期刊
FUEL PROCESSING TECHNOLOGY
卷 206, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.fuproc.2020.106462
关键词
Torrefaction; Waste wood-based panels; Denitrogenation; Upgrading; Evolution
资金
- National Key Research and Development Program of China [2016YFE0203300]
- National Natural Science Foundation of China [41961144029]
- Strategic Priority Research Program of Chinese Academy of Sciences [XDA21060600]
- Guangdong Basic and Applied Basic Research Foundation [2020A1515010337]
- Guangdong Foundation for Program of Science and Technology Research [2017B030314057]
- Postdoctoral Science Foundation of China [2018M643221]
As a type of special biowaste, waste wood-based panels (WWPs) have a high nitrogen content and typical biomass defect properties, which limit their clean and efficient thermal utilization. An upgrading and denitrogenation procedure prior to thermal utilization is necessary, but the relevant mechanisms and characteristics have not been clearly elucidated. Torrefaction pretreatment of three typical WWPs (plywood, fiberboard, particleboard) was conducted to investigate the evolution of carbon and nitrogen functionalities in relation to the upgrading/denitrogenation procedure. The results demonstrated that the combined upgrading/denitrogenation of WWPs was possible. Under optimal operating conditions (300 degrees C and 10 min), the denitrogenation efficiency could reach 60-70 wt% with a slight energy loss of < 30% and a high HHV (20-22 MJ/kg) of the corresponding torrefied products. The carbon functionality evolution (upgrading) was believed to be the continuous change from low-energy -C-H/-C-O/-C=O to high-energy aromatic -C-C/-C=C, which was related to the reactions of lignin (demethoxylation, chain scission and polycondensation), hemicellulose (deacetylation and degradation) and cellulose (degradation). The nitrogen functionality evolution (denitrogenation) was regarded as a conversion of amide-N into more stable heterocyclic-N (pyrrolic-N and pyridinic-N) through cross-linking reactions, together with a significant release of nitrogen containing gases (NH3 and HCN).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据