4.8 Article

Enriched graphitic N dopants of carbon dots as F cores mediate photothermal conversion in the NIR-II window with high efficiency

期刊

CARBON
卷 162, 期 -, 页码 220-233

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2020.02.053

关键词

-

资金

  1. National Natural Science Foundation of China [11774216]
  2. Science and Technology Commission of Shanghai Municipality [16ZR1412100]

向作者/读者索取更多资源

We have developed the rapid synthesis of NIR-II-responsive carbon dots (NIR-II-CDs) under microwave irradiation conditions. A close correlation between the photothermal effects and graphitic N doping level is well established by two observed effects: 1) absorbance at 808 and 1064 nm was consistently proportional to the graphitic N content; 2) the photothermal conversion efficiency remarkably increased with the graphitic N content. We further revealed a distinct photothermal conversion mechanism in the NIR-II-CDs, where doped graphitic N sites as paramagnetic F centers can mediate the highly efficient NIR absorption and photothermal conversion. Importantly, readily derived NIR-II-CDs with a graphitic N doping level as high as 4.30 at.% showed ultrahigh photothermal conversion efficiency of 81.3% in the NIR-II window. Using NIR-II-CDs or their hybrid liposomal formula as single PTT or imaging-guided PCT agents, complete tumor ablation without recurrence was realized under the 1064-nm laser irradiation at low laser power densities even in the presence of the breast tissue with a thickness larger than 10 mm. Our results suggest that the photothermal properties of biocompatible CDs can be regulated in the extended NIR regions by doping a high concentration of graphitic N defects as color centers for tumor treatment with minimized side effects. (c) 2020 Elsevier Ltd. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.8
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Biochemistry & Molecular Biology

A Two-Generation Reproductive Toxicity Study of Lanthanum Nitrate in SD Rats

Lang Yan, Fangyuan Gao, Wenjing Shi, Bijiang Geng, Jiqianzhu Zhang, Jingjing Mao, Yijun Tian, Lijun Ren, Xiaoyu Dai, Jikuai Chen, Jiangbo Zhu, Xiaofang Zhang

Summary: High-dose lanthanum nitrate had an effect on the liver weight and organ weight of SD rats, but there was no liver toxicity and no significant reproductive toxic effects.

BIOLOGICAL TRACE ELEMENT RESEARCH (2022)

Article Chemistry, Physical

DNA binding graphene quantum dots inhibit dual topoisomerases for cancer chemotherapy

Bijiang Geng, Jinyan Hu, Ping Li, Dengyu Pan, Longxiang Shen

Summary: The researchers developed a new DNA probe and interfacial inhibitor Graphenin, which showed enhanced inhibition against Topoisomerase I and II, demonstrating potential for cancer chemotherapy.

CARBON (2022)

Article Chemistry, Multidisciplinary

Simple and Fast Synthesis of Ni/NiO-loaded Carbon Nanotubes for the Alkaline Hydrogen Evolution Reaction

Chuanqi Feng, Bingwei Xin, Hongliang Li, Bijiang Geng

Summary: This study proposes a simple and efficient method to synthesize composites of Ni/NiO and carbon nanotubes, which exhibit excellent catalytic performance and good stability for alkaline water splitting hydrogen evolution.

CHEMISTRY LETTERS (2022)

Article Chemistry, Multidisciplinary

Platinum Crosslinked Carbon Dot@TiO2-x p-n Junctions for Relapse-Free Sonodynamic Tumor Eradication via High-Yield ROS and GSH Depletion

Bijiang Geng, Shuang Xu, Ping Li, Xiaokai Li, Fuling Fang, Dengyu Pan, Longxiang Shen

Summary: This study demonstrates the use of semiconductor p-n junctions as high-efficacy sonosensitizers for enhanced ROS generation through ultrasound excitation, and the oxidation of intracellular GSH by metal ions. The results show complete eradication of malignant tumors without relapse, highlighting the great potential of biocompatible, GSH-responsive p-n junctions as next-generation sonosensitizers.
Article Engineering, Environmental

Cu2-xO@TiO2-y Z-scheme heterojunctions for sonodynamic-chemodynamic combined tumor eradication

Bijiang Geng, Shirui Zhang, Xue Yang, Wenyan Shi, Ping Li, Dengyu Pan, Longxiang Shen

Summary: This study developed a novel heterojunction nanosonosensitizer with enhanced production of singlet oxygen and hydroxyl radicals for sonodynamic therapy. The nanosonosensitizer effectively separated the electron-hole pairs generated by ultrasound through a direct Z-scheme charge transfer mechanism. The experiments demonstrated complete tumor eradication in osteosarcoma models using a single drug injection and single ultrasound irradiation.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Engineering, Environmental

