In Situ Mass Spectrometric and Kinetic Investigations of Soai's Asymmetric Autocatalysis

Demystifying the asymmetry-amplifying, autocatalytic behaviour of the Soai reaction through structural, mechanistic and computational studies

(2020) Soumitra V. Athavale et al.   Nature Chemistry

Autocatalytic Models for the Origin of Biological Homochirality

(2019) Donna G. Blackmond   CHEMICAL REVIEWS

Rationalization of Asymmetric Amplification via Autocatalysis Triggered by Isotopically Chiral Molecules

(2018) Neil A. Hawbaker et al.   ACS Central Science

Can the analyte-triggered asymmetric autocatalytic Soai reaction serve as a universal analytical tool for measuring enantiopurity and assigning absolute configuration?

(2017) Christopher J. Welch et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Reversal of the sense of enantioselectivity between 1- and 2-aza[6]helicenes used as chiral inducers of asymmetric autocatalysis

(2017) Arimasa Matsumoto et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Spontaneous mirror symmetry breaking in heterocatalytically coupled enantioselective replicators

(2017) Josep M. Ribó et al.   Chemical Science

Recycling in Asymmetric Catalysis

(2016) Christina Moberg   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Induction by a Nitrogen14N/15N Isotopomer in Conjunction with Asymmetric Autocatalysis

(2016) Arimasa Matsumoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Determination of the absolute structure of the chiral crystal consisting of achiral dibutylhydroxytoluene and asymmetric autocatalysis triggered by this chiral crystal

(2016) Arimasa Matsumoto et al.   TETRAHEDRON-ASYMMETRY

Hyphenation of Hadamard Encoded Multiplexing Liquid Chromatography and Circular Dichroism Detection to Improve the Signal-to-Noise Ratio in Chiral Analysis

(2015) Alexander F. Siegle et al.   ANALYTICAL CHEMISTRY

Crystal Structure of the Isopropylzinc Alkoxide of Pyrimidyl Alkanol: Mechanistic Insights for Asymmetric Autocatalysis with Amplification of Enantiomeric Excess

(2015) Arimasa Matsumoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Perspectives in Chemistry-Aspects of Adaptive Chemistry and Materials

(2015) Jean-Marie Lehn   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

On the Origin and Structure of the Recently Observed Acetal in the Soai Reaction

(2015) Ilya D. Gridnev et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Asymmetric Autocatalysis Triggered by Chiral Crystal of Achiral Ethylenediamine Sulfate

(2015) Arimasa Matsumoto et al.   CHEMISTRY LETTERS

Absolute Asymmetric Synthesis: Protected Substrate Oxidation

(2015) Susanne Olsson et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Amplification Coupling Enantioselective Autocatalysis and Asymmetric Induction for Alkylation of Azaaryl Aldehydes

(2015) Carlo Romagnoli et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enabling Asymmetric Alkynylation of Azaaryl Aldehydes with Soai Autocatalyst

(2015) Matías Funes-Maldonado et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Stochastic and empirical models of the absolute asymmetric synthesis by the Soai-autocatalysis

(2015) Béla Barabás et al.   JOURNAL OF MOLECULAR MODELING

Development of a Straightforward and Robust Technique to Implement Hadamard Encoded Multiplexing to High-Performance Liquid Chromatography

(2014) Alexander F. Siegle et al.   ANALYTICAL CHEMISTRY

Self-Replication and Amplification of Enantiomeric Excess of Chiral Multifunctionalized Large Molecules by Asymmetric Autocatalysis

(2014) Tsuneomi Kawasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transient Substrate-Induced Catalyst Formation in a Dynamic Molecular Network

(2014) Hugo Fanlo-Virgós et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Minor Enantiomer Recycling: Application to Enantioselective Syntheses of Beta Blockers

(2014) Ye-Qian Wen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantiopure Isoindolinones through Viedma Ripening

(2014) René R. E. Steendam et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Autocatalysis Induced by Cinnabar: Observation of the Enantioselective Adsorption of a 5-Pyrimidyl Alkanol on the Crystal Surface

(2013) Hitoshi Shindo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Perspectives in Chemistry-Steps towards Complex Matter

(2013) Jean-Marie Lehn   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis Induced by the Helical Molecular Arrangement in the Chiral Crystal of Achiral Tris(2-hydroxyethyl) 1,3,5-Benzenetricarboxylate in Conjunction with Asymmetric Autocatalysis

(2013) Tsuneomi Kawasaki et al.   CHEMISTRY LETTERS

Artificial Allosteric Receptors

(2013) Christopher Kremer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Jaguar: A high-performance quantum chemistry software program with strengths in life and materials sciences

(2013) Art D. Bochevarov et al.   INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY

Asymmetric autocatalysis triggered by oxygen isotopically chiral glycerin

(2013) Arimasa Matsumoto et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantiodivergent formation of a chiral cytosine crystal by removal of crystal water from an achiral monohydrate crystal under reduced pressure

(2013) Hiroko Mineki et al.   TETRAHEDRON-ASYMMETRY

Observation of a Transient Intermediate in Soai’s Asymmetric Autocatalysis: Insights from 1H NMR Turnover in Real Time

