4.7 Article

Demonstration of epoxy/carbon steel interfacial delamination behavior: Electrochemical impedance and X-ray spectroscopic analyses

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CORROSION SCIENCE
卷 102, 期 -, 页码 326-337

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PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2015.10.024

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Organic coatings; XPS; EIS; Interfaces

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In this work, we introduce an efficient methodology to assess the delamination mechanism of epoxy coating from steel substrate combining spectroscopic and analytical techniques. To reflect the competence of this approach, different samples were prepared by applying epoxy/polyaminoamide layers on untreated, acid and alkaline pretreated substrates. The results obtained from XPS and energy dispersive X-ray analyses describe delamination of the coatings on differently pretreated surfaces during the pull-off-test. EIS measurements demonstrated that acid treatment improves the resistance against cathodic delamination, while XPS analysis provided useful data about coating delamination from the substrate. (C) 2015 Elsevier Ltd. All rights reserved.

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