A biodegradable p-n junction sonosensitizer for tumor microenvironment regulating sonodynamic tumor therapy

Jinyan Hu, Bijiang Geng, Julie Glowacki, Shirui Zhang, Xue Yang, Dengyu Pan, Longxiang Shen

Summary: This study presents a new design of p-n junction sonosensitizers for enhanced sonodynamic therapy (SDT) of tumors. The sonosensitizer combines partially oxidized LiFePO4 nanorods and renal-clearable n-type N-doped CDs (N-CDs) to achieve effective spatial separation of electron-hole pairs generated by ultrasound, resulting in enhanced SDT effects. The constructed sonosensitizer exhibits high efficiency in generating reactive oxygen species, consuming free radicals, and reacting with overexpressed GSH. Additionally, the sonosensitizer can be safely eliminated from the body through renal clearance after completion of the SDT treatment.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Physical

Agaric-like cobalt diselenide supported by carbon nanofiber as an efficient catalyst for hydrogen evolution reaction

Chuanqi Feng, Bingwei Xin, Hongliang Li, Zhen Jia, Xiuling Zhang, Bijiang Geng

Summary: In this study, a novel 3D cathode was synthesized by growing cobalt diselenide on the surface of carbon nanofiber for hydrogen evolution reaction. The cobalt diselenide exhibited excellent electrocatalytic performance and stability, making it a promising catalyst for hydrogen evolution reactions.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

Article Chemistry, Physical

Synergistic anti-tumor therapy by a homotypic cell membrane-cloaked biomimetic nanocarrier with exceptionally potent activity against hepatic carcinoma

Shini Feng, Pinyue Ni, Yan Gong, Bijiang Geng, Hui Li, Chenlin Miao, Ruyu Fan, Levon Galstyan, Dengyu Pan, Fuxue Chen, Huafei Li

Summary: A drug delivery system (DDS) named iM7721@GQD-YM, consisting of a SMMC-7721 cancerous cyto-membrane-cloaked and co-encapsulating YM155 and graphene quantum dots (GQDs), was developed. The DDS exhibited effective tumor targeting, good biocompatibility, and the ability to release the drug through photothermal effect under near-infrared radiation.

NANO RESEARCH (2022)

Article Chemistry, Physical

Glycerate-derived Co3O4 nano-microspheres as efficient catalysts for oxygen evolution reaction

Chuanqi Feng, Jie Yang, Changrong Xiao, Bingwei Xin, Shengnan Zhang, Lumin Wang, Bijiang Geng

Summary: In this study, Co3O4 nano-microspheres with excellent catalytic activity were synthesized using a two-step method. The smaller nanoparticles within the spheres provided numerous catalytic active sites, resulting in superior catalytic performance.

APPLIED SURFACE SCIENCE (2022)

Article Multidisciplinary Sciences

Near-infrared phosphorescent carbon dots for sonodynamic precision tumor therapy

Bijiang Geng, Jinyan Hu, Yuan Li, Shini Feng, Dengyu Pan, Lingyan Feng, Longxiang Shen

Summary: In this study, a new method for designing near infrared (NIR) emitting sonosensitizers is reported. These sonosensitizers have a narrow bandgap and long-lived excited states, which can enhance sonodynamic therapy under low-intensity ultrasound irradiation. By encapsulating the sonosensitizers in cancer cell membranes, precise targeting and complete eradication of solid tumors can be achieved with a single injection and single irradiation.

NATURE COMMUNICATIONS (2022)

Article Engineering, Environmental

Trienzyme-like Co3O4@TiO2-xnanozymes for heterojunction-enhanced nanocatalytic-sonodynamic tumor therapy

Shirui Zhang, Lu Zhang, Jinyan Hu, Xialing He, Bijiang Geng, Dengyu Pan, Longxiang Shen

Summary: In this study, a heterojunction-enhanced nanocatalytic-sonodynamic therapy platform based on Co3O4@TiO2-x Z-scheme heterojunctions was reported. The platform possesses ultrasound-triggered ROS generation ability and triple enzyme-mimic activities, resulting in amplified ROS levels and relief of tumor hypoxia. The construction of Z-scheme heterojunctions effectively enhances the enzyme-mimic activities and sonodynamic properties, leading to complete tumor eradication. This work opens up a promising approach for the development of semiconductor heterojunctions with both sonodynamic and enzyme-mimic activities for enhanced nanocatalytic-sonodynamic combination therapy.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Chemistry, Multidisciplinary

