Article
Chemistry, Physical
Geeta Durga, Pooja Kalra, Vinay Kumar Verma, Kanjur Wangdi, Anuradha Mishra
Summary: Ionic liquids have established themselves as a preferred solvent in synthetic chemistry, particularly in polymer chemistry. They are versatile solvents used for polymeric reactions and can also be polymerized to enhance their inherent properties, finding applications in various fields such as electrochemical devices, nanocomposites, optoelectronics, and more. This comprehensive review covers both aspects of ILs as a solvent in polymeric reactions and their polymeric form, poly(ionic liquids), presenting their diverse potential applications.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Multidisciplinary
Jocasta Avila, Chiara Corsini, Cintia M. Correa, Martin Rosenthal, Agilio Padua, Margarida Costa Gomes
Summary: This Perspective highlights the pathways to prepare porous ionic liquids using easily accessible materials for reduced environmental impact. The study demonstrates that suspensions of porous solids are stable in eutectic mixtures, which indicates their potential in preparing porous ionic liquids. Porous ionic liquids maintain the wide electrochemical window observed in their precursor pure ionic liquids, making them suitable for green electrochemical reactions, especially those involving gases with enhanced solubility in the porous suspensions. Furthermore, their capacity as gas-rich media suggests potential sustainable biomedical and pharmaceutical applications, provided that non-toxic, biocompatible ionic liquids and porous solids are utilized.
Article
Chemistry, Physical
Yvonne Manjarrez, Allison M. Clark, Megan E. Fieser
Summary: By using a phosphonium chloride ionic liquid as both the cocatalyst and solubilizing agent, a metal-containing ionic liquid (MIL) is formed, which leads to significantly faster polymerization rates and higher molecular weight polyesters compared to the original system.
Article
Polymer Science
Qunying Wang, Sergey Popov, Veronika Strehmel, Jochen S. Gutmann, Bernd Strehmel
Summary: A series of cyanines with varying methine chain lengths and terminal groups were reacted with a specific cation after excitation in the NIR region, resulting in the generation of free radicals and conjugate acids. This study investigated the efficiency of free radical and cationic polymerization, as well as their combination as a hybrid system. By using NIR-LED exposure and varying the sensitizers, different photopolymerization efficiencies were achieved. The results showed that the combination of free radical and cationic polymerization can work effectively in hybrid systems.
Article
Chemistry, Physical
Beichen Liu, Wenxiao Guo, Matthew A. Gebbie
Summary: In this study, we investigate the influence of ionic correlations on the reaction rates and selectivity of CO2 electroreduction. Through experiments, we find that at intermediate concentrations, the reduction rates of CO2 are accelerated and the efficiency of CO production is enhanced. The acceleration of CO2 reduction is due to the amplification of potential-dependent driving forces, rather than changes in onset potential. These findings are applicable to both cocatalytic and noncatalytic ions.
Article
Engineering, Environmental
Benoit Villemejeanne, Sophie Legeai, Eric Meux, Sandrine Dourdain, Hakima Mendil-Jakani, Emmanuel Billy
Summary: The one-step electroleaching-electrochemical deposition process using ionic liquid mixtures is a promising alternative for palladium and gold recovery, with chloride-based mixtures proving to be the most suitable electrolyte. The use of low viscous electrolytes allows for metal leaching at low anodic potential, leading to a more sustainable process compared to conventional processes.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Correction
Chemistry, Physical
Yury A. Budkov, Nikolai N. Kalikin, Andrei L. Kolesnikov
Summary: The correction for 'Electrochemistry meets polymer physics: polymerized ionic liquids on an electrified electrode' by Yury A. Budkov et al. published in Phys. Chem. Chem. Phys., 2022, DOI: 10.1039/d1cp04221a addresses any errors in the original article.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Review
Chemistry, Multidisciplinary
Olga Lebedeva, Dmitry Kultin, Leonid Kustov
Summary: This review explores the characteristics of electrochemical synthesis of nanostructures in ionic liquids, emphasizing the production of various nanomaterials and nanoscale polymer films. It highlights the potential application of ILs as an electrochemical medium and the relative simplicity of experimental procedures.
