期刊
INORGANIC CHEMISTRY
卷 59, 期 21, 页码 15962-15968出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.0c02433
关键词
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资金
- National Key Research and Development Plan of Ministry of Science and Technology [2016YFB0402104]
- National Natural Science Foundation of China [21921001, 51890862, 21975255, U1605245]
- NSF of Fujian Province [2019J01020758]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- Youth Innovation Promotion Association CAS [2019303]
Two new alkaline earth barbiturates, Ca(H3C4N2O3)(2)center dot H2O and Sr(H5C8N4O5)(2)center dot 4H(2)O, were synthesized via the mild hydrothermal technique. For Ca(H3C4N2O3)(2)center dot H2O, the stacking (H3C4N2O3)(-) anions along the c axis are interconnected by CaO7 polydedra forming a three-dimensional structure. Also, for Sr(H5C8N4O5)(2)center dot 4H(2)O, it has two-dimensional layers composed by SrO7 polyhedra and (H5C8N4O5)(-) anions. The (H5C8N4O5)(-) anions can be seen as two (H3C4N2O3)(-) anions connected each other via the N-C bond. Powder second-harmonic generation (SHG) measurements revealed that Ca(H3C4N2O3)(2)center dot H2O is a phase-matchable material with a moderate SHG response (ca. 1.15x that of KDP). Furthermore, the birefringence values of the two crystals were measured as 0.49 and 0.475 at 546.1 nm, respectively. The theoretical calculations showed that the SHG response and large birefringence were primarily caused by the (H3C4N2O3)(-) and (H5C8N4O5)(-) groups.
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