Evaluation of subchronic toxicity of the compound of diphenhydramine hydrochloride and caffeine after 28 days of repeated oral administration in Sprague-Dawley rats and beagle dogs

Lijun Ren, Lang Yan, Wenjing Shi, Tiantian Zhang, Bijiang Geng, Jingjing Mao, Jiqianzhu Zhang, Yijun Tian, Haoneng Wang, Fangyuan Gao, Xiaoyu Dai, Jinfeng Li, Jing Gu, Yun Chen, Xiaofang Zhang, Jikuai Chen, Jiangbo Zhu

Summary: This study evaluated the subchronic toxicity of a compound of diphenhydramine hydrochloride (DH) and caffeine in SD rats and beagle dogs. Adverse effects included anorexia and liver function impairment, but most were reversible. The no-observed-adverse-effect levels (NOAEL) were 51 mg/kg/day for SD rats and 28.30 mg/kg/day (male) and 5.66 mg/kg/day (female) for beagle dogs.

DRUG AND CHEMICAL TOXICOLOGY (2023)

Article Engineering, Biomedical

Carbon Dot@MXene Nanozymes with Triple Enzyme-Mimic Activities for Mild NIR-II Photothermal-Amplified Nanocatalytic Therapy

Bijiang Geng, Lang Yan, Yuping Zhu, Wenjing Shi, Haoneng Wang, Jingjing Mao, Lijun Ren, Jiqianzhu Zhang, Yijun Tian, Fangyuan Gao, Xiaofang Zhang, Jikuai Chen, Jiangbo Zhu

Summary: This study developed a mild hyperthermia-enhanced nanocatalytic therapy platform based on Z-scheme heterojunction nanozymes by depositing N-doped carbon dots onto Nb2C nanosheets, achieving efficient treatment of tumors.

ADVANCED HEALTHCARE MATERIALS (2023)

Article Chemistry, Multidisciplinary

In Situ Synthesis of Ru/TiO2-x@TiCN Ternary Heterojunctions for Enhanced Sonodynamic and Nanocatalytic Cancer Therapy

Yin Zhao, Bo Yuan, Lang Yan, Zhiwei Wang, Zheng Xu, Bijiang Geng, Xiang Guo, Xiongsheng Chen

Summary: In this study, a one-step in situ synthesis strategy was reported to construct Ru/TiO2-x@TiCN heterojunctions, which improved the catalytic activity of nanozymes and ultrasound-activated ROS generation. The enhanced ROS production was achieved through triple enzyme-like activities, and the complete elimination of tumors was achieved through synergetic sonodynamic therapy and NCT.

ADVANCED SCIENCE (2023)

Article Materials Science, Biomaterials

Graphitic-N-doped graphene quantum dots for photothermal eradication of multidrug-resistant bacteria in the second near-infrared window

Bijiang Geng, Yuan Li, Jinyan Hu, Yuanyuan Chen, Junyi Huang, Longxiang Shen, Dengyu Pan, Ping Li

Summary: In this study, highly graphitic-N-doped graphene quantum dots with efficient NIR-II photothermal conversion properties were synthesized for the first time and used for photothermal antibacterial therapy. In vivo investigations showed that these quantum dots can effectively combat multidrug-resistant bacterial infections and accelerate wound healing.

JOURNAL OF MATERIALS CHEMISTRY B (2022)

Article Chemistry, Physical

Dendritic growth lowers carbon electrode work function for efficient perovskite solar cells

Jie Sheng, Jingshan He, Dun Ma, Yuanbo Wang, Wu Shao, Tian Ding, Ronghao Cen, Jingwen He, Zhihao Deng, Wenjun Wu

Summary: This study presents an innovative approach to improve the photovoltaic conversion characteristics and stability of perovskite solar cells through carbon electrode interface modification. By in-situ polymerization and carbonization on the surface of nano-graphite, a dendritic structure carbon electrode is formed, reducing the work function and aligning the energy levels with perovskite. This leads to improved charge and hole collection efficiency, resulting in increased photovoltaic conversion efficiency. Furthermore, the modified carbon electrode-based perovskite solar cells exhibit exceptional stability, maintaining high efficiency even without encapsulation.

