期刊
ORGANIC LETTERS
卷 22, 期 14, 页码 5423-5428出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01783
关键词
-
资金
- Fonds der Chemischen Industrie
- King Abdullah University of Science and Technology (KAUST), Saudi Arabia, Office of Sponsored Research [FCC/1/1974]
A highly selective hydrogenation of alkynes using an air-stable and readily available manganese catalyst has been achieved. The reaction proceeds under mild reaction conditions and tolerates various functional groups, resulting in (Z)-alkenes and allylic alcohols in high yields. Mechanistic experiments suggest that the reaction proceeds via a bifunctional activation involving metal-ligand cooperativity.
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