Article
Chemistry, Physical
Bingxin Zhu, Lei Wang, Qiufeng Shi, Haijie Guo, Jianwei Qiao, Cai'e Cui, Ping Huang
Summary: Single-doped manganese with two luminous centers of MgGa2O4 fluorescent powder was synthesized through a solid-state reaction. The article provides a detailed analysis of the optical characteristics and temperature sensitivity of MgGa2O4:Mn2+, Mn4+. The emission spectrum activated by 322 nm UV light exhibited a sharp green peak at 502 nm for Mn2+ and a red peak at 694 nm for Mn4+. Furthermore, the emission of Mn4+ decreases with increasing temperature, whereas the emission of Mn2+ initially increases before declining, indicating different temperature sensitivities between Mn2+ and Mn4+ in the MgGa2O4 host. The fluorescence intensity ratio (FIR) technology was employed to investigate the temperature sensor capability within the range of 80-500 K. The sample achieved a maximal relative sensitivity (Sr) value of 1.64% K-1 at 260 K, suggesting the significant potential of MgGa2O4:Mn2+, Mn4+ for optical thermometry.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Inorganic & Nuclear
Dinesh K. Amarasinghe, Federico A. Rabuffetti
Summary: The utility of Tb3+:Mn4+:Na4Mg(WO4)(3) phosphors as ratiometric luminescent thermometers in the 200-450 K temperature range is demonstrated. Differential thermal quenching of emissions from terbium and manganese allows for thermochromic behavior, with a maximum relative sensitivity of 2.5 x 10(-2) K-1 at 375 K and a resolution of 0.5 K. The findings highlight the versatility of Na4Mg(WO4)(3) as a platform for luminescent thermometers through targeted aliovalent substitutions.
INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Physical
Yuyin Fang, Yuanyuan Zhang, Yuanpeng Zhang, Yuepin Zhang, Xin Su, Jianxu Hu
Summary: Indoor plant growing requires the creation of artificial light that meets the needs of future agriculture. This study focuses on enhancing the blue component in LEDs for plant development and explores the potential of synthesized phosphors for indoor plant growth and temperature monitoring.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Materials Science, Ceramics
Longchao Liu, Hailian Liu, Wenqian Zou, Shoujun Ding
Summary: Trivalent erbium (Er3+) doped trivalent ytterbium (Yb3+) stoichiometric upconversion (UC) phosphors YbTaO4 (YbTaO4:Er3+) were synthesized. The phase structure was analyzed, and the bonds were revealed through spectroscopy. The multi-photon UC green and red luminescence were investigated, and the temperature-dependent UC emission spectra were measured. The optical temperature sensing performance and sensitivity of YbTaO4:Er3+ were evaluated.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Inorganic & Nuclear
Guixian Li, Yu Xue, Qinan Mao, Lang Pei, Hong He, Meijiao Liu, Liang Chu, Jiasong Zhong
Summary: Luminescent thermometers provide a non-contact method of probing temperature with high sensitivity and response speed at the nanoscale. By co-doping the highly temperature-sensitive Mn4+ and less-sensitive Eu3+ (or Sm3+) activators into a Ca2GdSbO6 matrix, an effective thermometer is formed.
DALTON TRANSACTIONS
(2022)
Article
Materials Science, Multidisciplinary
Zhihu Xu, Hui Lin, Ruijin Hong, Chunxian Tao, Zhaoxia Han, Dawei Zhang, Shengming Zhou
Summary: Yb3+/Mn2+ co-doped Y3Al5O12 phosphors were prepared through high-temperature solid-phase reaction and exhibited orange-red up-conversion emission of Mn2+ at room temperature. The cooperative luminescence of Yb3+-Mn2+ dimers contributed to the orange up-conversion emission peak at 585 nm under 980 nm excitation. The phosphors showed high absolute sensitivity and relative sensitivity, indicating their potential as reliable optical temperature sensors. The thermal reliability of the phosphors was also demonstrated, making them suitable for temperature sensing applications.
Article
Materials Science, Multidisciplinary
Sheng Wu, Shanshan Hu, Quan Liu, Shuai Zhang, Dongliang Jiang, Guoxing Zhang, Yakun Le, Yao Xiao, Binli Xiao, Puxian Xiong, Yan Chen, Yinzhen Wang
Summary: The self-reduction of Mn4+ -> Mn2+ and excellent thermal stability of NaY9Si6O26:Mn2+ red phosphors were achieved. The effect of defects on luminescence properties was highlighted, stimulating further research on defect control.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Materials Science, Multidisciplinary
Arnoldus J. J. van Bunningen, Atul D. D. Sontakke, Ruben van der Vliet, Vincent G. G. Spit, Andries Meijerink
Summary: Narrower band red and green emission in phosphor-converted white light-emitting diodes can be achieved by using Mn2+ as a luminescent ion. The luminescence quenching temperature of Mn2+ is shown to vary greatly depending on the host material, with a positive correlation with the bandgap of the host. The quenching mechanism is found to be thermally activated photoionization, and a wide-bandgap host material is required for temperature-stable Mn2+ luminescence in high power LEDs.
