Article
Polymer Science
Bilal Anjum Ahmed, Uzair Nadeem, Abbas Saeed Hakeem, Anwar Ul-Hamid, Mohd Yusuf Khan, Muhammad Younas, Hasan Aftab Saeed
Summary: This study focuses on optimizing the FDM process and post-process parameters to maximize the tensile strength of PLA samples. The analysis shows that the gyroid infill pattern and a 90-degree Celsius annealing cycle result in the highest ultimate tensile strength.
Article
Chemistry, Applied
Khalil Ahmad, Jawad Manzur, Muhammad Tahir, Rabia Hussain, Mahmood Khan, Abdul Wadood, Egemen Avcu, Muhammad Atiq Ur Rehman
Summary: In this study, zein coatings containing cloves were developed on stainless steel substrates using electrophoretic deposition. The coatings exhibited excellent antibacterial activity, drug release capability, surface properties, corrosion resistance, and adhesion. These zein/cloves coatings have potential applications in orthopedics as they possess antimicrobial effects and can provide targeted drug delivery.
PROGRESS IN ORGANIC COATINGS
(2023)
Article
Materials Science, Coatings & Films
Sandeep Singh, Gurpreet Singh, Niraj Bala
Summary: The study fabricated a composite coating of CS-HA-BG-Fe3O4 with bioactivity, high corrosion resistance, and excellent cell proliferation, suitable for biomedical applications.
SURFACE & COATINGS TECHNOLOGY
(2021)
Review
Chemistry, Physical
Marija Djosic, Ana Jankovic, Vesna Miskovic-Stankovic
Summary: Current trends in biomaterials science focus on designing multifunctional implant coatings that can inhibit bacterial growth while promoting osseointegration to ensure prolonged implant functionality.
Article
Chemistry, Physical
Filip Maciag, Tomasz Moskalewicz, Kazimierz Kowalski, Alicja Lukaszczyk, Zoya Hadzhieva, Aldo Roberto Boccaccini
Summary: In this study, zein coatings were successfully obtained on titanium substrates by electrophoretic deposition, with the coating morphology being significantly influenced by the zein content, water to ethanol ratio, process voltage, and time. Chemical treatment of the Ti substrate surface prior to deposition was found to enhance the adhesion of the coatings. Coated titanium substrates exhibited slightly lower electrochemical corrosion resistance in aqueous solution compared to uncoated substrates, and showed well-developed surface topography and hydrophilic nature.
Article
Materials Science, Ceramics
Jingpei Zhu, Chuanwei Fan, Conghui Ning, Wei Wang
Summary: HA-rGO-ZnO ternary composite coatings were successfully prepared on ZK60 magnesium alloy by cathodic electrophoretic deposition method. The addition of ZnO nanoparticles reduced the crystallinity of hydroxyapatite and improved the corrosion resistance and bioactivity of the coatings.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Multidisciplinary
Zoya Hadzhieva, Katarzyna Cholewa-Kowalska, Ivo Dlouhy, Tomasz Moskalewicz, Aldo R. Boccaccini
Summary: Coatings based on zein with the addition of bioactive glass particles doped with fluoride or a combination of fluoride and copper were deposited on titanium by electrophoretic deposition. The coatings showed improved scratch resistance and antibacterial activity, with no impact on bioactivity. These coatings have potential applications in orthopaedic and dental implants.
Article
Materials Science, Multidisciplinary
Sandeep Singh, Gurpreet Singh, Niraj Bala
Summary: The study focused on electrophoretic deposition of hydroxyapatite, bioglass, and iron oxide nanoparticles nanocomposite coating into chitosan matrix on AZ91 Mg alloy. The nanocomposite coatings exhibited a porous spherical structure, with the hydroxyapatite-bioglass-1% iron oxide coating showing the highest corrosion resistance. Hemocompatibility tests indicated a hemolysis ratio < 5% and no detrimental effects on erythrocytes, suggesting the potential of this coating for degradable implant applications.
MATERIALS TODAY COMMUNICATIONS
(2021)
Article
Materials Science, Ceramics
Shirin Khanmohammadi, Mehdi Ojaghi-Ilkhchi, Morteza Farrokhi-Rad
Summary: The electrophoretic deposition of bioglass coatings reinforced with hydroxyapatite whiskers on anodized titanium substrates showed enhanced adhesion strength for fine bioglass particles, with no effect on microhardness and bioactivity. The introduction of titania nanotubes during anodizing process improved the bactericidal effect and cellular behavior of the coatings, while also reducing corrosion current density compared to bare titanium.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Multidisciplinary
Sri Rahmadani, Anawati Anawati, Muhammad Dikdik Gumelar, Razie Hanafi, I. Nyoman Jujur
Summary: Bioactive hydroxyapatite (HA) coating was successfully applied on commercially pure Ti using electrophoretic deposition (EPD), with the 30 V coating showing the best corrosion resistance due to high HA grain density and low corrosion current density.
MATERIALS RESEARCH EXPRESS
(2022)
Article
Engineering, Biomedical
Kaori Iwanami-Kadowaki, Tetsuo Uchikoshi, Masayoshi Uezono, Masanori Kikuchi, Keiji Moriyama
Summary: EPD is a simple, rapid, and inexpensive technique for uniform coatings with controlled thicknesses. The modified EPD technique using Mg2+ ions successfully coated HAp/Col on a Ti substrate with controlled thickness, drastically increasing adhesive strength compared to non-Mg2+ EPD coating. The new coating showed potential for applications in instruments requiring rapid osseointegration at the bone-implant surface.
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A
(2021)
Article
Engineering, Multidisciplinary
G. T. Mohanraj, Sharnappa Joladarashi, Harish Hanumanthappa, Bharath Kumar Shanmugam, Harsha Vardhan, Gajanan M. Naik, P. Devadas Bhat, M. R. Rahman
Summary: This study focused on numerical analysis of magnetic rollers with different magnet disc-to-steel disc width ratios using FEMM software. The optimized magnetic roller showed advantages in magnetic field value. Predictive analysis was conducted using artificial neural networks, and a lab-scale permanent magnet roller separator was developed based on the optimized roller.
ALEXANDRIA ENGINEERING JOURNAL
(2022)
Article
Materials Science, Composites
M. Heidari-Rarani, N. Ezati, P. Sadeghi, M. R. Badrossamay
Summary: Fused deposition modeling (FDM) is a common method for additive manufacturing of polymers, which is capable of producing complex parts quickly. This study examines the effect of three important process parameters - infill density, printing speed, and layer thickness - on the tensile properties of polylactic acid (PLA) specimens. The optimal parameters for maximum mechanical properties, minimum weight, and minimum printing time are determined using the Taguchi design of experiment method. The accuracy of the Taguchi method in predicting the mechanical properties of FDM-3D printed specimens is also assessed.
JOURNAL OF THERMOPLASTIC COMPOSITE MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
M. E. Aksoy, B. Aksakal, N. Aslan, B. Dikici
Summary: In this study, boron-doped hydroxyapatite (B-HAp) biocomposites were synthesized and applied as coatings to metallic implants using electrophoretic deposition (EPD). The results showed that the highest adhesion strength and corrosion resistance were achieved with 15 wt.% B-HAP coating at 120 s deposition time and 76.5 mu m coating thickness.
JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE
(2021)
Article
Materials Science, Coatings & Films
Mahboobeh Mahmoodi, Mohammad Hossein Hydari, Leila Mahmoodi, Lida Gazanfari, Marjan Mirhaj
Summary: In this study, graphene oxide/hydroxyapatite composite coating on tantalum substrate was achieved by electrophoretic deposition, enhancing hardness and corrosion resistance while reducing friction coefficient. The high surface roughness and wettability of the coating promoted the proliferation of MG-63 cells on the surface, suggesting potential for dental and orthopedic implant applications.
SURFACE & COATINGS TECHNOLOGY
(2021)
Review
Materials Science, Multidisciplinary
Muhammad Atiq Ur Rehman, Qianq Chen, Annabel Braem, Milo S. P. Shaffer, Aldo R. Boccaccini
Summary: Electrophoretic deposition (EPD) is a powerful technique for assembling carbon nanotube (CNT) coatings and composite films with controlled architectures. This review focuses on achievements and challenges within the last 15 years, emphasizing the importance of stable CNT suspensions for successful EPD. The advantages of EPD processing include the ability to prepare CNT films and composites with controlled structures, but there are also some disadvantages to consider.
