Recent advances in nickel-catalyzed reductive hydroalkylation and hydroarylation of electronically unbiased alkenes

Nickel-Catalyzed Chain-Walking Cross-Electrophile Coupling of Alkyl and Aryl Halides and Olefin Hydroarylation Enabled by Electrochemical Reduction

(2020) Gadde Sathish Kumar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Convergent Catalytic Asymmetric Synthesis of Esters of Chiral Dialkyl Carbinols

(2020) Ze-Peng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A review of enantioselective dual transition metal/photoredox catalysis

(2020) Hong-Hao Zhang et al.   Science China-Chemistry

Responsive boron biomaterials and their biomedical applications

(2020) Weizhi Chen et al.   Science China-Chemistry

Combination of olefin insertion polymerization and olefin metathesis to extend the topology and composition of polyolefins

(2020) Tianwei Yan et al.   Science China-Chemistry

Enantioconvergent Cross−Couplings of Alkyl Electrophiles: The Catalytic Asymmetric Synthesis of Organosilanes

(2019) Gregory C Fu   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand controlled cobalt catalyzed regiodivergent 1,2-hydroboration of 1,3-dienes

(2019) Sihan Peng et al.   Science China-Chemistry

Rare-earth metal catalysts for alkene hydrosilylation

(2019) Deshuai Liu et al.   Science China-Chemistry

Photocatalytic decarboxylative alkylations mediated by triphenylphosphine and sodium iodide

(2019) Ming-Chen Fu et al.   SCIENCE

Harnessing Alkylpyridinium Salts as Electrophiles in Deaminative Alkyl–Alkyl Cross-Couplings

(2019) Shane Plunkett et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroalkylation of Olefins To Form Quaternary Carbons

(2019) Samantha A. Green et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Regioselective Hydroalkylation and Hydroarylation of Alkenyl Boronic Esters

(2019) Srikrishna Bera et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rapid Access to Highly Functionalized Alkyl Boronates by NiH-Catalyzed Remote Hydroarylation of Boron-Containing Alkenes

(2019) Yao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organotitanium Nucleophiles in Asymmetric Cross-Coupling Reaction: Stereoconvergent Synthesis of Chiral α-CF3 Thioethers

(2019) Andrii Varenikov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-catalyzed reductive coupling of glucosyl halides with aryl/vinyl halides enabling β-selective preparation of C-aryl/vinyl glucosides

(2019) Jiandong Liu et al.   Science China-Chemistry

Ni-catalyzed deaminative cross-electrophile coupling of Katritzky salts with halides via C─N bond activation

(2019) Shengyang Ni et al.   Science Advances

Tackling Remote sp 3 C−H Functionalization via Ni‐Catalyzed “chain‐walking” Reactions

(2019) Daniel Janssen‐Müller et al.   ISRAEL JOURNAL OF CHEMISTRY

Radical-mediated hydroalkylation of 2-vinylpyrrolidine derivatives: a versatile entry into indolizidine alkaloids

(2019) Sankar Rao Suravarapu et al.   Science China-Chemistry

Ligand-Controlled Regiodivergent Hydroalkylation of Pyrrolines

(2019) Deyun Qian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal‐Catalyzed Substrate‐Directed Enantioselective Functionalization of Unactivated Alkenes

(2019) Zi‐Xuan Wang et al.   CHINESE JOURNAL OF CHEMISTRY

Site-Selective Catalytic Deaminative Alkylation of Unactivated Olefins

(2019) Shang-Zheng Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photocatalytic decarboxylative coupling between α-oxocarboxylicacids and alkenes

(2019) Ziyue Chen et al.   Science China-Chemistry

Radical cascade reactions of unsaturated C-C bonds involving migration

(2019) Ge Zhang et al.   Science China-Chemistry

Difunctionalization of Alkenes Involving Metal Migration

(2019) Yuqiang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Electrochemical Reductive Relay Cross-Coupling of Alkyl Halides to Aryl Halides

(2019) Ke-Jin Jiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Enantioconvergent Reductive Hydroalkylation of Olefins with α-Heteroatom Phosphorus or Sulfur Alkyl Electrophiles

(2019) Shi-Jiang He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

NiH-Catalyzed Reductive Relay Hydroalkylation: A Strategy for the Remote C(sp3 )−H Alkylation of Alkenes

(2018) Fang Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Ni–Al Bimetallic Catalyzed exo-Selective C–H Cyclization of Imidazoles with Alkenes

