期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 59, 期 45, 页码 19835-19840出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202005662
关键词
all-polymer solar cells; non-conjugated polymer acceptors; power conversion efficiency; thermal stability; thioalkyl chain linkages
资金
- Swedish Research Council [2015-04853, 2016-06146, 2019-04683]
- Swedish Research Council Formas
- Wallenberg Foundation [2017.0186, 2016.0059]
- Guangzhou Municipal Science and Technology Bureau [201804010501, 201904010381]
- Department of Education of Guangdong Province [2018GKTSCX041, 2017GKCXTD001]
- Department of Science and Technology of Guangdong Province [2016A010103046, 2019B1515120073, 2019B090921002]
- NSFC [51773142, 51973146, 61774077]
- China Scholarship Council [201908440047]
- China Postdoctoral Science Foundation [2020M673054]
- Vinnova [2019-04683] Funding Source: Vinnova
- Swedish Research Council [2019-04683, 2015-04853] Funding Source: Swedish Research Council
A non-conjugated polymer acceptor PF1-TS4 was firstly synthesized by embedding a thioalkyl segment in the mainchain, which shows excellent photophysical properties on par with a fully conjugated polymer, with a low optical band gap of 1.58 eV and a high absorption coefficient >10(5) cm(-1), a high LUMO level of -3.89 eV, and suitable crystallinity. Matched with the polymer donor PM6, the PF1-TS4-based all-PSC achieved a power conversion efficiency (PCE) of 8.63 %, which is approximate to 45 % higher than that of a device based on the small molecule acceptor counterpart IDIC16. Moreover, the PF1-TS4-based all-PSC has good thermal stability with approximate to 70 % of its initial PCE retained after being stored at 85 degrees C for 180 h, while the IDIC16-based device only retained approximate to 50 % of its initial PCE when stored at 85 degrees C for only 18 h. Our work provides a new strategy to develop efficient polymer acceptor materials by linkage of conjugated units with non-conjugated thioalkyl segments.
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