INTERNATIONAL MATERIALS REVIEWS
(2021)
Article
Materials Science, Ceramics
Raja Aqib, Sarang Kiani, Shaher Bano, Abdul Wadood, Muhammad Atiq Ur Rehman
Summary: This study investigated the surface and biological properties of Ag-Sr-doped mesoporous bioactive glass nanoparticle loaded chitosan/gelatin coatings deposited on 316L stainless steel by electrophoretic deposition. The optimized EPD parameters resulted in homogenous coatings with suitable wettability, adhesion strength, antibacterial properties, and promotion of osteoblast cell proliferation. The coatings also developed HA crystals upon immersion in simulated body fluid. The results confirmed the composite coatings' effectiveness against Escherichia coli cells.
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY
(2021)
Article
Materials Science, Multidisciplinary
Fatih Erdem Bastan, Muhammad Atiq Ur Rehman, Fatih Ustel
Summary: The substitution of Sr in hydroxyapatite alters its lattice structure and thermal properties, reducing thermal stability and increasing crystal volume.
MATERIALS CHEMISTRY AND PHYSICS
(2021)
Article
Materials Science, Multidisciplinary
Qaisar Nawaz, Steffen Fastner, Muhammad Atiq Ur Rehman, Sara Ferraris, Sergio Perero, G. Gautier di Confiengo, Emre Yavuz, Monica Ferraris, Aldo R. Boccaccini
Summary: In this study, multifunctional stratified antibacterial and bioactive coatings were deposited and characterised on stainless steel substrates using electrophoretic deposition (EPD) and radio frequency (RF) co-sputtering techniques. The comparison between the physicomechanical and biological characteristics of different coatings structures showed that the multi-layered coatings exhibited superior antibacterial effects and cell attachment capabilities.
JOURNAL OF MATERIALS SCIENCE
(2021)
Article
Biochemistry & Molecular Biology
Muhammad Maqbool, Qaisar Nawaz, Muhammad Atiq Ur Rehman, Mark Cresswell, Phil Jackson, Katrin Hurle, Rainer Detsch, Wolfgang H. Goldmann, Asma Tufail Shah, Aldo R. Boccaccini
Summary: In this study, selenium and strontium were substituted into hydroxyapatite to enhance the antimicrobial activity of biomaterials. The results showed that the Se-Sr-HA samples exhibited excellent antibacterial properties and the co-substitution of strontium offset the cytotoxic effect of selenium, improving the biological properties of HA. The prepared samples are considered a suitable choice for antibacterial coatings and bone filler applications.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2021)
Article
Automation & Control Systems
Wali Muhammad, Wilayat Husain, Anjum Tauqir, Abdul Wadood, Hamid Zaigham, Muhammad Atiq Ur Rehman
Summary: The study demonstrates that the temper conditions of the base metal have a strong influence on the microstructural morphologies and mechanical behavior of the welded joints. Differences in hardness and fracture locations were observed in the two temper conditions, with all samples fracturing at the retreating side. Scanning electron microscopy fractographic analysis revealed a ductile fracture mode with dimples, the size and shape of which depended on the base metal temper condition.
INTERNATIONAL JOURNAL OF ADVANCED MANUFACTURING TECHNOLOGY
(2021)
Review
Materials Science, Multidisciplinary
Memoona Akhtar, Syed Ahmed Uzair, Muhammad Rizwan, Muhammad Atiq Ur Rehman
Summary: Bioceramic coatings on metallic implants provide wear-resistance and biocompatibility, and can develop bone-like apatite in physiological environments. Radio frequency magnetron sputtering (RFMS) is a technique used to deposit these coatings, with features such as chemical composition stability and excellent surface finish. However, it requires high-temperature operation and annealing. RFMS has the potential to develop multifunctional coatings and has been used in the field of bioceramic coatings.
