期刊
CATALYSTS
卷 10, 期 8, 页码 -出版社
MDPI
DOI: 10.3390/catal10080873
关键词
CaO poisoning; Mn-Ce; AC catalyst; low-temperature SCR; less MnO2
资金
- National Natural Science Foundation of China [51874058]
- Fund of Chongqing Science and Technology [CQYC201905017, cstc2019jscx-msxmX0215]
In this study, the poisoning effect of CaO on activated carbon (AC)-based Mn-Ce catalysts was discussed. Loading CaO inhibited the catalytic activity of the catalyst and the NO conversion of the catalyst decreased from 69.5% to 38.2% at 75 degrees C. The amount of MnO(2)in AC surface decreased in the process of loading CaO, which was detrimental to the Selective Catalytic Reduction (SCR) performance of the catalyst. The change of manganese oxide form inhibited generation rate for the chemisorption oxygen and NO2, which was the most critical reason for the decrease of catalytic activity. Besides, loaded CaO entered into the pores of the catalyst, which led to the blockage of the pores and further resulted in the decrease of the Brunauer-Emmett-Teller (BET) surface area and total pore volume. It also destroyed the oxygen-containing functional groups and acid site on the surface of AC. All of these caused the deactivation of Mn-Ce/AC catalyst after loading CaO.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据