Role of extracellular polymeric substances in sludge dewatering under modified corn-core powder and sludge-based biochar pretreatments

Extracellular polymeric substances (EPS) which wrapped on sludge particles were deemed to hinder the out flowing of combined water in sludge system. The complex composition of EPS was the bottleneck for revealing its relationship with sludge dewaterability. In this study, a combined modified corn-core powder (MCCP) and sludge-based biochar (SBB) condition was executed to treat sludge for enhancing dehydration performance, and the concentration and the form distribution of organics in EPS, the variances of protein secondary structures were investigated. Correlation between the sludge dewaterability and EPS components were performed, found strong correlations among the net sludge solids yield (YN) and the specific resistance of filtration (SRF) (R = -0.923), Zeta potential (R = -0.971). Furthermore, the relationship between the secondary structures of protein and dehydration performance were strong related. With the optimal dosage of SBB and MCCP, aggregated strands and alpha-helix were released, indicated that the unfolding and despiralization in soluble EPS (SEPS) were improved, disordered the sludge network, reduced the flowing resistance of bound water, finally enhancing sludge dewaterability.