
Chemistry, Multidisciplinary
Victor V. Maltsev, Elena A. Volkova, Elizaveta V. Koporulina, Diana D. Mitina, Vladimir L. Kosorukov, Anna I. Jiliaeva, Daniil A. Naprasnikov, Konstantin N. Gorbachenya, Viktor E. Kisel
Summary: The phase relationships, crystal properties and luminescence kinetics of two complex systems were studied, including unit cell parameters, segregation coefficients of impurities, and lifetimes of energy levels.
Article
Chemistry, Multidisciplinary
Xiaoman Zhang, Wangwang Xu, W. J. Meng, Andrew C. Meng
Summary: This study successfully grew high-quality single crystal AlScN nanowires through ultra-high vacuum reactive sputtering technique and characterized their structure and properties. The nanowires exhibit significantly reduced mosaic spread and predominantly single ferroelectric domains, as well as a high piezoelectric constant.
Article
Chemistry, Multidisciplinary
Tom E. de Vries, Elias Vlieg, Rene de Gelder
Summary: Networks are important for describing relationships between people, roads between cities, reactions between chemicals, and other interactions. Bipartiteness, dividing the network into two groups, can facilitate the study of the network's structure. We have developed an algorithm that can find a near-optimal bipartisation within a reasonable time frame and used it to uncover the hidden structure of the CSD cocrystal network.
Article
Chemistry, Multidisciplinary
Chuchu Han, Jing Yang, Xin Zhang, Aisen Li, Jiang Peng
Summary: An elastic crystal based on a photo-reactive acylhydrazone derivative is reported, which exhibits reversible bending behavior under UV irradiation and heating. The crystal undergoes reversible E<->Z isomerization under light and heating conditions. The crystal demonstrates excellent elastic properties and the bending can be controlled to control the output direction of red light.
Article
Chemistry, Multidisciplinary
Lingfeng Zhang, Yu Wang, Yefeng Wang, Shuai Liu, Na Zhang, Mingmin Yang, Haixia Ma, Zhaoqi Guo
Summary: This study designs and synthesizes a series of high-energy salts compounds without heavy metal ions and azide groups. The molecular structures and stability of the compounds are confirmed through single-crystal X-ray diffraction and intermolecular interaction analysis. Furthermore, the thermal stability, energetic properties, and electrical initiation properties of the compounds are investigated, suggesting their potential as primary explosives.