期刊
ORGANIC LETTERS
卷 22, 期 18, 页码 7363-7368出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c02721
关键词
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资金
- NSFC [21971153, 21671122, 21802091]
- Shandong Provincial Natural Science Foundation [ZR2018BB006]
- Project of the Shandong Province Higher Educational Science and Technology Program [J18KA066]
- Taishan Scholar's Construction Project of China at SDNU
- Changjiang Scholar project of China at SDNU
We demonstrate herein that the N-heterocyclic-carbene (NHC)-metal complex (NHC-M)-involved covalent organic framework (COF) can be prepared by the direct polymerization of the NHC-M monomer with its counterpart under solvothermal conditions. The NHC-M-COF with different counterions is readily achieved via solid-state anion exchange. The obtained NHC-AuX-COF (X = Cl- and SbF6-) can be a highly active reusable catalyst to separately promote the carboxylation of the terminal alkyne with CO2 and alkyne hydration under mild conditions.
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