Article
Polymer Science
Wei Wu, Hailan Zeng, Weiran Zhang, Weili Zhang, Haiyun Jiang, Guohua Wu, Ziyu Li, Xiang Wang, Yiyang Huang, Zhiyong Lei
Summary: This study presents a method for in-situ electrochemical polymerization of PEDOT:PSS/Reline films in aqueous solution. By using deep eutectic solvents composed of choline chloride and urea (Reline) as green solvents and dopants, PEDOT:PSS/Reline films with excellent electrochromic properties were prepared.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Dafei Yuan, Evan Plunkett, Phong H. Nguyen, Dakota Rawlings, My Linh Le, Rene Kroon, Christian Mueller, Rachel A. Segalman, Michael L. Chabinyc
Summary: The interactions between counterions and electronic carriers in electrically doped semiconducting polymers play a crucial role in charge carrier delocalization, electronic conductivity, and thermal stability. Introducing dianions in semiconducting polymers leads to double doping, minimizing structural distortions but altering the electrostatic interactions. Polymeric ionic liquids (PILs) with croconate dianions prove useful in studying the role of counterions in p-type semiconducting polymers, preventing cation diffusion during ion exchange. The choice of croconate dianions influences the thermoelectric performance and thermal stability of the doped semiconducting polymer.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Review
Chemistry, Physical
Gagandeep Kaur, Harsh Kumar, Meenu Singla
Summary: This article presents the extensive utilization and range of ionic liquids in various fields, based on available literature. It provides a systematic and concise analysis of the applications of different ionic liquids, highlighting recent significant advances in each area. This review contributes to enhancing the understanding of the substantial knowledge in every research branch using ionic liquids. Additionally, it discusses the challenges associated with the industrial use of ionic liquids, which require further investigation.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Electrochemistry
Oscar Javier Moreno-Piza, Marco-Fidel Suarez-Herrera
Summary: This study investigates the redox reactions of elemental sulfur under different conditions and explores the effects of different electrolytes on the performance of lithium-sulfur batteries. The results show that by optimizing the electrolyte and electrode materials, the kinetic behavior of sulfur reactions can be improved, providing a potential solution to the short service life issue of lithium-sulfur batteries.
ELECTROCHIMICA ACTA
(2022)
Article
Chemistry, Multidisciplinary
Christian Balischewski, Biswajit Bhattacharyya, Eric Sperlich, Christina Guenter, Alkit Beqiraj, Tillmann Klamroth, Karsten Behrens, Stefan Mies, Alexandra Kelling, Susanne Lubahn, Lea Holtzheimer, Anne Nitschke, Andreas Taubert
Summary: The study synthesized fifteen N-butylpyridinium salts and investigated their structures, thermal properties, and electrochemical properties. All compounds are ionic liquids with melting points between 64 and 101 degrees C, isostructural, with electrochemical stability windows between 2 and 3 V, and conductivities ranging from 10(-5) to 10(-6) S cm(-1).
CHEMISTRY-A EUROPEAN JOURNAL
(2022)
Article
Engineering, Environmental
Ana Silva, Raquel V. Barrulas, Marta C. Corvo, Marcileia Zanatta
Summary: Ionic liquids and poly(ionic liquid)s are promising materials for CO2 capture, but their industrial application has been delayed due to economic and technical issues. This study focuses on the synthesis and characterization of imidazolium and pyrrolidinium-derived ILs and PILs with basic anions, and evaluates their CO2 sorption capacity. The results show great potential for CO2 capture and recycling.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Chemistry, Multidisciplinary
Guillaume Zante, Christopher E. Elgar, Katherine George, Andrew P. Abbott, Jennifer M. Hartley
Summary: The study explores the properties of concentrated ionic fluids and distinguishes them from concentrated aqueous brines. It demonstrates a continuous relationship between molar conductivity and fluidity, regardless of cation, charge density, or ionic radius. The diffusion coefficients of specific metal chlorides in various ionic fluids show a linear correlation with fluidity. By adjusting chloride and water activity, selective etching of mixed metal waste streams can be achieved.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Dmitrii Rakov, Meisam Hasanpoor, Artem Baskin, John W. Lawson, Fangfang Chen, Pavel Cherepanov, Alexandr N. Simonov, Patrick C. Howlett, Maria Forsyth
Summary: By modifying the composition of ionic liquid electrolyte and cycling conditions, the cycling performance and deposition morphology of lithium metal anodes can be improved.
