4.7 Article

Synthesis and strength optimization of one-part geopolymer based on red mud

期刊

CONSTRUCTION AND BUILDING MATERIALS
卷 111, 期 -, 页码 317-325

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.conbuildmat.2016.02.099

关键词

Bayer red mud; One-part geopolymer; Alkali-thermal activation; Sodium aluminosilicate; Silica fume

资金

  1. New Century Excellent Talents Project of Ministry of Education [NCET-10-0392]
  2. Public Welfare Program of Environmental Protection Ministry of China [201509056]
  3. Project of Innovative and Interdisciplinary Team of Huazhong University of Science and Technology (HUST) [0118261077]

向作者/读者索取更多资源

One-part geopolymer was synthesized from alkali-thermal activated Bayer red mud (RM) with addition of silica to optimize its composition. The RM was pretreated through alkali-thermal activation and turned to geopolymer precursor, which could be used by only adding water in blending process. However the long-term strength of the binder with only RM was poor because of the unstable polymerization due to the low SiO2/Al2O3 molar ratio (1.41). Silica fume (SF) was chosen to increase the SiO2/Al2O3 molar ratio of the geopolymer formulation. By adding 25 wt% of SF, the 28 d compressive strength of the geopolymer with a SiO2/Al2O3 molar ratio of 3.45 could reach 31.5 MPa at a water/solid ratio of 0.45. Sodium aluminosilicate in the activated RM dissolved in water and formed an alkaline environment to dissolve SF. The dissolved silica participated in geopolymerization, leading to a satisfactory geopolymer composition. Typical amorphous geopolymer matrices were formed in the binder completely cured. (c) 2016 Elsevier Ltd. All rights reserved.

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