期刊
COORDINATION CHEMISTRY REVIEWS
卷 309, 期 -, 页码 68-83出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2015.11.001
关键词
Cobalamin; Vitamin B-12; Free radicals; Reduction; Oxidation; Reaction mechanisms
资金
- Russian Scientific Foundation [14-23-00204]
- Council on Grants of the President of the Russian Federation [MK-3661.2015.3]
- Romanian Ministry of Education and Research [PCE 418/2012]
- Russian Science Foundation [14-23-00204] Funding Source: Russian Science Foundation
A comprehensive review on redox reactions of Co(III), Co(II) and Co(I) forms of cobalamins (vitamin B-12) and their derivatives (cobinamide, cobyrinates) is presented. An influence of coordination environment of cobalt ion on reactivity of corresponding species is discussed. Mechanisms of reduction of Co(III) and Co(II) species as well as oxidation of Co(II) and Co(I) complexes are given in terms of their in vivo and catalytic implications. (C) 2015 Elsevier B.V. All rights reserved.
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