4.7 Article

Removal of soluble microbial products and dyes using heavy metal wastes decorated on eggshell

期刊

CHEMOSPHERE
卷 270, 期 -, 页码 -

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.chemosphere.2020.128615

关键词

Powdered eggshell; Metal ion; Soluble microbial product; Dye; Removal

资金

  1. Ministry of Science and Technology of Taiwan [MOST 104-2622-E-131-021, MOST 103-2622-E-131-CC3]

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This study explored the potential of using eggshell waste as an adsorbent for the sequential removal of heavy metals, soluble microbial products, and dye wastes. The modified eggshell particles showed effective adsorption of CEW proteins and absorption of dyes, demonstrating a low-cost and simple method for treating wastewater.
This work studied the potential of using eggshell (ES) (200-300 mm) waste as adsorbent for sequential removal of heavy metals, soluble microbial products, and dye wastes. In this study, among soluble microbial products, chicken egg white (CEW) proteins were selected as simulated contaminants. ES was applied to capture heavy metal ions (e.g., Cu2+ and Zn2+) and the formed eggshell metal (ES-M) complex was use to absorb soluble microbial products (e.g., soluble proteins), followed by subsequent removal of dyes from aqueous solutions using ES-M-CEW adsorbent. The experimental conditions for the adsorption of CEW proteins by ES-M include shaking rate, adsorption pH, isothermal and kinetic studies. The maximum protein adsorption by ES-Zn and ES-Cu were 175.67 and 153.65 mg/g, respectively. Optimal removal efficiencies of the ES-M-CEW particles for Acid Orange (AO7) and Toluidine blue (TBO) dyes were at pH 2 and 12, respectively, achieving performance of 75.38 and 114.18 mg/g, respectively. The removal of TBO dye by ES-M-CEW adsorbent was equilibrated at 5 min. The results showed that low cost and simple preparation of the modified ES particles are feasible for treating various wastewaters. (C) 2020 Elsevier Ltd. All rights reserved.

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