Synthesis and magnetic properties of chromium doped cobalt ferrite nanotubes

Chromium (Cr) doped cobalt ferrite (Co1-xCrxFe2O4:x = 0.0, 0.02, 0.04, 0.06, 0.08, 0.1, denoted as to CCFO) hollow nanotubes were synthesized by electrospinnig method followed by, calcining treatment at 700 degrees C in air. The samples exhibited a single phase cubic spinel phase. The lattice constant of the samples was found to initially decreased and thereafter increases with increased of Cr content. The morphology analysis indicated that the samples displayed a disordered arrangements of hollow structures and the relevant surfaces were rough and porous. Transmission electron microscopy (TEM) paragraph confirmed that the doped CCFO nanotubes had a polycrystalline nature and exhibited the changes in the corresponding crystal structure. X-ray photoelectron spectroscopy (XPS) confirmed that Cr doping affect the crystal structure and atomic-binding energy. The analysis of magnetic hysteresis loop indicated an obvious reduction in the saturation magnetization (Ms) of cobalt ferrite with increasing in Cr substitution. The remanent magnetization (Mr) and coercivity were increased at first and then decreased with increasing of Cr content, which was elucidated by the surface effect and magnetic moment direction. The switching field distribution analysis indicated the magnetically crystal soft phase and there were multiple-step processes to reach magnetic reversal.