FRONTIERS IN MATERIALS
(2022)
Article
Automation & Control Systems
Muhammad Atiq Ur Rehman, Syeda Ammara Batool
Summary: This study enhanced the antibacterial behavior and bioactivity of polyetheretherketone (PEEK)-based coating through a multi-layer coating approach. The antibacterial efficiency and in vitro bioactivity of gentamicin sulfate (GS)-loaded chitosan (CS)/gelatin (GT)/bioactive glass (BG) layers on PEEK/BG coatings were investigated. The results showed that the multi-layered coatings had sustained drug release and antibacterial activity, forming an apatite-like layer after immersion in simulated body fluid (SBF). Additionally, the coatings were non-toxic based on in vitro cellular studies.
INTERNATIONAL JOURNAL OF ADVANCED MANUFACTURING TECHNOLOGY
(2022)
Article
Materials Science, Composites
Huma Ozair, Muhammad Atiq Ur Rehman, Abrar H. Baluch, Khurram Yaqoob, Ibrahim Qazi, Abdul Wadood
Summary: This research investigated the impact resistance properties of GFRP with the addition of shape memory wires and stainless-steel wires. The shape-memory-alloy-wires-reinforced GFRP showed the highest impact strength, followed by stainless-steel-wires-reinforced GFRPs and then conventional GFRPs. The smart shape memory wires and stainless-steel-wires-based hybrid composites improved the impact strength by 13% and 4% respectively compared to unreinforced GFRPs.
JOURNAL OF COMPOSITES SCIENCE
(2022)
Review
Chemistry, Physical
Syeda Ammara Batool, Muhammad Salman Salman Maqbool, Muhammad Awais Javed, Akbar Niaz, Muhammad Atiq Ur Rehman
Summary: This review focuses on the process and mechanism of electrochemical anodization of titania nanotubes (TNTs) and highlights their important applications in biomedical devices, water purification, and solar cells.
Article
Polymer Science
Fatima Masood, Muhammad Atif Makhdoom, Iftikhar Ahmed Channa, Sadaf Jamal Gilani, Ahmad Khan, Rabia Hussain, Syeda Ammara Batool, Kiran Konain, Saeed Ur Rahman, Abdul Wadood, May Nasser bin Jumah, Muhammad Atiq Ur Rehman
Summary: The combination of chitosan and chondroitin sulfate was used to synthesize hydrogels enriched with garlic for faster wound healing and resistance to microbial growth. The synthesized hydrogels showed significant antibacterial activity and cytocompatibility, suggesting their potential for wound healing and tissue regeneration.
Article
Engineering, Biomedical
Syeda Ammara Batool, Khalil Ahmad, Muhammad Irfan, Muhammad Atiq Ur Rehman
Summary: In recent years, natural polymers have been increasingly used for antibacterial orthopedic applications due to their biocompatibility and biodegradability. In this study, a zein/Zn-Mn mesoporous bioactive glass nanoparticles (MBGNs) composite coating was deposited on stainless steel using electrophoretic deposition. The optimized parameters resulted in uniform coatings with highly dispersed MBGNs. The composite coatings exhibited good mechanical and chemical stability, as well as excellent antibacterial and bioactive properties.
JOURNAL OF FUNCTIONAL BIOMATERIALS
(2022)
Article
Biotechnology & Applied Microbiology
Syeda Ammara Batool, Ushna Liaquat, Iftikhar Ahmad Channa, Sadaf Jamal Gilani, Muhammad Atif Makhdoom, Muhammad Yasir, Jaweria Ashfaq, May Nasser bin Jumah, Muhammad Atiq Ur Rehman
Summary: Zein/Ag-Sr doped MBGN coatings exhibit good mechanical and biological properties, with the potential to prevent implant corrosion and harmful effects.
BIOENGINEERING-BASEL
(2022)
Review
Materials Science, Biomaterials
Muhammad Awais, Aqsa Aizaz, Arooba Nazneen, Qurat ul Ain Bhatti, Memoona Akhtar, Abdul Wadood, Muhammad Atiq Ur Rehman
Summary: This review focuses on the therapeutic effects of ions released in physiological environments. Recent studies have shown promising results of metallic ions in drug delivery systems and regenerative medicine. These ions can be loaded in various materials and exhibit different functions, such as antibacterial, antiviral, anticancer, bioactive, biocompatible, and angiogenic effects.
