4.7 Article

Environmental and economical assessment for a sustainable Zn/air battery

期刊

CHEMOSPHERE
卷 250, 期 -, 页码 -

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.chemosphere.2020.126273

关键词

Energy storage; Zn/air battery; Life cycle assessment; Environmental impact

资金

  1. Ministerio de Ciencia, Innovacion y Universidades AEI/FEDER/UE (Spain), EU Feder funds [ENE2016-79282-C5-5-R, CTQ2017-90659-REDT, MAT2015-65274-R]
  2. Fundacion Seneca (Spain), EU Feder funds [19882-GERM-15, 20985/PI/18]
  3. F. Seneca [19768/FPI/15]

向作者/读者索取更多资源

Metal/Air batteries are being developed and soon could become competitive with other battery technologies already in the market, such as Li-ion battery. The main problem to be addressed is the cyclability, although some progress has been recently achieved. A Life Cycle Assessment (LCA) of the manufacturing process of a Zn/Air battery is presented in this article, including raw extraction and process of materials and battery assembly at laboratory scale (cradle to gate approach). The results indicate that Zn/Air battery can be fabricated with low environmental impacts in most categories and only four deserve attention (still being low impacts), such as Human Toxicity (cancer and non-cancer), Freshwater Ecotoxicity and Resource Depletion (the later one depending mainly on Zn use, which is not a critical material, but has a strong impact on this category). Cathode fabrication arises as the sub-assembly with higher impacts, followed by membrane, then anode and finally electrolyte. An economic cost calculation indicates that if cyclability of Zn/Air batteries is achieved, they can become competitive with other technologies already in the market. (C) 2020 Elsevier Ltd. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Editorial Material Green & Sustainable Science & Technology

Hydration as a solution to zinc batteries

Florencio Santos, Antonio J. Fernandez Romero

NATURE SUSTAINABILITY (2022)

Article Energy & Fuels

Accurate thermal prediction model for building-integrated photovoltaics systems using guided artificial intelligence algorithms

L. Serrano-Lujan, C. Toledo, J. M. Colmenar, J. Abad, A. Urbina

Summary: This article presents an artificial intelligence-based approach for predicting the temperature of a photovoltaic module by considering both indoor and outdoor environmental factors. The results demonstrate the high accuracy of this method under different weather conditions.

APPLIED ENERGY (2022)

Article Food Science & Technology

Short vs. Long-Distance Avocado Supply Chains: Life Cycle Assessment Impact Associated to Transport and Effect of Fruit Origin and Supply Conditions Chain on Primary and Secondary Metabolites

Romina Pedreschi, Excequel Ponce, Ignacia Hernandez, Claudia Fuentealba, Antonio Urbina, Jose J. Gonzalez-Fernandez, Jose I. Hormaza, David Campos, Rosana Chirinos, Encarna Aguayo

Summary: Consumption and trade of avocados are increasing globally, with Europe relying heavily on imports from Chile and Peru due to limited domestic production in Spain. Long-distance transport does not significantly affect the nutritional and functional compounds of avocados, as long as proper transportation conditions are maintained.
Article Energy & Fuels

Sustainability of photovoltaic technologies in future net-zero emissions scenarios

Antonio Urbina

Summary: This article analyzes the sustainability of the massive deployment of photovoltaic modules. Through a literature review and their own research, the authors conducted a life cycle assessment (LCA) of different photovoltaic technologies and compared their environmental impacts to other electricity production methods. The results show that solar electricity has lower environmental impacts than fossil fuel electricity. The article also discusses the potential risks arising from mineral scarcity for certain photovoltaic technologies. The authors emphasize the importance of investing in recycling to improve the recovery ratio of minerals and components from PV module waste.

PROGRESS IN PHOTOVOLTAICS (2022)

Article Energy & Fuels

Enovoltaics: Symbiotic integration of photovoltaics in vineyards

Javier Padilla, Carlos Toledo, Jose Abad

Summary: In this study, the symbiotic integration of photovoltaic systems into vineyard structures is proposed to reduce land intervention and costs, while minimizing the impact on crop production and quality. By analyzing shading patterns and PV energy generation using simulation and geographical information system data, grape trellises are identified as suitable for this concept. Vertical integration of PV surfaces over the vines allows for complete irradiation and minimal shadowing. Different module configurations have been evaluated, resulting in a range of installable capacity and confirming the viability of this agrivoltaic solution.

FRONTIERS IN ENERGY RESEARCH (2022)

Article Chemistry, Multidisciplinary

Bifunctional P-Containing RuO2 Catalysts Prepared from Surplus Ru Co-Ordination Complexes and Applied to Zn/Air Batteries

Sebastian Lorca, Javier Torres, Jose L. Serrano, Jose Perez, Jose Abad, Florencio Santos, Antonio J. Fernandez Romero

Summary: A synthetic route involving thermal treatment of Ru co-ordination complexes was used to prepare RuO2-based materials with catalytic activity for ORR and OER reactions. Characterization confirmed the presence of Ru metal and RuP3O9 in the materials, with improved electrocatalytic performance obtained from calcinated RuCl2(PPh3)3. The catalysts were tested in all-solid and flooded alkaline Zn/air batteries, showing high specific discharge capacity and power density.