CHEMISTRY OF MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Shammi A. Ferdousi, Luke A. O'Dell, Ju Sun, Yvonne Hora, Maria Forsyth, Patrick C. Howlett
Summary: We investigated the sodium electrochemistry and the evolution and chemistry of the solid-electrolyte interphase (SEI) during cycling of Na metal electrodes in two ionic liquid (IL) electrolytes. We found that the IL based on the phosphonium cation demonstrated superior performance and stability compared to the pyrrolidinium-based counterpart, even after the addition of water. This research breakthrough shows promise for the development of high-capacity Na metal anodes and future higher-temperature Na-metal-based batteries.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
Ju Sun, Isuru E. Gunathilaka, Luke A. O'Dell, Patrick C. Howlett, Maria Forsyth
Summary: The relationship between formation procedure and interfacial characteristics of electrodes in sodium-ion batteries is crucial for cell performance. We successfully shortened the formation time and improved the cycling performance of the sodium-ion half cell through optimized formation protocols in superconcentrated ionic liquid electrolytes. Our findings show that high C-rate formation contributes to a highly conductive and thinner solid-electrolyte interphase (SEI) layer, facilitating Na+ diffusion kinetics. This work provides a cost-effective and time efficient formation protocol for NIBs.
JOURNAL OF POWER SOURCES
(2023)
Article
Chemistry, Physical
Maria Martinez-Ibanez, Nicola Boaretto, Alexander Santiago, Leire Meabe, Xiaoen Wang, Oihane Zugazua, Inigo Raposo, Maria Forsyth, Michel Armand, Heng Zhang
Summary: This paper reports a highly-concentrated FSI-based ternary gel polymer electrolyte (TGPE) with high lithium-ion conductivities, wide electrochemical stability, and superior compatibility with lithium metal electrode. The TGPE enables stable Li plating and stripping processes, as well as high discharge capacity of a Li||Li(Ni0.6Mn0.2Co0.2)O2 cell at ambient temperatures. This study not only provides safe and highly conductive polymer electrolytes but also enhances our understanding of the role of FSI anions in high-energy lithium metal batteries.
JOURNAL OF POWER SOURCES
(2023)
Article
Chemistry, Physical
Gregorio Guzman-Gonzalez, Marta Alvarez-Tirado, Jorge L. Olmedo-Martinez, Matias L. Picchio, Nerea Casado, Maria Forsyth, David Mecerreyes
Summary: This article demonstrates the use of single-component electrolytes in lithium batteries based on new lithium borate ionic liquids at room temperature. The optimized lithium ionic liquids (LiILs) show high ionic conductivity, lithium transference numbers, and electrochemical stability. These LiILs also exhibit high compatibility with lithium-metal electrodes, resulting in excellent electrochemical performance in lithium-metal battery cells.
ADVANCED ENERGY MATERIALS
(2023)
Article
Energy & Fuels
Karolina Biernacka, Ju Sun, Faezeh Makhlooghiazad, Ali Balkis, Isuru E. Gunathilaka, Luke A. O'Dell, Montserrat Galceran Mestres, Patrick C. Howlett, Jennifer M. Pringle, Maria Forsyth
Summary: In this study, a promising electrolyte based on hexamethylguanidinium bis(fluorosulfonyl)imide [FSI] at a sodium concentration of 25 mol% NaFSI is presented for sodium batteries. The electrolyte exhibits good physicochemical properties, supporting stable sodium plating and stripping as well as high sodium-ion transference number. The electrolyte also shows excellent cycling performance with hard carbon anode and NaFePO4 cathode.
