Caught in the H inact : Crystal Structure and Spectroscopy Reveal a Sulfur Bound to the Active Site of an O 2 ‐stable State of [FeFe] Hydrogenase

X-ray Crystallography and Vibrational Spectroscopy Reveal the Key Determinants of Biocatalytic Dihydrogen Cycling by [NiFe] Hydrogenases

(2019) Yulia Ilina et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Interaction of the H-Cluster of FeFe Hydrogenase with Halides

(2018) Melisa del Barrio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sulfide Protects [FeFe] Hydrogenases From O2

(2018) Patricia Rodríguez-Maciá et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A bound reaction intermediate sheds light on the mechanism of nitrogenase

(2018) Daniel Sippel et al.   SCIENCE

Crystallographic and spectroscopic assignment of the proton transfer pathway in [FeFe]-hydrogenases

(2018) Jifu Duan et al.   Nature Communications

Spectroscopic Evidence of Reversible Disassembly of the [FeFe] Hydrogenase Active Site

(2017) Patricia Rodríguez-Maciá et al.   Journal of Physical Chemistry Letters

Proton Coupled Electronic Rearrangement within the H-Cluster as an Essential Step in the Catalytic Cycle of [FeFe] Hydrogenases

(2017) Constanze Sommer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction Coordinate Leading to H2 Production in [FeFe]-Hydrogenase Identified by Nuclear Resonance Vibrational Spectroscopy and Density Functional Theory

(2017) Vladimir Pelmenschikov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxygen Stability in the New [FeFe]-Hydrogenase from Clostridium beijerinckii SM10 (CbA5H)

(2016) Simone Morra et al.   BIOCHEMISTRY

Artificial Maturation of the Highly Active Heterodimeric [FeFe] Hydrogenase fromDesulfovibrio desulfuricansATCC 7757

(2016) James A. Birrell et al.   ISRAEL JOURNAL OF CHEMISTRY

Identification of a Catalytic Iron-Hydride at the H-Cluster of [FeFe]-Hydrogenase

(2016) David W. Mulder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of O2 diffusion and reduction in FeFe hydrogenases

(2016) Adam Kubas et al.   Nature Chemistry

Vibrational spectroscopy reveals the initial steps of biological hydrogen evolution

(2016) S. Katz et al.   Chemical Science

A Redox Hydrogel Protects the O2-Sensitive [FeFe]-Hydrogenase fromChlamydomonas reinhardtiifrom Oxidative Damage

(2015) Alaa Alsheikh Oughli et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hybrid [FeFe]-Hydrogenases with Modified Active Sites Show Remarkable Residual Enzymatic Activity

(2015) Judith F. Siebel et al.   BIOCHEMISTRY

Resonance Raman Spectroscopic Analysis of the [NiFe] Active Site and the Proximal [4Fe-3S] Cluster of an O2-Tolerant Membrane-Bound Hydrogenase in the Crystalline State

(2015) Elisabeth Siebert et al.   JOURNAL OF PHYSICAL CHEMISTRY B

[FeFe]-Hydrogenase Oxygen Inactivation Is Initiated at the H Cluster 2Fe Subcluster

(2015) Kevin D. Swanson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Spectroscopic Investigations of [FeFe] Hydrogenase Maturated with [57Fe2(adt)(CN)2(CO)4]2–

(2015) Ryan Gilbert-Wilson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogenases

(2014) Wolfgang Lubitz et al.   CHEMICAL REVIEWS

Ligand binding to the FeMo-cofactor: Structures of CO-bound and reactivated nitrogenase

(2014) T. Spatzal et al.   SCIENCE

A Unified Electrocatalytic Description of the Action of Inhibitors of Nickel Carbon Monoxide Dehydrogenase

(2013) Vincent C.-C. Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Identification and Characterization of the “Super-Reduced” State of the H-Cluster in [FeFe] Hydrogenase: A New Building Block for the Catalytic Cycle?

(2012) Agnieszka Adamska et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reversibility and efficiency in electrocatalytic energy conversion and lessons from enzymes

(2011) F. A. Armstrong et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

The Hydrogen Issue

(2010) Nicola Armaroli et al.   ChemSusChem

14N HYSCORE investigation of the H-cluster of [FeFe] hydrogenase: evidence for a nitrogen in the dithiol bridge

(2009) Alexey Silakov et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

How oxygen attacks [FeFe] hydrogenases from photosynthetic organisms

(2009) S. T. Stripp et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA