期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 26, 期 71, 页码 17011-17015出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202003506
关键词
alkenes; desymmetrization; hydrosilylation; rhodium; Si-stereogenic center
资金
- National Natural Science Foundation of China [21625104, 21971133]
- National Key Research and Development Program of China [2017YFA0505200]
Catalytic, enantioselective synthesis of stereogenic silicon compounds remains a challenge. Herein, we report a rhodium-catalyzed regio- and enantio-selective intermolecular hydrosilylation of alkene with prochiral dihydrosilane. This new method features a simple catalytic system, mild reaction conditions and a wide functional group tolerance.
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