Article
Energy & Fuels
Minoo Bagheri, Yeganeh Amidi, Mohammad Yaser Masoomi
Summary: In this study, quasi-ZIF-67 (Q-ZIF-67) with large-scale structural defects was synthesized via controlled thermal partial deligandation. Q-ZIF-67 exhibited enhanced catalytic activity for hydrolysis of NaBH4, generating hydrogen at a high rate under mild conditions. Mechanistic studies revealed the importance of strong acidity for efficient hydrogen generation.
Article
Chemistry, Physical
Cafer Saka, Asim Balbay
Summary: For the first time, phosphoric acid and acetic acid catalysts were used for efficient hydrogen production from sodium borohydride ethylene glycolysis reaction. The experimental results showed that the presence of water negatively affects H-2 production. The hydrogen generation rate obtained with H3PO4 and CH3COOH catalysts were 5800 and 4542 mL/min, respectively.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Multidisciplinary
Frances Pope, Jeffrey Jonk, Millie Fowler, Petrus C. M. Laan, Norbert J. Geels, Larissa Drangai, Vitaly Gitis, Gadi Rothenberg
Summary: The safety concern of using large amounts of compressed or liquid hydrogen in a transition to a hydrogen economy can be addressed by using chitosan as a catalyst support. Chitosan spheres encapsulating cobalt catalysts remain stable at high reaction pH, and show high catalytic activity and reusability.
Article
Chemistry, Inorganic & Nuclear
Junchao Han, Wuning Yuan, Menghui Wei, Bo Zhang, Yanhui Guo
Summary: We propose a novel strategy to achieve real-time dynamic tunability of the hydrogen generation rate by depositing catalytic materials on polymer foams through electroless plating. By adjusting the contact area between the magnetic catalyst and the NaBH4 solution, valuable regulation of the H-2 production rate is achieved. This strategy may improve the efficiency of borohydrides hydrolysis and be applied to other liquid-phase hydrogen production systems.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Physical
Yiting Bu, Jiaxi Liu, Dan Cai, Pengru Huang, Sheng Wei, Xiaoshuang Luo, Zhaoyu Liu, Fen Xu, Lixian Sun, Xueying Wei
Summary: A magnetic recyclable hollow shell material H-Co/N/C-Ru@C-T, with carbonized ZIF-67 as a framework and a surface-coated carbon film, showed good catalytic activity and durability in the hydrolysis reaction of NaBH4. It achieved a high hydrogen generation rate of 9815.82 mLH2 min-1 g-1 and a reduced activation energy of 26.9 kJ mol-1. The use of a hollow Co/N/C framework and a carbon film coating improved the catalytic activity and durability of H-Co/N/C-Ru@C-650. This work is significant for exploring novel hydrogen storage material catalysts and improving the performance of catalysts.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Yu-Jin Lee, Arash Badakhsh, Dongsu Min, Young Suk Jo, Hyuntae Sohn, Chang Won Yoon, Hyangsoo Jeong, Yongmin Kim, Kwang-Bum Kim, Suk Woo Nam
Summary: By incorporating aluminum and utilizing pulsed chronoamperometric electrodeposition, structured cobalt-nickel catalysts were prepared, showing 1.5 times higher catalytic activity compared to porous nickel foam, with only 0.57 wt% cobalt content. The structured cobalt-nickel catalyst exhibited higher stability than the porous nickel foam even after an accelerated durability test.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Physical
Hongming Zhang, Lu Zhang, Ismael A. Rodriguez-Perez, Wenkang Miao, Kangli Chen, Wenfeng Wang, Yuan Li, Shumin Han
Summary: A highly efficient catalyst composed of carbon nanospheres supporting ultrafine bimetallic Pt-Co nanoparticles was successfully synthesized for hydrogen evolution from NaBH4 hydrolysis in this study. The catalyst exhibited outstanding performance in kinetic and thermodynamic tests, with high hydrogen generation rate and low activation energy. The hydrolytic mechanism was investigated using isotopic tracer method and mass spectrometric analysis, showing that the catalyst maintained high catalytic activity even after five cycles of performance tests.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Physical
O. V. Netskina, E. S. Tayban, V. A. Rogov, A. M. Ozerova, S. A. Mukha, V. I. Simagina, O. V. Komova
Summary: In the study, it was found that cobalt catalysts are more active than nickel catalysts in the hydrolysis of sodium borohydride. One reason for the lower activity of nickel catalysts is the presence of hydrogen on its surface, which interferes with reactant adsorption. The addition of cobalt to nickel catalysts can enhance hydrogen generation rate.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Energy & Fuels
Cafer Saka
Summary: Heterojunction catalysts have better catalytic effects compared to single-component catalysts in the field of catalytic reactions. In this study, a metal-free catalyst g-C3N4-TiO2-P was synthesized through a three-step process and used for efficient hydrogen release from NaBH4 methanolysis. The catalyst exhibited good activity and reusability, and the mechanism of H2 production was explored.
Article
Chemistry, Inorganic & Nuclear
Umme Thahira Khatoon, Aditya Velidandi, G. V. S. Nageswara Rao
Summary: Copper oxide nanoparticles were synthesized using oxalic acid, sodium borohydride, and tri-sodium citrate as both reducing and stabilizing agents. Different concentrations of metal precursor and reducing agent were tested. The synthesized nanoparticles showed maximum absorbance in the range of 200 nm to 450 nm. XRD and EDX confirmed the synthesis of CuO NPs. S-CuO NPs exhibited the best particle size and surface charge, as well as the highest antibacterial activity against various bacteria.
INORGANIC CHEMISTRY COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Maria Alaide de Oliveira, Elibe Silva Souza, Jildimara de Jesus Santana, Natalia Lukasik, Barbara Stefany Lima da Silva, Braulio Silva Barros, Joanna Kulesza
Summary: Mono- (Co-BDC, Fe-BDC) and bimetallic FeCo-BDC Metal-Organic Frameworks were synthesized via solvothermal method and utilized as catalysts for sodium borohydride hydrolysis. Among them, Co-BDC exhibited the most promising performance with a hydrogen generation rate of 1886.8 mL min(-1) g(cat)(-1) and high efficiency of 77.7% at 319 K under basic conditions. It also had a lower activation energy of 25.4 kJ mol(-1) compared to most cobalt-bearing catalysts reported in literature. The catalyst showed good reusability for at least ten cycles, making it a potential candidate for portable hydrogen fuel systems.
APPLIED SURFACE SCIENCE
(2023)
Article
Materials Science, Multidisciplinary
Yan Wang, Jian Ren, Jiaxin Ma, Fengyan Xu, Ke Zhang, Qiuju Sun, Zhongqiu Cao, Guode Li, Shiwei Wu
Summary: Co-Fe-B@g-C3N4/Cu sheet was successfully prepared via chemical deposition process. The optimized weight of g-C3N4, 0.005 g, resulted in a catalyst with unique surface structure that exhibited improved catalytic performance in the hydrolysis of NaBH4 solution. Under visible light irradiation, a HGR of 8343 mL•min-1•g-1 and Ea of 48.4 kJ•mol-1 were achieved, surpassing most reported non-precious metal and precious metal catalysts. This work offers a viable method for manufacturing non-noble metal catalysts with high catalytic properties in the hydrolysis of NaBH4 solution.
Article
Energy & Fuels
Orhan Baytar, Omer Sahin, Arzu Ekinci
Summary: This study prepared hydrochars from pine cones and rheum ribes shells through the hydrothermal method and used them as catalysts in the hydrolysis of sodium borohydride. The synthesized catalyst hydrochars were characterized by various techniques. The results showed that the hydrochars from pine cones and rheum ribes shells had both amorphous and crystalline structures. The BET surface areas of the two hydrochars were determined to be 1.6 m2/g and 19.01 m2/g, respectively. The hydrolysis kinetics of sodium borohydride in the presence of these hydrochars were investigated.
Review
Chemistry, Physical
Dongyan Xu, Yan Zhang, Qingjie Guo
Summary: This review summarizes recent advances in metallic and nonmetallic catalysts for the alcoholysis of NaBH4, discusses the advantages and disadvantages of various catalysts, and explores the catalytic mechanisms related to NaBH4 methanolysis.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Multidisciplinary Sciences
Irshad Begum, Fuad Ameen, Zahid Soomro, Sana Shamim, Saleh AlNadhari, A. Almansob, Ahmed Al-Sabri, Afsheen Arif
Summary: The successful management of infections caused by human pathogenic bacteria is becoming a challenge for clinicians. New strategies to circumvent pathogen growth need to be developed. The synthesized silver nanoparticles (AgNPs) with malonic acid (MA) capping agent showed promising antibacterial activity against human bacterial pathogens, suggesting their potential application in controlling bacterial infections in clinical settings and further biomedical applications.
JOURNAL OF KING SAUD UNIVERSITY SCIENCE
(2021)
Article
Materials Science, Multidisciplinary
Qingfeng Zhang, Tingfeng Xia, Qihan Zhang, Yucao Zhu, Huanzhi Zhang, Fen Xu, Lixian Sun, Xiaodong Wang, Yongpeng Xia, Xiangcheng Lin, Hongliang Peng, Pengru Huang, Yongjin Zou, Hailiang Chu, Bin Li
Summary: A novel composite phase-change material was developed by encapsulating polyethylene glycol in a functional form stable composite carbon aerogel structure. The composite phase-change material exhibited good structure stability, comprehensive energy storage performance, and enhanced thermal response rate. This strategy can be efficiently used to develop novel composite phase-change materials with improved comprehensive thermal performance and high light-thermal conversion.
ENERGY & ENVIRONMENTAL MATERIALS
(2023)
Article
Chemistry, Physical
Zhaoyu Liu, Jiaxi Liu, Sheng Wei, Yongpeng Xia, Riguang Cheng, Lixian Sun, Fen Xu, Pengru Huang, Yiting Bu, Jian Cheng, Tianhao Zhou, Hongge Pan, Zhong Cao, Julan Zeng, Hans Jurgen Seifert, Shuhui Sun, Gaixia Zhang
Summary: In this study, Ni/C nanoparticles anchored on Ti3C2Tx nanosheets were introduced into LiAlH4 to investigate its catalytic effect. It was found that the Ni/C@Ti3C2 composite can effectively catalyze the dehydrogenation and rehydrogenation reactions of LiAlH4, lowering the activation energy and improving the hydrogen adsorption and release kinetics.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Xianyong Hong, Mingzhu Xia, Mingxing Shi, Chun Liu, Yanghao Yan, Yu Tao, Yongqiang Zhang, Yulei Zhang, Ping Du, Fengyun Wang
Summary: The role of functional groups in the adsorption process of functionalized layered double hydroxide (LDH) to target pollutants was investigated. Functionalized NiFe-LDH with 2 mercaptoethane sulfonic acid (MS) as an intercalation modifier was prepared. Molecular dynamics simulation revealed the interfacial interaction between the functional groups and the NiFe-LDH surface. The results showed that the sulfonic acid group self-assembled electrostatically with the LDH laminate, while the sulfhydryl group complexed heavy metal ions. The adsorption experiments demonstrated significantly improved adsorption performance of the modified NiFe-LDH for Cd2+, Mn2+, and Co2+ ions. The molecular dynamics simulation and wavefunction analysis provided insights into the mechanism of enhanced adsorption capacity by the functional groups.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Nanoscience & Nanotechnology
Qijiang Shu, Pengru Huang, Xicheng Zhang, Linjing Yang, Donghai Ye, Li Yang, Hongxing Liu, Lei Chen
Summary: The authors prepared multilayered Si-based Ge quantum dots (Ge/Si QDs) using the magnetron sputtering technique and investigated their morphology evolution through AFM, SEM, XPS, Raman, and XRD tests. They found that increased temperature improved the crystallinity of the Si-isolated layer and enhanced the density, size, and uniformity of top-layer QDs. The study revealed different phenomena and laws regarding the morphology and vertical correlation between the layers of QDs at different temperatures.
MICRO & NANO LETTERS
(2023)
Article
Biochemistry & Molecular Biology
Sergey P. Verevkin, Dzmitry H. Zaitsau, Ralf Ludwig
Summary: In this study, we measured the enthalpies of vaporisation for a set of molecular and ionic liquids using modern techniques for vapour pressure measurements. We were able to avoid the decomposition problem at high temperatures by using the quartz crystal microbalance, thermogravimetric analysis, and gas chromatographic methods. By applying group contribution methods for molecular liquids and the centerpiece method for ionic liquids, we were able to analyse the enthalpies of vaporisation and understand different types of molecular interaction in the liquid phase.
Article
Engineering, Chemical
Yanghao Yan, Yeming Zhao, Chunxiang Gong, Yu Tao, Keren Lu, Xianyong Hong, Mingzhu Xia, Fengyun Wang
Summary: A novel phosphate adsorbent UNM has been successfully synthesized and its adsorption behavior and mechanism have been explored. The results demonstrate that UNM exhibits high removal efficiency in environmental water samples and shows good reusability and chemical stability.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Sergey P. P. Verevkin, Artemiy A. A. Samarov, Vladimir V. V. Turovtsev, Sergey V. V. Vostrikov, Peter Wasserscheid, Karsten Mueller
Summary: This study investigates the use of homocyclic aromatics with different degrees of alkylation as Liquid Organic Hydrogen Carriers (LOHC). The presence of multiple alkyl groups in crowded alkylated aromatics suggests their potential as efficient LOHCs, but existing data does not show a clear trend. The aim of this study is to provide a consistent and comprehensive data set to evaluate the benefits of multi-alkylation. The results reveal that the positive effect on enthalpy of reaction for dehydrogenation is weak, indicating that crowded alkylbenzenes may not significantly decrease the temperature for hydrogen release.
APPLIED SCIENCES-BASEL
(2023)
Article
Green & Sustainable Science & Technology
Qiuhong Wei, Jiaxi Liu, Shujun Qiu, Yongpeng Xia, Yongjin Zou, Fen Xu, Xin Wen, Pengru Huang, Lixian Sun, Hailiang Chu
Summary: The synthesis of Ru-Ni nanoclusters stabilized on reduced graphene oxide through in situ chemical reduction is reported. The optimized catalyst exhibits excellent catalytic performance for the hydrolysis of ammonia-borane and shows good recyclability.
ADVANCED SUSTAINABLE SYSTEMS
(2023)
Article
Chemistry, Physical
Yiting Bu, Jiaxi Liu, Dan Cai, Pengru Huang, Sheng Wei, Xiaoshuang Luo, Zhaoyu Liu, Fen Xu, Lixian Sun, Xueying Wei
Summary: A magnetic recyclable hollow shell material H-Co/N/C-Ru@C-T, with carbonized ZIF-67 as a framework and a surface-coated carbon film, showed good catalytic activity and durability in the hydrolysis reaction of NaBH4. It achieved a high hydrogen generation rate of 9815.82 mLH2 min-1 g-1 and a reduced activation energy of 26.9 kJ mol-1. The use of a hollow Co/N/C framework and a carbon film coating improved the catalytic activity and durability of H-Co/N/C-Ru@C-650. This work is significant for exploring novel hydrogen storage material catalysts and improving the performance of catalysts.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Multidisciplinary
Danis I. Badrtdinov, Carlos Rodriguez-Fernandez, Magdalena Grzeszczyk, Zhizhan Qiu, Kristina Vaklinova, Pengru Huang, Alexander Hampel, Kenji Watanabe, Takashi Taniguchi, Lu Jiong, Marek Potemski, Cyrus E. Dreyer, Maciej Koperski, Malte Rosner
Summary: A key advantage of utilizing van-der-Waals (vdW) materials as defect-hosting platforms for quantum applications is the controllable proximity of the defect to the surface or the substrate, which allows for improved light extraction, enhanced coupling with photonic elements, or more sensitive metrology. However, this also poses a challenge for defect identification and characterization due to the influence of the atomic environment on the defect's properties. This study explores how the environment influences the properties of carbon impurity centers in hexagonal boron nitride (hBN) and demonstrates the dominant effect of the change in the environment on the screening of density-density Coulomb interactions between the defect orbitals.
Article
Chemistry, Physical
Sergey V. Vostrikov, Artemiy A. Samarov, Vladimir V. Turovtsev, Peter Wasserscheid, Karsten Mueller, Sergey P. Verevkin
Summary: Liquid organic hydrogen carriers can safely and densely store hydrogen using covalent bonds. Catalytic hydrogenation and dehydrogenation enable the uptake and release of hydrogen. Indoles have been investigated as potential candidates for this purpose. The enthalpy of reaction plays a crucial role by determining the heat demand for hydrogen release and the reaction equilibrium. This study combines experimental measurements, quantum chemical methods, and a group-additivity approach to obtain a consistent dataset on the formation enthalpies of various methylated indole derivatives and their hydrogenated forms. The results indicate a significant influence of the number and position of methyl groups on the enthalpy of reaction. The enthalpy of the overall hydrogenation reaction varies up to 18.2 kJ.mol(-1) (equivalent to 4.6 kJ.mol(-1)(H-2)(-1)). The highest range of enthalpy of reaction data is observed for the hydrogenation of the last double bond in the five-membered ring of different methyl indoles, with a difference of up to 7.3 kJ.mol(-1)(H-2)(-1) between the highest and lowest values.
Article
Chemistry, Multidisciplinary
Sergey P. P. Verevkin, Aleksandra A. A. Zhabina
Summary: This paper determines the vapor pressures and combustion energies of ethylene glycol (EG) derivatives, such as mono- and di-tert-butyl ethers, to obtain their vaporization enthalpies and enthalpies of formation. The reliable thermodynamics of ether synthesis reactions were discovered using methods based on the First and Second Law of Thermodynamics. The thermochemical data for ethylene glycol tert-butyl ethers were validated using structure-property correlations and quantum chemical calculations.
CHEMISTRY-SWITZERLAND
(2023)
Article
Chemistry, Multidisciplinary
Siyue Hui, Rong Ji, Huanzhi Zhang, Chaowei Huang, Fen Xu, Lixian Sun, Yongpeng Xia, Xiangcheng Lin, Lei Ma, Hongliang Peng, Bin Li, Yazhen Wang, Erhu Yan, Pengru Huang
Summary: The rapid development of industry has highlighted the importance of phase change materials (PCMs) with high latent-heat storage capacity and good thermal stability for sustainable energy solutions. However, the low thermal conductivity and poor thermal-cycling stability of PCMs have limited their applications. In this study, a three-dimensional (3D) hybrid graphene aerogel (GBA) was constructed by synergistic assembly and cross-linking between graphene oxide (GO) and modified hexagonal boron nitride (h-BN). The GBA, with high thermal conductivity, was used as the supporting matrix for encapsulating n-octadecane (OD), resulting in composite phase change materials (PCMs) with improved thermal properties.
Article
Chemistry, Physical
Nikita Kazeev, Abdalaziz Rashid Al-Maeeni, Ignat Romanov, Maxim Faleev, Ruslan Lukin, Alexander Tormasov, A. H. Castro Neto, Kostya S. Novoselov, Pengru Huang, Andrey Ustyuzhanin
Summary: Two-dimensional materials offer a promising platform for next-generation electronic devices and high-tech applications. We propose a machine learning approach to estimate the properties of 2D materials based on their lattice structure and defect configuration, allowing for rapid tuning of material properties. Our methodology outperforms state-of-the-art approaches in terms of energy prediction accuracy and resource efficiency.
NPJ COMPUTATIONAL MATERIALS
(2023)
Article
Engineering, Environmental
Mingxing Shi, Xianyong Hong, Chun Liu, Hua Qiang, Fengyun Wang, Mingzhu Xia
Summary: This study develops a green double organic salt activation strategy for fabricating high-performance CDI desalination using lotus stem. The resulting 3DNHPC exhibits a suitable porous structure and abundant surface active sites, showing excellent salt removal capability and adsorption capacity, as well as maintaining high stability.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Orkun Furat, Donal P. Finegan, Zhenzhen Yang, Matthias Neumann, Sangwook Kim, Tanvir R. Tanim, Peter Weddle, Kandler Smith, Volker Schmidt
Summary: The operating temperature has a significant impact on the degradation behavior of batteries. This study investigates the structural degradation of lithium-ion positive electrodes under different operating temperatures, and finds that particle porosity increases with higher cycling temperature, while particle surface area remains similar across different cycling-temperature aging conditions.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Junyan Li, Ming Lu, Weijia Zheng, Wei Zhang
Summary: MXenes are two-dimensional materials with unique structures and properties, which have attracted significant scientific interest. Ion intercalation, as an important mechanism, plays a crucial role in regulating the electronic and chemical properties of MXene materials. This review provides an overview of the interaction events between ions and MXenes, including advanced characterization techniques, influencing factors, mechanisms, and functionalization roles of ion intercalation.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Zhengtai Zha, Tianjiang Sun, Diantao Li, Tao Ma, Weijia Zhang, Zhanliang Tao
Summary: A novel zwitterion additive is developed to improve the electrochemical performance and cycling stability of aqueous zinc batteries. The zwitterion forms a stable solid electrolyte interphase on the electrode surface, isolating the zinc anode from the electrolytes and enabling fast zinc ion migration. The proposed electrolyte shows promising results in symmetric cells and full cells, with long cycling stability and high capacity retention.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Nyung Joo Kong, Myeong Seon Kim, Jae Hyun Park, Jongbok Kim, Jungho Jin, Hyun-Wook Lee, Seok Ju Kang
Summary: Polymeric conducting binders have significant research value as they can serve as both binders and conducting agents, increasing the proportion of active materials in batteries and the volumetric energy density. This study explores the potential of a composite of PEDOT:PSS and polyethylene glycol (PEG) as a high-performing binder for silicon anodes. The addition of PEG polymer enhances the conductivity of PEDOT:PSS and improves the mechanical properties of the silicon anode, resulting in extended cycle endurance. The use of operando optical microscopy allows for direct observation of the binder's operation. Consequently, the bifunctional PEDOT:PSS/PEG binder shows promise for high-performance lithium-ion battery binders.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Yangze Huang, Lixuan Zhang, Jiawen Ji, Chenyang Cai, Yu Fu
Summary: This study proposed a novel temperature-dependent viscoelastic liquid electrolyte and a hollow transition bi-metal selenide as the sulfur host material to address the issues in Li-S batteries. The experiments showed promising results in stabilizing the anode and improving cycling performance.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Ao Yu, Wei Zhang, Nimanyu Joshi, Yang Yang
Summary: This review provides a comprehensive overview of research progress in ZIB anodes, including protective coating layers on zinc surfaces and intercalated anode materials. By designing protective coating layers and selecting appropriate intercalated anode materials, the inherent limitations of zinc metal anode can be overcome, leading to improved reliability and performance of ZIBs.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Xin Wang, Yumiao Tian, Konghua Yang, Chenhui Ma, Wenqiang Lu, Xiaofei Bian, Nan Chen, Heng Jiang, Yan Li, Xing Meng, Pengyue Gao, Dong Zhang, Fei Du
Summary: Researchers developed a new sandwich deposition approach using boron nitride layer as a current collector, which enhances the performance of aqueous zinc-ion batteries.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Sang Jun Lee, Dongwoo Kang, Dong Yeol Hyeon, Dong Seok Kim, Suyoon Eom, Su Hwan Jeong, Dong Park Lee, Dawon Baek, Jou-Hyeon Ahn, Gyeong Hee Ryu, Kwi-Il Park, San Moon, Joo-Hyung Kim
Summary: This study utilizes the ice-templating method to create a self-supporting three-dimensional hierarchical porous structure, which effectively inhibits sodium dendrite growth and improves the performance and longevity of sodium-metal batteries.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Yifan Yu, Meng Lei, Yangyang Liu, Keyi Chen, Chuanzhong Lai, Jiulin Hu, Chilin Li
Summary: Metal fluorides as conversion-reaction cathodes have advantages such as low cost, environmentally friendly, and high energy density. In this study, a hydroxyl-rich copper fluoride (Cu2(OH)3F) was proposed as a conversion cathode, coupled with an electrolyte additive engineering, to address the poor reversibility issue. The presence of OH in Cu2(OH)3F enables effective suppression of Cu+ dissolution, resulting in better reaction reversibility and kinetics.
ENERGY STORAGE MATERIALS
(2024)