Achieving Ultrahigh Molecular Weights with Diverse Architectures for Unconjugated Monomers through Oxygen‐Tolerant Photoenzymatic RAFT Polymerization

100th Anniversary of Macromolecular Science Viewpoint: Achieving Ultrahigh Molecular Weights with Reversible Deactivation Radical Polymerization

(2020) Zesheng An   ACS Macro Letters

Ultrahigh Molecular Weight Hydrophobic Acrylic and Styrenic Polymers through Organic-Phase Photoiniferter-Mediated Polymerization

(2020) R. Nicholas Carmean et al.   ACS Macro Letters

Influence of the Polymer Glass Transition Temperature and Molecular Weight on Drug Amorphization Kinetics Using Ball Milling

(2020) Camilla Asgreen et al.   Pharmaceutics

Synthesis of ultra-high molecular weight polymers by controlled production of initiating radicals

(2019) Amin Reyhani et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Non-natural Photoenzymatic Controlled Radical Polymerization Inspired by DNA Photolyase

(2019) Fanfan Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tuning Dispersity by Photo-Induced ATRP: Monomodal Distributions with ppm Copper Concentration

(2019) Richard Whitfield et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoexcitation of flavoenzymes enables a stereoselective radical cyclization

(2019) Kyle F. Biegasiewicz et al.   SCIENCE

Highly Living Stars via Core-First Photo-RAFT Polymerization: Exploitation for Ultra-High Molecular Weight Star Synthesis

(2019) Stephanie Allison-Logan et al.   ACS Macro Letters

Precise Synthesis of Ultra-High-Molecular-Weight Fluoropolymers Enabled by Chain-Transfer Agent Differentiation under Visible-Light Irradiation

(2019) Honghong Gong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of UHMW Star-Shaped AB Block Copolymers and Their Flocculation Efficiency in High-Ionic-Strength Environments

(2019) Vu H. Dao et al.   MACROMOLECULES

Photocontrolled Iodine-Mediated Reversible-Deactivation Radical Polymerization System: Solution Polymerization of Methacrylates by Irradiation with NIR LED Light

(2019) Chun Tian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric redox-neutral radical cyclization catalysed by flavin-dependent ‘ene’-reductases

(2019) Michael J. Black et al.   Nature Chemistry

Copper-Mediated Polymerization without External Deoxygenation or Oxygen Scavengers

(2018) Evelina Liarou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Breathing Atom-Transfer Radical Polymerization: Fully Oxygen-Tolerant Polymerization Inspired by Aerobic Respiration of Cells

(2018) Alan E. Enciso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Blood-Catalyzed RAFT Polymerization

(2018) Amin Reyhani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Oxygen-Tolerant PET-RAFT Polymerization for Screening Structure-Activity Relationships

(2018) Adam J. Gormley et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxygen-Initiated and Regulated Controlled Radical Polymerization under Ambient Conditions

(2018) Chunna Lv et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Mediated Reversible Deactivation Radical Polymerization in Aqueous Media

(2018) Glen R. Jones et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Near-Infrared Sensitized Photoinduced Atom-Transfer Radical Polymerization (ATRP) with a Copper(II) Catalyst Concentration in the ppm Range

(2018) Ceren Kütahya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

PET-RAFT polymerisation: towards green and precision polymer manufacturing

(2018) Jamie Phommalysack-Lovan et al.   CHEMICAL COMMUNICATIONS

Biocompatible Choline Iodide Catalysts for Green Living Radical Polymerization of Functional Polymers

(2018) Chen-Gang Wang et al.   ACS Macro Letters

Heteroatom-Doped Carbon Dots (CDs) as a Class of Metal-Free Photocatalysts for PET-RAFT Polymerization under Visible Light and Sunlight

(2018) Jingjie Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Evolution and Future Directions of Metal-Free Atom Transfer Radical Polymerization

(2018) Emre H. Discekici et al.   MACROMOLECULES

Repurposing Biocatalysts to Control Radical Polymerizations

(2018) Kyle J. Rodriguez et al.   ACS Macro Letters

Visible-Light-Driven MADIX Polymerisation via a Reusable, Low-Cost, and Non-Toxic Bismuth Oxide Photocatalyst

(2018) Karen Hakobyan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ultra-High-Molecular-Weight Polymers Produced by the Immortal Phosphine-Based Catalyst System

(2018) Yun Bai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Biocatalytic “Oxygen-Fueled” Atom Transfer Radical Polymerization

(2018) Alan E. Enciso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

50th Anniversary Perspective: RAFT Polymerization—A User Guide

(2017) Sébastien Perrier   MACROMOLECULES

Organometallic-mediated radical polymerization of ‘less activated monomers’: Fundamentals, challenges and opportunities

(2017) Antoine Debuigne et al.   POLYMER

RAFT/MADIX polymerization of N-vinylcaprolactam in water–ethanol solvent mixtures

(2017) Ine Van Nieuwenhove et al.   Polymer Chemistry

Synthesis of ultra-high molecular weight ABA triblock copolymers via aqueous RAFT-mediated gel polymerisation, end group modification and chain coupling

(2017) Vu H. Dao et al.   Polymer Chemistry

Coenzyme-Catalyzed Electro-RAFT Polymerization

(2017) Wei Sang et al.   ACS Macro Letters

One-Enzyme Triple Catalysis: Employing the Promiscuity of Horseradish Peroxidase for Synthesis and Functionalization of Well-Defined Polymers

