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Redox chemistry of cobalamin and its derivatives

期刊

COORDINATION CHEMISTRY REVIEWS
卷 309, 期 -, 页码 68-83

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2015.11.001

关键词

Cobalamin; Vitamin B-12; Free radicals; Reduction; Oxidation; Reaction mechanisms

资金

  1. Russian Scientific Foundation [14-23-00204]
  2. Council on Grants of the President of the Russian Federation [MK-3661.2015.3]
  3. Romanian Ministry of Education and Research [PCE 418/2012]
  4. Russian Science Foundation [14-23-00204] Funding Source: Russian Science Foundation

向作者/读者索取更多资源

A comprehensive review on redox reactions of Co(III), Co(II) and Co(I) forms of cobalamins (vitamin B-12) and their derivatives (cobinamide, cobyrinates) is presented. An influence of coordination environment of cobalt ion on reactivity of corresponding species is discussed. Mechanisms of reduction of Co(III) and Co(II) species as well as oxidation of Co(II) and Co(I) complexes are given in terms of their in vivo and catalytic implications. (C) 2015 Elsevier B.V. All rights reserved.

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