Enhancing Magnetic Hysteresis in Single-Molecule Magnets by Ligand Functionalization

Design criteria for dysprosium(III) single-molecule magnets (SMMs) with large thermal energy barriers to magnetic reversal have been established and proven, and the challenge to enhance performance is in understanding and controlling electron-vibration coupling that is the origin of magnetic reversal. We have prepared an SMM, [Dy(L)(2)(PY)(5)][BPh4] 1 (HL = (S)-(-)-1-phenylethanol), based on the archetype [Dy((OBu)-Bu-t)(2)(py)(5)][BPh4] 2. Compounds 1 and 2 have similarly large energy barriers of U-eff = 1,130(20) cm(-1) and (J(eff) = 1,250(10) cm(-1), and yet 1 shows magnetic hysteresis at a far higher temperature of 22 K cf. T-H = 4 K for 2. Ab initio calculation of the electron-vibration coupling and spin dynamics shows that substitution of the alkoxide ligand in fact enhances relaxation over the energy barrier for 1 compared with 2, in agreement with experiment, and that the higher temperature of magnetic hysteresis likely owes to reduced quantum tunneling at low temperatures.