(2018) Yin-Xia Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photochemical Nickel-Catalyzed Reductive Migratory Cross-Coupling of Alkyl Bromides with Aryl Bromides

(2018) Long Peng et al.   ORGANIC LETTERS

Terminal C(sp 3 ) H alkylation of internal alkenes via Ni/H-catalyzed isomerization

(2018) Zhen-Yu Wang et al.   TETRAHEDRON LETTERS

Walking Metals for Remote Functionalization

(2018) Heiko Sommer et al.   ACS Central Science

Iron–Nickel Dual-Catalysis: A New Engine for Olefin Functionalization and the Formation of Quaternary Centers

(2018) Samantha A. Green et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Interrogation of Co/Ni-Dual Catalyzed Hydroarylation

(2018) Sophia L. Shevick et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-Selective Ni-Catalyzed Reductive Coupling of α-Haloboranes with Unactivated Olefins

(2018) Shang-Zheng Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in Ni−Al bimetallic catalysis for unreactive bond transformation

(2018) Yin-Xia Wang et al.   Science China-Chemistry

Base-catalyzed diborylation of alkynes: synthesis and applications of cis-1,2-bis(boryl)alkenes

(2018) Zhijie Kuang et al.   Science China-Chemistry

The High Chemofidelity of Metal-Catalyzed Hydrogen Atom Transfer

(2018) Samantha A. Green et al.   ACCOUNTS OF CHEMICAL RESEARCH

NiH-Catalyzed Remote Asymmetric Hydroalkylation of Alkenes with Racemic α-Bromo Amides

(2018) Fang Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic enantioconvergent coupling of secondary and tertiary electrophiles with olefins

(2018) Zhaobin Wang et al.   NATURE

Remote Migratory Cross-Electrophile Coupling and Olefin Hydroarylation Reactions Enabled by in Situ Generation of NiH

(2017) Fenglin Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mild and Regioselective Benzylic C–H Functionalization: Ni-Catalyzed Reductive Arylation of Remote and Proximal Olefins

(2017) Yuli He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Harnessing Alkyl Amines as Electrophiles for Nickel-Catalyzed Cross Couplings via C–N Bond Activation

(2017) Corey H. Basch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition metal–catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry

(2017) Junwon Choi et al.   SCIENCE

Ligand-Controlled Nickel-Catalyzed Reductive Relay Cross-Coupling of Alkyl Bromides and Aryl Bromides

(2017) Long Peng et al.   ACS Catalysis

Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes

(2017) Gregory C. Fu   ACS Central Science

Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins

(2016) Steven W. M. Crossley et al.   CHEMICAL REVIEWS

Markovnikov free radical addition reactions, a sleeping beauty kissed to life

(2016) Reinhard W. Hoffmann   CHEMICAL SOCIETY REVIEWS

Formation of C(sp3 )-C(sp3 ) Bonds through Nickel-Catalyzed Decarboxylative Olefin Hydroalkylation Reactions

(2016) Xi Lu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Practical Ni-Catalyzed Aryl–Alkyl Cross-Coupling of Secondary Redox-Active Esters

(2016) Josep Cornella et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Decarboxylative Arylation of α-Amino Acids via the Merger of Photoredox and Nickel Catalysis

(2016) Zhiwei Zuo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarboxylative Cross-Electrophile Coupling of N-Hydroxyphthalimide Esters with Aryl Iodides

(2016) Kierra M. M. Huihui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Branch-Selective Hydroarylation: Iodoarene–Olefin Cross-Coupling

(2016) Samantha A. Green et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic, Regioselective Hydrocarbofunctionalization of Unactivated Alkenes with Diverse C–H Nucleophiles

(2016) Kin S. Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A general, modular method for the catalytic asymmetric synthesis of alkylboronate esters

(2016) J. Schmidt et al.   SCIENCE

A general alkyl-alkyl cross-coupling enabled by redox-active esters and alkylzinc reagents

(2016) T. Qin et al.   SCIENCE

Practical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation

(2016) Xi Lu et al.   Nature Communications

Nickel-Catalyzed Reductive Couplings

(2016) Xuan Wang et al.   Topics in Current Chemistry

Ni-Catalyzed C–C Couplings Using Alkyl Electrophiles

(2016) Takanori Iwasaki et al.   Topics in Current Chemistry

Methods and Mechanisms for Cross-Electrophile Coupling of Csp2 Halides with Alkyl Electrophiles

(2015) Daniel J. Weix   ACCOUNTS OF CHEMICAL RESEARCH

Fascinating Hydrogen Atom Transfer Chemistry of Alkenes Inspired by Problems in Total Synthesis

