期刊
CHEMSUSCHEM
卷 9, 期 15, 页码 1904-1910出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201600290
关键词
electrocatalysis; heterogeneous catalysis; hydrogenation; nickel; renewable resources
资金
- Ernest-Solvay-Foundation
- Elite Network of Bavaria
- National Science Foundation
- CAREER Award [1122374]
Electrocatalytic hydrogenation (ECH) is a sustainable pathway for the synthesis of value-added organic compounds, provided affordable catalysts with high activity, selectivity and durability are developed. Here, we synthesize Cu/C, Ni/C, and CuNi/C nanoparticles and compare their performance to Pt/C, Ru/C, PtRu/C for the ECH of hydroxyacetone, a bio-derived feedstock surrogate containing a carbonyl and a hydroxyl functional group. The non-precious metal electrocatalysts show promising conversion-time behavior, product selectivities, and Faradaic efficiencies. Ni/C forms propylene glycol with a selectivity of 89% (at 80% conversion), while Cu/C catalyzes ECH (52% selectivity) and hydrodeoxygenation (HDO, 48% selectivity, accounting for evaporation). CuNi/C shows increased turnover frequencies but reduced ECH selectivity (80% at 80% conversion) as compared to the Ni/C catalyst. Importantly, stability studies show that the non-precious metal catalysts do not leach at operating conditions.
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