(2017) Zhifen Liu et al.   ACS Macro Letters

Ultra-High Molecular Weights via Aqueous Reversible-Deactivation Radical Polymerization

(2017) R. Nicholas Carmean et al.   Chem

Combinatorial Low-Volume Synthesis of Well-Defined Polymers by Enzyme Degassing

(2016) Robert Chapman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Star Polymers

(2016) Jing M. Ren et al.   CHEMICAL REVIEWS

Glucose oxidase deoxygenation−redox initiation for RAFT polymerization in air

(2016) Yue Lv et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Highly Extensible Supramolecular Elastomers with Large Stress Generation Capability Originating from Multiple Hydrogen Bonds on the Long Soft Network Strands

(2016) Mikihiro Hayashi et al.   MACROMOLECULAR RAPID COMMUNICATIONS

RAFT-Polymerization-Induced Self-Assembly and Reorganizations: Ultrahigh-Molecular-Weight Polymer and Morphology-Tunable Micro-/Nanoparticles in One Pot

(2016) Xiao-Yun Zhang et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Ultrahigh Molecular Weight Linear Block Copolymers: Rapid Access by Reversible-Deactivation Radical Polymerization and Self-Assembly into Large Domain Nanostructures

(2016) Jose Kenneth D. Mapas et al.   MACROMOLECULES

Mechanically controlled radical polymerization initiated by ultrasound

(2016) Hemakesh Mohapatra et al.   Nature Chemistry

Low concentration thermoresponsive hydrogels from readily accessible triblock copolymers

(2016) Laurie Despax et al.   Polymer Chemistry

Organocatalyzed atom transfer radical polymerization driven by visible light

(2016) J. C. Theriot et al.   SCIENCE

Light-Regulated Polymerization under Near-Infrared/Far-Red Irradiation Catalyzed by Bacteriochlorophyll a

(2015) Sivaprakash Shanmugam et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enzyme-Initiated Reversible Addition–Fragmentation Chain Transfer Polymerization

(2015) Baohua Zhang et al.   MACROMOLECULES

Rapid synthesis of ultrahigh molecular weight and low polydispersity polystyrene diblock copolymers by RAFT-mediated emulsion polymerization

(2015) Nghia P. Truong et al.   Polymer Chemistry

Metal-Free Atom Transfer Radical Polymerization

(2014) Nicolas J. Treat et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Robust and Versatile Photoinduced Living Polymerization of Conjugated and Unconjugated Monomers and Its Oxygen Tolerance

(2014) Jiangtao Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Controlled Open Vessel RAFT Polymerizations by Enzyme Degassing

(2014) Robert Chapman et al.   MACROMOLECULES

Emulsion Polymerization of Vinyl Acetate in the Presence of Different Hydrophilic Polymers Obtained by RAFT/MADIX

(2014) Sandra Binauld et al.   MACROMOLECULES

Photoinduced Electron Transfer–Reversible Addition–Fragmentation Chain Transfer (PET-RAFT) Polymerization of Vinyl Acetate and N-Vinylpyrrolidinone: Kinetic and Oxygen Tolerance Study

(2014) Sivaprakash Shanmugam et al.   MACROMOLECULES

Low temperature RAFT/MADIX gel polymerisation: access to controlled ultra-high molar mass polyacrylamides

(2014) Emmanuelle Read et al.   Polymer Chemistry

Hemoglobin and Red Blood Cells Catalyze Atom Transfer Radical Polymerization

(2013) Tilana B. Silva et al.   BIOMACROMOLECULES

Facile Access to Poly(N-vinylpyrrolidone)-Based Double Hydrophilic Block Copolymers by Aqueous Ambient RAFT/MADIX Polymerization

(2013) Aymeric Guinaudeau et al.   MACROMOLECULES

Control of a Living Radical Polymerization of Methacrylates by Light

(2012) Brett P. Fors et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aqueous RAFT/MADIX polymerisation of N-vinyl pyrrolidone at ambient temperature

(2011) Aymeric Guinaudeau et al.   Polymer Chemistry

Electrochemically Mediated Atom Transfer Radical Polymerization

(2011) A. J. D. Magenau et al.   SCIENCE

'Green' reversible addition-fragmentation chain-transfer (RAFT) polymerization

(2010) Mona Semsarilar et al.   Nature Chemistry

A Green Route to Well-Defined High-Molecular-Weight (Co)polymers Using ARGET ATRP with Alkyl Pseudohalides and Copper Catalysis

(2009) Renaud Nicolaÿ et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Glucose oxidase — An overview

(2009) Sandip B. Bankar et al.   BIOTECHNOLOGY ADVANCES

Toward Living Radical Polymerization

(2008) Graeme Moad et al.   ACCOUNTS OF CHEMICAL RESEARCH

Polymer–protein conjugates from ω-aldehyde endfunctional poly(N-vinylpyrrolidone) synthesised via xanthate-mediated living radical polymerisation

(2008) Gwenaelle Pound et al.   CHEMICAL COMMUNICATIONS

Unexpected reactions associated with the xanthate-mediated polymerization ofN-vinylpyrrolidone

(2008) Gwenaelle Pound et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY