4.6 Article

Enhanced visible light photochemical activity and stability of MoS2/Cu2O nanocomposites by tunable heterojunction

期刊

MATERIALS TODAY COMMUNICATIONS
卷 23, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.mtcomm.2020.100933

关键词

Photocatalyst; MoS2/Cu2O nanocomposites; Tunable heterojunction; Photochemical activity; Stability

资金

  1. National Natural Science Foundation of China [61674113, 51622507, 61471255]
  2. Natural Science Foundation of Shanxi Province, China [2016011040]
  3. Scientific and Technologial Innovation Programs of Higher Education Institutions in Shanxi Province, China [2016138]

向作者/读者索取更多资源

Here we report the hydrothermal synthesis of MoS2/Cu2O nanocomposites with tunable heterojunction for enhancing visible light photochemical activity and stability. The conduction and valence band positions of few-layers MoS2 have been tuned to optimize photo-induced charge separation efficiency by regulating the layer thickness of MoS2. The photochemical activity and stability of MoS2/Cu2O nanoparticles are demonstrated by visible light assisted degradation of methyl orange. Among all of the samples, the MoS2/Cu2O nanocomposite assembled with 6000 rpm centrifuged MoS2 has the highest degradation efficiency of 95.8 % after 3 h of visible light illumination, due to the high visible light absorption and optimized electron-hole separation by the tunable heterojunction design. The influence of MoS2 mass ratio was further investigated. At last, for better understanding of the enhanced photochemical activity, a novel charge separation mechanism is proposed based on the band alignment and build-in electric field between Cu2O and MoS2.

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