JOURNAL OF PHYSICS-ENERGY
(2023)
Article
Chemistry, Physical
Mojtaba Eftekharnia, Robert Kerr, Maria Forsyth, Patrick C. Howlett
Summary: In order to utilize the advantages of high energy density lithium-metal batteries, their cycle life and safety need to be improved. External compression has been shown to enhance the performance of these batteries by reducing dendrite growth and improving lithium deposition morphology. This study investigates the behavior of high-capacity Li||LFP pouch cells in pyrrolidinium-based ionic liquid electrolytes under different levels of compression and discusses the mechanisms that affect the cell performance and failure. The results indicate that higher compression leads to more uniform and less dendritic lithium deposition.
JOURNAL OF POWER SOURCES
(2023)
Article
Biochemistry & Molecular Biology
Sharon Monaci, Daniela Minudri, Lorenzo Guazzelli, Andrea Mezzetta, David Mecerreyes, Maria Forsyth, Anthony Somers
Summary: Corrosion is a major problem that affects structures and buildings, leading to premature failure and economic loss. Biobased lignin and ionic liquids have shown potential as corrosion inhibitors. This study investigated the inhibitory properties of new biobased lignin ionic liquids and found that one of them exhibited promising performance.
Review
Polymer Science
Esmat Ebadati, Eliza Switalska, Enzo Lombi, Stephen C. Warren-Smith, Drew Evans
Summary: Soil nutrients are essential for plant growth, but their availability can be influenced by soil pH. This review focuses on the development of polymer materials for in-ground pH sensing and discusses the importance of pH in nutrient availability and toxicity control.
JOURNAL OF POLYMER SCIENCE
(2023)
Article
Nanoscience & Nanotechnology
Siti Musliha Ajmal Mokhtar, Ainslie L. K. Derrick-Roberts, Drew R. Evans, Xanthe L. Strudwick
Summary: Transdermal monitoring and drug delivery have attracted attention due to the development of minimally invasive microneedle (MN) devices. Recent research has focused on incorporating conducting polymers (CPs) onto MNs, but the biocompatibility of CPs in skin and the effects of electrical biasing on cells have not been extensively studied. This study found that cells cultured at a low seeding density exhibited lower viability and proliferation after exposure to electrochemically biased MNs comprising PEDOT polymers.
ACS APPLIED BIO MATERIALS
(2023)
Article
Materials Science, Biomaterials
Siti Musliha Ajmal Mokhtar, Miko Yamada, Tarl W. Prow, Mark Moore, Xanthe L. Strudwick, Drew R. Evans
Summary: Skin sampling is a diagnostic procedure that analyzes extracted skin tissues and biomarkers in bodily fluids. This study introduces new microneedles coated with a biocompatible organic conducting polymer for electrochemically assisted skin sampling, allowing for real-time information on skin penetration depth and salt detection in interstitial fluid. The ability to extract ions from the skin adds chemical information for disease detection, such as in the case of psoriasis.
JOURNAL OF MATERIALS CHEMISTRY B
(2023)
Article
Electrochemistry
Rafael Del Olmo, Gregorio Guzman-Gonzalez, Ilda O. Santos-Mendoza, David Mecerreyes, Maria Forsyth, Nerea Casado
Summary: Ion transport in composite electrodes is crucial for the performance of lithium-metal batteries, and the use of ionic conducting polymers as binders has been suggested. In this study, two poly(ionic liquid) polymers were analyzed as binders in LiFePO4 cathodes, and PMTFSI-Li showed the best performance with high specific capacity and long lifespan. Surprisingly, the presence of ionic binders also affected the lithium metal deposition morphology, leading to a more homogeneous plating and mitigating mossy lithium growth.
BATTERIES & SUPERCAPS
(2023)