Review
Chemistry, Physical
Syeda Ammara Batool, Abdul Wadood, Syed Wilayat Hussain, Muhammad Yasir, Muhammad Atiq Ur Rehman
Summary: Electrophoretic deposition (EPD) is a powerful technique used to assemble various materials into implants with different shapes, and deposit multifunctional coatings. The key characteristics of EPD coatings, including inorganic bioactivity, angiogenic potential, and antibacterial properties, enable their advanced applications in orthopedic field.
Article
Chemistry, Physical
Jhilik Roy, Shubham Roy, Dhananjoy Mondal, Neelanjana Bag, Jaba Roy Chowdhury, Saheli Ghosh, Souravi Bardhan, Rajib Mondal, Ruma Basu, Sukhen Das
Summary: This study presents the synthesis and characterization of a gadolinium-doped bismuth ferrite piezo catalyst for the degradation of carcinogenic organic dyes and eradication of pathogenic bacteria. The piezo catalyst exhibits high polarization and demonstrates exceptional degradation efficiency under soft ultrasound stimulation. It also shows remarkable antibacterial activity and can be easily extracted using a magnetic field, making it a promising candidate for water treatment to prevent secondary pollution.
SURFACES AND INTERFACES
(2024)
Article
Chemistry, Physical
Sanggon Kim, Orisson Gomes, Ali Riaz, Mourad Roudjane, Paulo N. Lisboa-Filho, Augusto Batagin-Neto, Younes Messaddeq, Yves De Koninck
Summary: Surface-enhanced Raman spectroscopy (SERS) is a powerful tool in biophysics, bioanalytical chemistry, and biomedicine for monitoring extracellular chemical activity. However, the limited choice of SERS nanotags has hindered its practical application. This study repurposes fluorescent chemosensors as SERS nanotags, using a plasmon-induced reaction to immobilize them onto plasmonic nanostructures. The results demonstrate the successful immobilization and functionality of xanthene-based chemosensors as SERS chemosensors.
SURFACES AND INTERFACES
(2024)
Article
Chemistry, Physical
A. Fernandez Garcia, M. Garcia-Lechuga, F. Agullo Rueda, J. Rubio Zuazo, M. Manso Silvan
Summary: In this work, a method for fabricating WTe2 thin-films and controlling their conductivity using femtosecond laser post processing is presented. The synthesis of WTe2 films, characterization of their surface conductivity gradient and the demonstration of conductivity modulation using laser writing are described.
SURFACES AND INTERFACES
(2024)
Article
Chemistry, Physical
Zhaoqing Kang, Xin Li, Le Zhou, Dan Li, Jiangping Wang
Summary: Microencapsulated phase change materials (MicroPCMs) with polyethylene wax (PE-W) as nucleating agent were prepared using emulsion polymerization. The addition of PE-W significantly reduced the degree of supercooling and increased the enthalpy associated with heterogeneous nucleation in MicroPCMs. The thermal resistance of the MicroPCMs encapsulated by P(MMA-co-AMA) was greatly improved. The MicroPCMs demonstrated exceptional thermal storage and protective characteristics.
SURFACES AND INTERFACES
(2024)
Article
Chemistry, Physical
Chenliang Li, Kezhen Lv, Xiaomin Ding, Liyang Feng, Xiaolong Lv, Decai Ma
Summary: This study investigates the effect of surface termination composition and disorder on the electronic and contact properties of Janus Ti3C2FO materials, and provides new insight into the tuning of contact properties in MXenes/TMD heterostructures.
SURFACES AND INTERFACES
(2024)
Article
Chemistry, Physical
Asha Rajiv, Aruna Kapse, Varun Kumar Singh, Manender Singh Chauhan, Aishwary Awasthi, Prabhakar Singh
Summary: Surface modification of inorganic metal oxide nanoparticles with organic biopolymers has endowed these particles with multifunctional properties, making them versatile in the field of nanomedicine. In this study, magnesium oxide and chitosan modified magnesium oxide were synthesized using a green method. The antibacterial and anticancer activities of the synthesized hybrid nanomaterial were attributed to the generated reactive oxygen species. Chitosan modified magnesium oxide hybrid nanomaterial demonstrated appreciable efficacy against bacterial strains and showed significant anticancer potential against human breast cancer cells. Cytotoxicity assays on human fibroblast cells revealed high cell viability rates for both magnesium oxide and chitosan modified magnesium oxide hybrid nanomaterial. These findings suggest that chitosan modified magnesium oxide hybrid nanomaterial has promising applications in the biomedical field.