(2015) Antoine Simonneau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand-Controlled Regiodivergent Copper-Catalyzed Alkylboration of Alkenes

(2015) Wei Su et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective, Asymmetric Formal Hydroamination of Unactivated Internal Alkenes

(2015) Yumeng Xi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Induced Decarboxylative Functionalization of Carboxylic Acids and Their Derivatives

(2015) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C–C Bonds

(2015) Alan H. Cherney et al.   CHEMICAL REVIEWS

Organotrifluoroborates: Another Branch of the Mighty Oak

(2015) Gary A. Molander   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Synthesis of Carbo- and Heterocycles through a CuH-Catalyzed Hydroalkylation Approach

(2015) Yi-Ming Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of α-Aminoboronic Acid Derivatives by Copper-Catalyzed Enantioselective Hydroamination

(2015) Daiki Nishikawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Regiodivergent Cu-Catalyzed Aminoboration of Unactivated Terminal Alkenes

(2015) Ryosuke Sakae et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings

(2015) Osvaldo Gutierrez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Practical olefin hydroamination with nitroarenes

(2015) J. Gui et al.   SCIENCE

Catalytic asymmetric hydroamination of unactivated internal olefins to aliphatic amines

(2015) Y. Yang et al.   SCIENCE

Catalytic conjunctive cross-coupling enabled by metal-induced metallate rearrangement

(2015) L. Zhang et al.   SCIENCE

A Practical and Catalytic Reductive Olefin Coupling

(2014) Julian C. Lo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Linear-Selective Hydroarylation of Unactivated Terminal and Internal Olefins with Trifluoromethyl-Substituted Arenes

(2014) Joseph S. Bair et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Negishi Arylations of Propargylic Bromides: A Mechanistic Investigation

(2014) Nathan D. Schley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Reductive Coupling of Alkyl Acids with Unactivated Tertiary Alkyl and Glycosyl Halides

(2014) Chenglong Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules

(2014) Egor Geist et al.   NATURAL PRODUCT REPORTS

Functionalized olefin cross-coupling to construct carbon–carbon bonds

(2014) Julian C. Lo et al.   NATURE

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Enantioconvergent Cross-Couplings of Racemic Alkylmetal Reagents with Unactivated Secondary Alkyl Electrophiles: Catalytic Asymmetric Negishi α-Alkylations of N-Boc-pyrrolidine

(2013) Christopher J. Cordier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism and Selectivity in Nickel-Catalyzed Cross-Electrophile Coupling of Aryl Halides with Alkyl Halides

(2013) Soumik Biswas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel/Bis(oxazoline)-Catalyzed Asymmetric Negishi Arylations of Racemic Secondary Benzylic Electrophiles to Generate Enantioenriched 1,1-Diarylalkanes

(2013) Hien-Quang Do et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantio- and Regioselective CuH-Catalyzed Hydroamination of Alkenes

(2013) Shaolin Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fe(III)/NaBH4-Mediated Free Radical Hydrofluorination of Unactivated Alkenes

(2012) Timothy J. Barker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron(III)/NaBH4-Mediated Additions to Unactivated Alkenes: Synthesis of Novel 20′-Vinblastine Analogues

(2012) Erick K. Leggans et al.   ORGANIC LETTERS

Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners

(2011) Ranjan Jana et al.   CHEMICAL REVIEWS

Discovery of Isoerianin Analogues as Promising Anticancer Agents

(2011) Samir Messaoudi et al.   ChemMedChem

Transition metal-catalyzed decarboxylative cross-coupling reactions

(2011) Rui Shang et al.   Science China-Chemistry

Nickel-catalyzed cross coupling of non-activated alkyl halides: a mechanistic perspective

(2011) Xile Hu   Chemical Science

Selective C-4 Alkylation of Pyridine by Nickel/Lewis Acid Catalysis

(2010) Yoshiaki Nakao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Secondary Alkyl Halides in Transition-Metal-Catalyzed Cross-Coupling Reactions

(2009) Alena Rudolph et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C2-Symmetric Pyrrolidines Derived from Tartaric Acids: Versatile Chiral Building Blocks for Total Synthesis, Catalyst Design, Supramolecular and Medicinal Chemistry

(2009) Andreas Blum et al.   CURRENT ORGANIC SYNTHESIS

Catalytic Hydrochlorination of Unactivated Olefins withpara‐Toluenesulfonyl Chloride

(2008) Boris Gaspar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION