Review
Chemistry, Physical
Lijing Xie, Cheng Tang, Zhihong Bi, Mingxin Song, Yafeng Fan, Chong Yan, Xiaoming Li, Fangyuan Su, Qiang Zhang, Chengmeng Chen
Summary: Hard carbons, with their enriched microcrystalline structure, have attracted attention as a promising anode material for high-energy LIBs, but face challenges such as low initial efficiency and capacity issues. Current research efforts are focused on addressing these challenges to enable practical application in next-generation batteries.
ADVANCED ENERGY MATERIALS
(2021)
Article
Materials Science, Multidisciplinary
Yaxiong Yang, Shugang Liu, Zhe Dong, Zhenguo Huang, Cheng Lu, Yongjun Wu, Mingxia Gao, Yongfeng Liu, Hongge Pan
Summary: This study demonstrates an effective hierarchical conformal coating strategy for high-performance microsized Si anodes, which enhances mechanical properties, promotes ionic diffusion, stabilizes electrode/electrolyte interfaces, and increases electronic conductivity. The optimized structure achieves high reversible capacity, cycling stability, and rate capability.
APPLIED MATERIALS TODAY
(2022)
Article
Chemistry, Physical
Xiang Li, Jianwei He, Yucong Liao, Shaoshan Zhu, Yayun Tang, Hanyang Li, Ning Lv, Yuexin Xu, Yadong Wang
Summary: In this study, a conjugate carbonyl polyimide and nano-silicon composite was designed and synthesized to address the challenges of rapid capacity fading and complicated electrode material preparation in silicon-based electrodes for lithium-ion batteries. This composite exhibited a relative high specific capacity and excellent cycling stability, as well as improved electrode kinetics and electrochemical performance.
JOURNAL OF POWER SOURCES
(2022)
Review
Electrochemistry
Yao Liu, Wei Li, Yongyao Xia
Summary: While carbon, oxide, and silicon-based materials have limitations in current LIB applications, polyanionic compounds have gained attention for their ability to stabilize structures, adjust redox couples, and provide migration channels for guest ions, leading to electrode materials with long-term cycling, high energy density, and outstanding rate capability.
ELECTROCHEMICAL ENERGY REVIEWS
(2021)
Article
Engineering, Environmental
Fei Zhang, Miaomiao Wu, Xingchao Wang, Qian Xiang, Yan Wu, Juan Ding, Ying Sun
Summary: This study reports a novel organic electrode material, hexalithium salt of mellitic acid (Li6C12O12), which shows promising characteristics including low cost, high capacity, non-toxicity, and environmental friendliness for lithium-ion batteries (LIB) and dual-ion batteries (DIB). The electrochemical and spectroscopic analysis confirmed a reversible coordination reaction mechanism based on carboxylic carbonyl and Li+ ions. Li6C12O12 achieved large reversible capacities of 730 mA h g(-1) at 0.21 A/g and 372 mA h g(-1) even at 2 A/g. Moreover, Li6C12O12 electrode exhibited excellent performance in full LIB and DIB, showing high capacity and cycling stability. This work provides a new perspective on designing and tailoring organic electrode materials for high-performance lithium-ion batteries and dual-ion batteries.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Yuke Li, Yijiao Ding, Juncheng Wu, Yu Wang, Lei Chen, Yanxian Jin, Li Zhang, Shi-Bin Ren, De-Man Han
Summary: This study investigates the electrochemical properties of lithium-ion batteries by designing and synthesizing four new PTO polymers with different aryl derivatives as linking units. The optimal PTO-Py polymer displayed high electronic conductivity and enhanced pseudocapacitive behavior. When evaluated as a cathode for LIBs, the PTO-Py electrode exhibited excellent lithium storage performance, rate performance, and cycling abilities.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Physical
Yuke Li, Yijiao Ding, Juncheng Wu, Yu Wang, Lei Chen, Yanxian Jin, Li Zhang, Shi-Bin Ren, De-Man Han
Summary: By designing and synthesizing a series of novel PTO polymers, the effect of N content in aryl linkers on the electronic conduction and transportation of polymer structures was studied. The optimal PTO-Py polymer exhibited high electronic conductivity and enhanced pseudocapacitive behavior, leading to excellent lithium storage performance and cycling stability in lithium-ion batteries.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Energy & Fuels
Ikramul Hasan Sohel, Tarik Ozturk, Umut Aydemir, Naeimeh Sadat Peighambardoust, Ozgur Duygulu, Isil Isik-Gulsac, Mustafa Altun, Mehmet Nurullah Ates
Summary: This study presents a simple method to enhance the stability of electroplated Silicon (Si) electrodes through heat treatment. The cycling stability of the Si anode improves significantly with increasing heat treatment temperature. The Si electrode heat treated at 400 degrees C maintains 77% capacity even after exposure to air for one week.
JOURNAL OF ENERGY STORAGE
(2022)
Article
Chemistry, Physical
Xiao Bai, Hui Zhang, Junpin Lin
Summary: This study explores the use of conducting polymers as both a conductive agent and binder in silicon anodes. By utilizing polyaniline (PANI) as a three-dimensional bridge, it is possible to maintain constant electric connectivity with silicon, even during long-term cycling. The research also demonstrates the improvement of Li-ion diffusion kinetics and cycling properties through low-temperature sintering of double-protected silicon nanoparticles (SiNPs) without damaging the PANI conductive skeleton. The novel composite material, Si@C/PANI-CNT, exhibits excellent discharge capacity and stability over multiple cycles.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Multidisciplinary
Mingyuan Zhao, Shaobin Yang, Wei Dong
Summary: In this study, silicon nanofibers were prepared using natural sepiolite as a template via a low-temperature aluminum reduction process. The resulting nanofibers showed a more complete structure and exhibited higher reversible capacity as an anode material for lithium-ion batteries compared to commercial silicon. This simple and low-cost method provides a new strategy for the synthesis of high-capacity silicon anodes.
FRONTIERS IN CHEMISTRY
(2022)
Article
Polymer Science
Bogyoung Kim, Yeeun Song, Byungwook Youn, Doojin Lee
Summary: We investigated the relationship between surface chemistry and rheological properties in silicon anode slurries. Various binders were used to control particle aggregation and improve flowability and homogeneity. Zeta potential analysis showed that binder conformation on silicon particles can be influenced by neutralization and pH conditions. The results demonstrated the importance of considering surface chemistry, neutralization, and pH conditions when assessing the rheological properties of the slurry and coating quality for lithium-ion batteries.
Article
Chemistry, Physical
Xi Chen, Laura C. Loaiza, Laure Monconduit, Vincent Seznec
Summary: The 2D Si-Ge alloy materials, known as siliganes, have been developed for use as anodes in Li-ion batteries, offering reasonable cost and promising electrochemical performance. Among them, the siligane_Si0.9Ge0.1 showed the best performance, with a reversible capacity of 1325 mA h g-1, high capacity retention, and coulombic efficiency at a current density of 0.05 A g-1 after 10 cycles.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Ruslan R. Samigullin, Oleg A. Drozhzhin, Evgeny Antipov
Summary: The thermal stability of cathode and anode materials for Li-ion and Na-ion batteries was studied using differential scanning calorimetry and ex situ powder X-ray diffraction. The results showed that the thermal stability of Na-ion cathode materials increases in the order NFM < NVPF < NVP < NVPO. The heat on energy term was proposed and analyzed for all studied materials.
ACS APPLIED ENERGY MATERIALS
(2022)
Review
Chemistry, Physical
Yanxiu Liu, Rong Shao, Ruiyu Jiang, Xinyu Song, Zhong Jin, Lin Sun
Summary: Silicon anodes have been extensively studied as a potential alternative to graphite ones for Li-ion batteries, but their commercial application is limited by poor structural and interfacial stability. Designing robust conductive binder networks is a key strategy to fully exploit the capacity potential of Si-based anodes. This review summarizes existing binders for Si anodes, focusing on three-dimensional and multifunctional polymeric binders with excellent electrical conductivity, flexibility, and adhesion, which are expected to accelerate the practical application of silicon anodes. Suggestions for future development of Si anodic binders are also provided.
Article
Chemistry, Physical
Ziqi Zhang, Huiqiong Wang, Meijuan Cheng, Yang He, Xiang Han, Linshan Luo, Pengfei Su, Wei Huang, Jianyuan Wang, Cheng Li, Zizhong Zhu, Qiaobao Zhang, Songyan Chen
Summary: A novel silicon nano-ribbon (SiNR) with (110) crystal plane was proposed as an anode for Lithium-ion batteries, showing stability and high capacity retention during cycling. SiNR, without the need for surface coating treatment, exhibited high ionic conductivity and long cycling stability.
ENERGY STORAGE MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
Christofer Sangeland, Guiomar Hernandez, Daniel Brandell, Reza Younesi, Maria Hahlin, Jonas Mindemark
Summary: Proper understanding of the formation of solid polymer electrolyte electrode interfacial layer and its impact on cell performance is crucial for practical solid-state lithium-ion batteries. However, probing these solid-solid interfaces is challenging. This study combines electrochemistry and spectroscopic analysis to evaluate the electrochemical stability window of a polyester-based electrolyte and demonstrates the formation of resistive interphase layers at the electrode-electrolyte interface.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Girish D. Salian, Jonathan Hojberg, Christian Fink Elkjaer, Yonas Tesfamhret, Guiomar Hernandez, Matthew J. Lacey, Reza Younesi
Summary: This study compares the effects of two water-soluble binders (CMC and SA) with N-methylpyrrolidone-soluble PVdF-HFP on the electrochemical performance of high-voltage LNMO cathodes. The results show that the cathodes prepared with water-soluble binders exhibit similar performance to PVdF-HFP at room temperature, but have higher cycling stability at 55 degrees C.
Article
Chemistry, Physical
Isabell L. Johansson, Christofer Sangeland, Tamao Uemiya, Fumito Iwasaki, Masahiro Yoshizawa-Fujita, Daniel Brandell, Jonas Mindemark
Summary: It is important to enhance the electrochemical stability of polymer electrolytes and the cycling performance of lithium-ion batteries for next-generation high-energy-density storage solutions. The study found that adding zwitterionic additives can improve the stability of the electrolyte and enhance the cycling stability of the battery by preventing the formation of decomposition products at the polymer-cathode interface.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Biochemistry & Molecular Biology
Guiomar Hernandez, Sergio Ferrero, Helmut Reinecke, Camino Bartolome, Jesus M. Martinez-Ilarduya, Cristina Alvarez, Angel E. Lozano
Summary: By modifying the polyamidation method and using in situ silylated diamines and acid chlorides, a rod-type polyamide, poly(p-phenylene terephthalamide) (PPTA), with a significantly higher molecular weight than the classical and industrial method was obtained. The optimization of the method involved the use of a mixture of pyridine and a high-pKa tertiary amine along with the silylating agent. Nuclear magnetic resonance and molecular simulation studies confirmed that the increase in molecular weight was mainly attributed to the formation of silylamide groups in the polymer chain.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Polymer Science
Therese Eriksson, Harish Gudla, Yumehiro Manabe, Tomoki Yoneda, Daniel Friesen, Chao Zhang, Yasuhide Inokuma, Daniel Brandell, Jonas Mindemark
Summary: This study compares the properties of solid polymer electrolytes (SPEs) of three different carbonyl-containing polymers. Experimental measurements and molecular dynamics simulations reveal the influence of the polymer structure on ion transport and the possibility of achieving desired transport properties by fine-tuning the polymer chemistry.
Article
Electrochemistry
Samuel Emilsson, Vidyanand Vijayakumar, Jonas Mindemark, Mats Johansson
Summary: Phase-separated structural battery electrolytes (SBEs), achieved via polymerization-induced phase separation (PIPS), show enhanced mechanical stability and high ion conduction. This study investigates the use of novel oligomeric carbonates to improve the safety of SBEs. Increasing the carbonate chain length improves the thermal stability of the SBEs and tuning the molecular structure of the liquid electrolyte affects the PIPS process and SBE morphology.
ELECTROCHIMICA ACTA
(2023)
Review
Chemistry, Physical
Vidyanand Vijayakumar, Meena Ghosh, Kiran Asokan, Santhosh Babu Sukumaran, Sreekumar Kurungot, Jonas Mindemark, Daniel Brandell, Martin Winter, Jijeesh Ravi Nair
Summary: Polymer composite electrolytes (PCEs) have gained significant attention for lithium-based battery applications due to their combination of polymer chemistry, inorganic chemistry, and electrochemistry. This review focuses on the prospects of using 2D layered inorganic, organic, and hybrid nanomaterials as fillers in PCEs. It discusses various types of nanofillers, such as graphene oxide, boron nitride, and layered clay minerals, and their impact on battery cell performance. The review also highlights the potential of 2D organic and hybrid nanomaterials in PCE development.
ADVANCED ENERGY MATERIALS
(2023)
Article
Electrochemistry
Kenza Elbouazzaoui, Funeka Nkosi, Daniel Brandell, Jonas Mindemark, Kristina Edstrom
Summary: In this study, the ionic transport characteristics of solid-state composite electrolytes based on poly(trimethylene carbonate) (PTMC) with LiTFSI salt and garnet-type ion-conducting Li6.7Al0.3-La3Zr2O12 (LLZO) ceramic particles were investigated. The incorporation of LLZO particles showed positive effects on the ionic conductivity, with low to moderate loadings exhibiting a gradual increase in conductivity, transference number, and polymer-cation coordination number. The enhancement can be explained by the combined contributions of ionic transport along polymer-ceramic interfaces and Lewis acid-base interaction between LLZO particles and LiTFSI salt. However, excessive loading of LLZO particles led to a detrimental effect on the ionic conductivity due to particle agglomeration and partial coverage with a Li2CO3 layer, which hindered interfacial pathways and inter-particle connectivity necessary for efficient ionic transport.
ELECTROCHIMICA ACTA
(2023)
Article
Electrochemistry
Mads C. Heintz, Jekabs Grins, Aleksander Jaworski, Gunnar Svensson, Thomas Thersleff, William R. Brant, Rebecka Lindblad, Andrew J. Naylor, Kristina Edstrom, Guiomar Hernandez
Summary: Silicon powder kerf loss from diamond wire sawing can be used as a raw material for lithium-ion battery negative electrodes. The kerf particles contain approximately 50% amorphous silicon. Thorough investigation of the amorphicity and other relevant features was conducted. In-situ X-ray powder diffraction experiments demonstrated the significance of the powders for battery applications.
Review
Chemistry, Physical
Habtom D. Asfaw, Antonia Kotronia, Nuria Garcia-Araez, Kristina Edstrom, Daniel Brandell
Summary: This review highlights the latest advances in the application of different electrolytes, particularly gel polymer electrolytes (GPEs), in dual-ion batteries (DIBs). GPEs have been shown to improve the Coulombic efficiency, energy density, and long-term cycle life of DIBs, and are suitable for compact designs.
Article
Chemistry, Physical
Guiomar Hernandez, Tian Khoon Lee, Mate Erdelyi, Daniel Brandell, Jonas Mindemark
Summary: By studying the salt dissolution properties and ionic conductivity of PVdF-HFP-based electrolytes using different fabrication methods and a low-molecular-weight solvent analogue, it is found that PVdF-HFP is a poor host for solid polymer electrolytes despite its high dielectric constant. The salt dissolution properties are instead controlled by fluorophilic interactions between the anion and the polymer.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Physical
Fabian Jeschull, Cornelius Hub, Timofey I. Kolesnikov, David Sundermann, Guiomar Hernandez, Dominik Voll, Jonas Mindemark, Patrick Theato
Summary: Battery technologies are diversifying towards post-Li batteries, including both monovalent and multivalent ions. The electrolyte plays a crucial role in forming stable interfaces and providing sufficient ionic conductivity. Solid polymer electrolytes face challenges in transporting multivalent ions. Past achievements and recent advancements are discussed to outline possibilities and challenges in this rapidly evolving research area.
ADVANCED ENERGY MATERIALS
(2023)