4.4 Article

Electrochemical nanostructuring of (111) oriented GaAs crystals: from porous structures to nanowires

期刊

BEILSTEIN JOURNAL OF NANOTECHNOLOGY
卷 11, 期 -, 页码 966-975

出版社

BEILSTEIN-INSTITUT
DOI: 10.3762/bjnano.11.81

关键词

anodization; crystallographically oriented pores; gallium arsenide (GaAs); nanowires; neutral electrolyte; photocurrent; porous GaAs

资金

  1. Alexander von Humboldt Foundation
  2. Ministry of Education, Culture and Research of Moldova [20.80009.5007.20, 19.80013.50.07.03A/BL]
  3. European Commission [810652]

向作者/读者索取更多资源

A comparative study of the anodization processes occurring at the GaAs(111)A and GaAs(111)B surfaces exposed to electrochemical etching in neutral NaCl and acidic HNO3 aqueous electrolytes is performed in galvanostatic and potentiostatic anodization modes. Anodization in NaCl electrolytes was found to result in the formation of porous structures with porosity controlled either by current under the galvanostatic anodization, or by the potential under the potentiostatic anodization. Possibilities to produce multi-layer porous structures are demonstrated. At the same time, one-step anodization in a HNO3 electrolyte is shown to lead to the formation of GaAs triangular shape nanowires with high aspect ratio (400 nm in diameter and 100 mu m in length). The new data are compared to those previously obtained through anodizing GaAs(100) wafers in alkaline KOH electrolyte. An IR photodetector based on the GaAs nanowires is demonstrated.

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