CARBON (2024)

Article Chemistry, Physical

High-performance epoxy nanocomposites via constructing a rigid-flexible interface with graphene oxide functionalized by polyetheramine and f-SiO2

Guodong Shi, Jian Song, Xiaoxiao Tian, Tongtong Liu, Zhanjun Wu

Summary: This study demonstrates the improvement of mechanical properties and reduction of coefficient of thermal expansion (CTE) in graphene oxide (GO)/epoxy (EP) nanocomposites by enhancing the interface between GO and EP through functionalization and incorporating rigid-flexible interphases. The results reveal that the SiO2-PEA-GO hybrid exhibits better strengthening and toughening effects, as well as lower CTE, compared to the PEA-GO hybrid due to the presence of rigid-flexible interfaces with higher bonding strength and better energy dissipation mechanisms. Additionally, the nanocomposites with longer polyetheramine (PEA) molecules in the rigid-flexible interphases demonstrate higher strength and toughness, while maintaining a lower CTE. This work provides a promising strategy for constructing adjustable flexible-rigid interfacial structures and offers potential in developing GO/EP nanocomposites with high mechanical properties and low CTE.

CARBON (2024)

Article Chemistry, Physical

A facile route to the synthesis of carbon replicas cast from narrow-mesoporous matrices

Rafal Janus, Sebastian Jarczewski, Jacek Jagiello, Piotr Natkanski, Mariusz Wadrzyk, Marek Lewandowski, Marek Michalik, Piotr Kustrowski

Summary: In this study, a facile procedure for the synthesis of CMK-1 and CMK-2 carbon replicas was developed. The method utilizes basic laboratory equipment and a renewable carbon source, and operates under mild conditions. The resulting carbon mesostructures exhibit exquisite replication fidelity and structural homogeneity, making them suitable for applications in various fields.

CARBON (2024)

Article Chemistry, Physical

Microstructure and energetic characteristics of direct ink printed polymer-free rGO/nanothermite aerogel

Anqi Wang, Connor J. MacRobbie, Alex Baranovsky, Jean-Pierre Hickey, John Z. Wen

Summary: In this study, a novel polymer-free nanothermite aerogel with a wide range of nanoparticle loading was fabricated via a new additive manufacturing process. The SEM images showed a unique porous structure formed by extra thin rGO sheets, wrapping individual nanothermite clusters. The DSC-TGA results and high-speed combustion videos confirmed the enhanced energetic performance of the printed specimen.

CARBON (2024)

Article Chemistry, Physical

A solar-driven interfacial evaporator for seawater desalination based on mussel-inspired superhydrophobic composite coating

Wanze Wu, Misheng Zhao, Shiwei Miao, Xiaoyan Li, Yongzhong Wu, Xiao Gong, Hangxiang Wang

Summary: Superhydrophobic solar-driven interfacial evaporator is an energy-efficient technology for seawater desalination, which is easily fabricated using robust photothermal superhydrophobic coating and substrate. The created bifunctional coating on the melamine sponge substrate shows stable and highly efficient photothermal and superhydrophobic performance for seawater desalination. This superhydrophobic solar-driven interfacial evaporator is expected to have wide applications in seawater desalination.

CARBON (2024)

Article Chemistry, Physical

Bead-like flexible ZIF-67-derived Co@Carbon composite nanofibre mat for wideband microwave absorption in C-band

Zichen Xiang, Zhi Song, Tiansheng Wang, Menghang Feng, Yijing Zhao, Qitu Zhang, Yi Hou, Lixi Wang

Summary: This study presents a co-electrospinning synthesis strategy to fabricate lightweight and porous Co@C composite nanofibres with wideband microwave attenuation capacity. The addition of MOF-derived Co additives enhances the low-frequency absorption performance.

CARBON (2024)

Article Chemistry, Physical

A perovskite-graphene device for X-ray detection

J. Snow, C. Olson, E. Torres, K. Shirley, E. Cazalas

Summary: This study investigates the use of a perovskite-based graphene field effect transistor (P-GFET) device for X-ray detection. The sensitivity and responsivity of the device were found to be influenced by factors such as X-ray tube voltage, current, and source-drain voltage. Simulation experiments were conducted to determine the dose rate and energy incident on the device during irradiation.

CARBON (2024)

Article Chemistry, Physical

Microporous carbon prepared by microwave pyrolysis of scrap tyres and the effect of K+ in its structure on xylene adsorption

Zuzana Jankovska, Lenka Matejova, Jonas Tokarsky, Pavlina Peikertova, Milan Dopita, Karolina Gorzolkova, Dominika Habermannova, Michal Vastyl, Jakub Belik

Summary: This study provides new insights into microwave-assisted pyrolysis of scrap tyres, demonstrating that it can produce microporous carbon black with potential application in xylene adsorption. Compared to conventional pyrolysis, microwave pyrolysis requires less time and energy while maintaining similar adsorption capacity.