NANOMATERIALS (2023)

Article Electrochemistry

Importance of Continuous and Simultaneous Monitoring of Both Electrode Voltages during Discharge/Charge Battery Tests: Application to Zn-Based Batteries

Sebastian Lorca, Florencio Santos, Javier Padilla, J. J. Lopez Cascales, Antonio J. Fernandez Romero

Summary: This study tests and analyzes two different Zn-based batteries, demonstrating the advantages of using a three-electrode cell system compared to the traditional two-electrode system. The three-electrode cell allows for real-time monitoring of unexpected events during battery tests and enables immediate action. Additionally, Spectroscopic Impedance measurements are applied to analyze a specific case of the Zn/Bi2O3 battery.

BATTERIES-BASEL (2022)

Article Chemistry, Physical

Graphene Oxide: Key to Efficient Charge Extraction and Suppression of Polaronic Transport in Hybrids with Poly (3-hexylthiophene) Nanoparticles

Eduardo Colom, Javier Hernandez-Ferrer, Alejandro Galan-Gonzalez, Alejandro Anson-Casaos, Mario Navarro-Rodriguez, Elisa Palacios-Lidon, Jaime Colchero, Javier Padilla, Antonio Urbina, Raul Arenal, Ana M. Benito, Wolfgang K. Maser

Summary: Nanoparticles of conjugated polymers in contact with graphene oxide sheets were prepared using a miniemulsion synthesis approach. This led to a unique conformation of the polymer chains and an unprecedented charge transfer between the two constituents. The resulting nanohybrid enabled direct and efficient charge extraction through the graphene oxide sheets.

CHEMISTRY OF MATERIALS (2023)

Article Energy & Fuels

Human Hemoglobin-Based Zinc-Air Battery in a Neutral Electrolyte

Valentin Garcia-Caballero, Sebastian Lorca, Marta Villa-Moreno, Alvaro Caballero, Juan J. Giner-Casares, Antonio J. Fernandez-Romero, Manuel Cano

Summary: This study investigates the use of human hemoglobin (Hb) as a catalytic component in the air electrode of a primary zinc-air battery. Three different electrode modifications using Hb and Nafion were tested, and the Hb-Nafion modified electrode showed the best performance and long-term stability for oxygen electroreduction (ORR). The Hb-Nafion-based air electrode also provided higher specific capacity and discharge time compared to the Nafion-Hb modification.

ENERGY & FUELS (2023)

Article Chemistry, Analytical

FeN4 active sites generated on dipyridylpyridazine functionalized reduced graphene oxide for high-performance air electrode in a Zn-air battery

Juan Amaro-Gahete, Valentin Garcia-Caballero, Almudena Benitez, Dolores G. Gil-Gavilan, Raul Rojas-Luna, Dolores Esquivel, Antonio J. Fernandez-Romero, Manuel Cano, Juan J. Giner-Casares, Francisco J. Romero-Salguero

Summary: The growing global electricity demand requires the development of cost-effective energy conversion and storage systems with inexpensive, eco-friendly, and high-efficiency catalysts. This study focuses on the oxygen reduction reaction (ORR), which is crucial for high-power density fuel cells and Zn-air batteries. The researchers have successfully developed a non-noble iron-nitrogen-carbon catalyst with excellent activity for ORR processes, providing a potential alternative to the expensive commercial Pt-C catalysts. The catalyst showed promising performance as an electrode in a flooded ZAB, outperforming the benchmark Pt-C electrocatalyst.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2023)

Article Chemistry, Analytical

Compact Wideband Groove Gap Waveguide Bandpass Filters Manufactured with 3D Printing and CNC Milling Techniques

Clara Maximo-Gutierrez, Juan Hinojosa, Jose Abad-Lopez, Antonio Urbina-Yeregui, Alejandro Alvarez-Melcon

Summary: This paper presents a compact wideband bandpass filter using groove gap waveguide (GGW) technology. The structure includes metallic pins along the GGW bottom plate and achieves a bandpass response by combining the high-pass characteristic of GGW and the low-pass behavior of the metallic pins. The filter design technique allows for a reduction in manufacturing complexity and the realization of high-performance filters.

SENSORS (2023)

Article Chemistry, Physical

A 2D copper-imidazolate framework without thermal treatment as an efficient ORR electrocatalyst for Zn-air batteries

Ana Franco, Jose Angel Salatti-Dorado, Valentin Garcia-Caballero, Sebastian Lorca, Luis Camacho, Manuel Cano, Antonio J. Fernandez-Romero, Juan J. Delgado, Juan J. Giner-Casares, Carolina Carrillo-Carrion

Summary: A new ultrathin and water-stable 2D Cu-based metal-organic framework has been synthesized with notable electrocatalytic activity for the oxygen reduction reaction in alkaline media, showing excellent performance in both alkaline flooded and all-solid-state Zn-air batteries.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

暂无数据