ADVANCED OPTICAL MATERIALS
(2023)
Article
Chemistry, Physical
Enrique Jara, Rafael Valiente, Marco Bettinelli, Fernando Rodriguez
Summary: We conducted a spectroscopic study on Mn-doped Mg2TiO4 under different pressure and temperature conditions to evaluate its potential as a red-emitting phosphor. The synthesis method used to create the material resulted in the formation of both Mn4+ and small traces of Mn3+. Despite the presence of Mn3+ not significantly affecting the photoluminescence of Mn4+, its local structure at the substituted Ti4+ host site led to a reduction in pumping efficiency and a drastic decrease in quantum yield at room temperature.Through a combination of Raman spectroscopy and time-resolved emission and excitation spectroscopies, we proposed a model to explain the nonradiative and inefficient pumping processes observed in this material. Additionally, we discovered a structural phase transition above 14 GPa that negatively impacted the photoluminescence capabilities. The reduction in emission intensity and lifetime with increasing temperature was attributed to small activation energies and the electric-dipole transition mechanism related to coupling to odd-parity vibrational modes. A detailed model based on the configurational energy level diagram of the A(1g) normal mode effectively explained the excitation and emission quantum yield of the material.
JOURNAL OF PHYSICAL CHEMISTRY C
(2021)
Article
Engineering, Environmental
Teng Zheng, Laihui Luo, Peng Du, Stefan Lis, Ulises R. Rodriguez-Mendoza, Victor Lavin, Marcin Runowski
Summary: Remote temperature and pressure monitoring provides opportunities to explore the luminescence properties of compounds under extreme conditions. In this study, double perovskite Gd2ZnTiO6 phosphors doped with Mn4+ were developed as bifunctional sensors for temperature and pressure. The optimized doping concentration of Mn4+ was found to achieve the highest emission intensity, and the concentration quenching mechanism was determined to be dipole-dipole interaction. The synthesized phosphors exhibited high internal and external quantum efficiencies, and demonstrated good thermal and pressure sensing properties.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Debao Zhang, Ji Zhou, Xuguang Cao, Xiaotian Ge, Fei Tang, Changcheng Zheng, Jiqiang Ning, Shijie Xu
Summary: In this paper, the giant tunability of thermal behaviors for the vibronic luminescence of Mn4+ ions in fluoride phosphors is demonstrated. The peculiar behavior is associated with the thermal excitation of low-frequency phonon bath, and a theoretical model is constructed to explain the phenomenon. The governing parameters for the distinct thermal behaviors of Mn4+-ion luminescence, including the thermal activation energy and the average phonon energy, are determined.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2023)
Article
Chemistry, Physical
Teng Zheng, Marcin Runowski, Natalia Stopikowska, Malgorzata Skwierczynska, Stefan Lis, Peng Du, Laihui Luo
Summary: Optical thermometers based on Er3+/Tm3+/Yb3+-doped Bi2MoO6 materials exhibit bright color-tunable upconversion emissions and exceptional thermal sensitivity, making them promising candidates for multi-parameter temperature sensing applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Spectroscopy
Minghua Wang, Zhuo Han, Junxiang Huang, Jinsheng Liao, Yijian Sun, Haiping Huang, He-rui Wen
Summary: A Bi3+-doped NaLaMgWO6:Mn4+/Pr3+/Bi3+ phosphor with tunable photoluminescence for controlling plant growth has been successfully prepared. The maximum relative sensitivity of approximately 3.39%/K at 298 K was achieved based on the fluorescence intensity ratios of Mn4+ and Pr3+. This phosphor is a bifunctional material for plant growth illumination and temperature sensing with high sensitivity.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2021)
Article
Materials Science, Multidisciplinary
Yingbin Meng, Peican Chen, Hua Fan, Zuizhi Lu, Xiaoying Zhong, Jiangying Lu, Yingjun Ou, Liya Zhou
Summary: In this study, the crystal structure, surface morphology, optical properties, and thermal properties of LCZ: Mn4+ phosphors were investigated. The possible site of Mn4+ ions was discussed based on density functional theory. The doped phosphor showed enhanced light absorption capacity and a wider absorption range, and emitted deep-red light with potential application value in plant growing LEDs.
MATERIALS RESEARCH BULLETIN
(2022)
Article
Chemistry, Physical
Michele Back, Jian Xu, Jumpei Ueda, Alvise Benedetti, Setsuhisa Tanabe
Summary: The design and development of effective luminescent thermal sensors have driven technological progress in various fields. However, finding reliable and simple methods to measure temperature remains a challenge. By combining narrow band gap semiconductors with lanthanoid ions, reliable multimodal thermal sensors can be designed, opening up new possibilities for thermochromic and luminescent thermal sensors.
CHEMISTRY OF MATERIALS
(2022)