CARBON (2024)

Article Chemistry, Physical

Ambipolar charge transfer of larger fullerenes enabled by the modulated surface potential of h-BN/Rh(111)

Max Bommert, Bruno Schuler, Carlo A. Pignedoli, Roland Widmer, Oliver Groning

Summary: A detailed understanding of the interaction between molecules and two-dimensional materials is crucial for incorporating functional molecular films into next-generation 2D material-organic hybrid devices. This study compares the energy level alignment of different-sized fullerenes on a Moire superstructure and finds that C-84 fullerenes can be either neutral or negatively charged depending on slight variations of the electrostatic potential. This discovery suggests a new path to achieve ambipolar charge transfer without overcoming the electronic gap of fullerenes.

CARBON (2024)

Article Chemistry, Physical

Flexible SiO2/rGO aerogel for wide-angle broadband microwave absorption

Yuanjing Cheng, Xianxian Sun, Ye Yuan, Shuang Yang, Yuanhao Ning, Dan Wang, Weilong Yin, Yibin Li

Summary: The dual-structure aerogel (GS) consisting of flexible silica fibers and graphene honeycomb structures exhibits excellent resilience, flexibility, and reliability. It also shows remarkable wave absorbing performance, making it an ideal candidate for microwave absorption applications such as flexible electronics and aerospace.

CARBON (2024)

Article Chemistry, Physical

In situ self-adaptive growth of graphene coatings on hard substrates via competitive NiCo catalysis reaction

Shuyu Fan, Yinong Chen, Shu Xiao, Kejun Shi, Xinyu Meng, Songsheng Lin, Fenghua Su, Yifan Su, Paul K. Chu

Summary: Graphene coatings are promising solid lubrication materials due to their mechanical properties. This study presents a new method for in situ deposition of high-quality graphene coatings on hard substrates using NiCo solid solution and competitive reaction strategies. The graphene coating deposited on substrates with deep NiCo solid solution demonstrates superior low-friction and durability.

CARBON (2024)

Article Chemistry, Physical

Monodispersed semiconducting SWNTs significantly enhanced the thermoelectric performance of regioregular poly(3-dodecylthiophene) films

Mengdi Wang, Sanyin Qu, Yanling Chen, Qin Yao, Lidong Chen

Summary: The improved thermoelectric properties of conducting polymers are achieved by selectively capturing single-walled carbon nanotubes (SWNTs) in a conducting polymer film, leading to increased carrier mobility and reduced thermal conductivity. The resulting composite film exhibits significantly higher electrical conductivity and lower thermal conductivity compared to films with a mixture of SWNTs. This work provides a convenient and efficient method to enhance the thermoelectric properties of conducting polymers.

CARBON (2024)

Review Chemistry, Physical

Component optimization and microstructure design of carbon nanotube-based microwave absorbing materials: A review

Heng Wei, Weihua Li, Kareem Bachagha

Summary: This article reviews the research progress of carbon nanotube-based microwave absorbing materials (MAMs) in recent years, covering the fundamental theory, design strategies, synthesis methods, and future development directions.

CARBON (2024)

Article Chemistry, Physical

MXene-based polymer brushes decorated with small-sized Ag nanoparticles enabled high-performance lithium host for stable lithium metal battery

Chenguang Shi, Junlong Huang, Zongheng Cen, Tan Yi, Shaohong Liu, Ruowen Fu

Summary: This study developed a high-performance Li metal host material, which achieved dendrite-free Li deposition with a low nucleation overpotential and high Coulombic efficiencies through the combination of Ti3C2-g-PV4P sheets and Ag nanoparticles. The full cells assembled with the Li@host anode and LiFePO4 cathode exhibited high discharge capacity and excellent cycling stability, demonstrating a perspective design for future energy storage devices.

CARBON (2024)

Article Chemistry, Physical

A stable full cell having high energy density realized by using a three-dimensional current collector of carbon nanotubes and partial prelithiation of silicon monoxide

Tomotaro Mae, Kentaro Kaneko, Hiroki Sakurai, Suguru Noda

Summary: A new partial prelithiation method for SiO/C-CNT electrodes was developed, which showed reduced irreversible capacity and achieved high energy densities with good reversibility. The method allows for precise control of the degree of prelithiation and is applicable to various chemistries.

CARBON (2024)