期刊
CHEMSUSCHEM
卷 14, 期 1, 页码 293-302出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.202001914
关键词
carbon dioxide reduction; heterogeneous catalysis; homogeneous catalysis; metalloporphyrins; oxygen reduction
资金
- Natural Sciences and Engineering Research Council (NSERC) [RGPIN 05559, 06272]
- Simon Fraser University
- China Scholarship Council
In the past decade, significant advances have been made in the use of metalloporphyrins as catalysts for the activation and reduction of small molecules, particularly O-2 and CO2. The development of new molecular designs, scaling relationships, and theoretical modeling has rapidly advanced the utility of porphyrins as electrocatalysts. Emphasis is placed on contrasting homogeneous and heterogeneous electrocatalysis and proposing ideas for the development of practical catalysts based on lessons learned from the last decade of research.
Porphyrins are archetypal ligands in inorganic chemistry. The last 10 years have seen important new advances in the use of metalloporphyrins as catalysts in the activation and reduction of small molecules, in particular O-2 and CO2. Recent developments of new molecular designs, scaling relationships, and theoretical modeling of mechanisms have rapidly advanced the utility of porphyrins as electrocatalysts. This Minireview focuses on the summary and evaluation of recent developments of metalloporphyrin O-2 and CO2 reduction electrocatalysts, with an emphasis on contrasting homogeneous and heterogeneous electrocatalysis. Comparisons for proposed reaction mechanisms are provided for both CO2 and O-2 reduction, and ideas are proposed about how lessons from the last decade of research can lead to the development of practical, applied porphyrin-derived catalysts.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据