SURFACES AND INTERFACES
(2024)
Article
Chemistry, Physical
Lin Tao, Jingkai Wang, Qiuju Qin, Bingxian Chu, Pin Gao, Jiaqi Qiu, Qin Li, Xuechi Du, Lihui Dong, Bin Li
Summary: This study focuses on the modification of transition metal catalysts for the selective catalytic reduction of NO by CO. It investigates the effect of different anions on the modification of CO-SCR catalysts. The results show that the use of nitrate ions as a regulator for LDH support leads to a high NO conversion rate, surpassing the use of sulfate ions. The study also highlights the importance of anion modulation in controlling the valence state of loaded copper species. In situ DRIFTS analysis reveals the reaction mechanisms at different temperatures. Overall, this work provides new insights for the valence modulation of copper and the modification of LDH materials in CO-SCR applications.
SURFACES AND INTERFACES
(2024)
Article
Chemistry, Physical
Fan Xiao, Ming Cao, Yingbo Chen
Summary: In this study, a continuous and uniform ultra-thin polyamide (PA) membrane, ranging from 10 to 20 nm, was successfully synthesized by utilizing a UiO-66-(OH)2 n-hexane dispersion as a transition layer. The presence of the transition layer improved interface stability and facilitated bidirectional diffusion-contact reaction between the monomers, resulting in superior thinness and uniformity of the PA active layers.
SURFACES AND INTERFACES
(2024)
Article
Chemistry, Physical
Ashwini B. Rohom, Priyanka U. Londhe, Jeong In Han, Nandu B. Chaure
Summary: This study describes the synthesis and characterization of a ternary nanocomposite electrode for supercapacitors. The electrode, made of tin oxide/reduced graphene oxide wrapped with poly (3,4-ethylenedioxythiophene)-poly-(styrenesulfonate), exhibits excellent electrochemical properties and high cycling stability.
SURFACES AND INTERFACES
(2024)
Article
Chemistry, Physical
Jiayao Zhang, Danni Xue, Huan Liu, Zhao Wei, Chenjie Gu, Shuwen Zeng, Junhui Jiang, Tao Jiang, Xingfei Zhou, Kerong Wu
Summary: This study investigates the size-dependent enhancement of charge transfer resonance in semiconductors by adjusting the size of red phosphorus. The nano-sized red phosphorus achieves a three-fold enhancement in surface enhanced Raman scattering (SERS) intensity compared to nanosheets, making it a potential tool for accurate and efficient cancer marker diagnostics.
SURFACES AND INTERFACES
(2024)
Article
Chemistry, Physical
Bouhadjar Boukoussa, Khoukha Rachida Cherdouane, Rajaa Zegai, Adel Mokhtar, Mohammed Hachemaoui, Ismail Issam, Jibran Iqbal, Shashikant P. Patole, Fatima Zohra Zeggai, Rachida Hamacha, Mohamed Abboud
Summary: This work focuses on the preparation of inexpensive composite materials based on activated carbon-containing metallic nanoparticles MNPs (M = Cu, Ag, Fe). Different samples were tested as catalysts for the catalytic reduction of organic pollutants in the presence of NaBH4. The AC-Cu material exhibited good dispersion of CuNPs and showed the highest efficiency among the tested catalysts.
SURFACES AND INTERFACES
(2024)
Article
Chemistry, Physical
Changxing Yang, Guxia Wang, Qingyan Bai, Dan Li, Shengwei Guo
Summary: This study designed a simple and efficient graphene-based nanolubricant, which improved the lubrication performance of steel ball friction pairs through a three-step process. It has potential practical applications in the field of lubrication.
SURFACES AND INTERFACES
(2024)