(2012) Timo Gehring et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Effects of the Stationary Phase and the Solvent on the Stereodynamics of biphep Ligands Quantified by Dynamic Three-Column HPLC

(2012) Frank Maier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amplification of enantiomeric excess, mirror-image symmetry breaking and kinetic proofreading in Soai reaction models with different oligomeric orders

(2012) Jean-Claude Micheau et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Quantification of Sophisticated Equilibria in the Reaction Pool and Amplifying Catalytic Cycle of the Soai Reaction

(2012) Ilya D. Gridnev et al.   ACS Catalysis

Enantioselective CC Bond Formation as a Result of the Oriented Prochirality of an Achiral Aldehyde at the Single-Crystal Face upon Treatment with a Dialkyl Zinc Vapor

(2011) Tsuneomi Kawasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Autocatalysis: Triggered by Chiral Isotopomer Arising from Oxygen Isotope Substitution

(2011) Tsuneomi Kawasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis Induced by Compounds with Chirality Arising from Partially Deuterated Methyl Groups in Conjunction with Asymmetric Autocatalysis

(2011) Tsuneomi Kawasaki et al.   CHEMISTRY LETTERS

Opposite Enantiomers from Minor Enantiomer Recycling and Dynamic Kinetic Resolution Using a Single Biocatalyst

(2011) Anna Laurell et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Putting the Mechanism of the Soai Reaction to the Test: DFT Study of the Role of Aldehyde and Dialkylzinc Structure

(2011) Gianfranco Ercolani et al.   JOURNAL OF ORGANIC CHEMISTRY

Stochastic interpretation of the asymmetry of enantiomeric distribution observed in the absolute asymmetric Soai reaction

(2011) Gábor Lente   TETRAHEDRON-ASYMMETRY

Minor Enantiomer Recycling-Effect of Two Reinforcing Catalysts on Product Yield and Enantiomeric Excess

(2010) Linda Fransson et al.   ChemCatChem

Gaining Selectivity by Combining Catalysts: Sequential versus Recycling Processes

(2010) Linda Fransson et al.   ChemCatChem

When chiral product and catalyst are the same: discovery of asymmetric organoautocatalysis

(2010) Svetlana B. Tsogoeva   CHEMICAL COMMUNICATIONS

Mechanism of the Asymmetric Autocatalytic Soai Reaction Studied by Density Functional Theory

(2010) Luca Schiaffino et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Autocatalytic Cycle Model of Asymmetric Amplification and Mirror-Symmetry Breaking in the Soai Reaction

(2010) Jean-Claude Micheau et al.   CHEMPHYSCHEM

A concise summary of experimental facts about the Soai reaction

(2010) Timo Gehring et al.   CHIRALITY

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

(2010) Stefan Grimme et al.   JOURNAL OF CHEMICAL PHYSICS

Unusual Inverse Temperature Dependence on Reaction Rate in the Asymmetric Autocatalytic Alkylation of Pyrimidyl Aldehydes

(2010) Michela Quaranta et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kinetic aspects of non-linear effects in asymmetric synthesis, catalysis, and autocatalysis

(2010) Donna G. Blackmond   TETRAHEDRON-ASYMMETRY

MISER chromatography (multiple injections in a single experimental run): the chromatogram is the graph

(2010) Christopher J. Welch et al.   TETRAHEDRON-ASYMMETRY

Nonlinear Effects in Asymmetric Catalysis

(2009) Tummanapalli Satyanarayana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis

(2009) Tsuneomi Kawasaki et al.   CHEMICAL COMMUNICATIONS

Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality

(2009) Tsuneomi Kawasaki et al.   CHEMICAL COMMUNICATIONS

Systematic Studies using 2-(1-Adamantylethynyl)pyrimidine-5-carbaldehyde as a Starting Material in Soai’s Asymmetric Autocatalysis

(2009) Mark Busch et al.   CHEMISTRY-A EUROPEAN JOURNAL

Minor Enantiomer Recycling: Metal Catalyst, Organocatalyst and Biocatalyst Working in Concert

(2009) Erica Wingstrand et al.   CHEMISTRY-A EUROPEAN JOURNAL

Amplification of Chirality and Enantioselectivity in the Asymmetric Autocatalytic Soai Reaction

(2009) Luca Schiaffino et al.   CHEMPHYSCHEM

Asymmetric Autocatalysis Triggered by Carbon Isotope (13C/12C) Chirality

(2009) T. Kawasaki et al.   SCIENCE

Unraveling the Mechanism of the Soai Asymmetric Autocatalytic Reaction by First-Principles Calculations: Induction and Amplification of Chirality by Self-Assembly of Hexamolecular Complexes

(2008) Luca Schiaffino et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Re-Examination of Reversibility in Reaction Models for the Spontaneous Emergence of Homochirality

(2008) Donna G. Blackmond et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Achiral Nucleobase Cytosine Acts as an Origin of Homochirality of Biomolecules in Conjunction with Asymmetric Autocatalysis

(2007) Tsuneomi Kawasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION