期刊
ADVANCED MATERIALS INTERFACES
卷 7, 期 13, 页码 -出版社
WILEY
DOI: 10.1002/admi.202000475
关键词
biphilic; condensation; fog harvesting; superhydrophobicity; volatile organic compounds
资金
- Office of Naval Research [N00014-16-1-2625]
- National Science Foundation [1554249]
- National Natural Science Foundation of China [51206092]
- National Science and Technology Major Project [ZX06901]
- China Scholarship Council [201606210181]
- International Institute for Carbon Neutral Energy Research (WPI-I2CNER) - Japanese Ministry of Education, Culture, Sports, Science and Technology
Biphilic surfaces having spatially distinct wetting have the potential to enable a plethora of applications ranging from fog harvesting, microfluidics, advanced manufacturing, and pumpless fluid transfer. However, complex and costly fabrication along with poor durability have hindered the widespread utilization of biphilic surfaces. Here, hierarchical biphilic micro/nanostructured surfaces passively functionalized by the atmosphere are demonstrated as a platform to create scalable and abrasion-resistant biphilic interfaces. Biphilic hierarchical copper oxide (CuO) nanowires are fabricated on copper substrates via laser ablation followed by thermal oxidation. The surfaces spontaneously become globally superhydrophobic and locally hydrophilic due to the adsorption of airborne volatile organic compounds on the ultrahigh surface energy CuO nanowires. The curvature-dependent spatial variation in nanowire morphology enables local roughness variation and wetting contrast without the need for selective functionalization. Coalescence-induced droplet jumping and water vapor condensation experiments demonstrate global superhydrophobicity with discrete local hydrophilicity. In addition to enhanced fog harvesting rates, the surfaces are demonstrated to have repeatable self-healing function with enhanced abrasion resistance compared to single-tier structured surfaces. The work not only develops a facile method of fabricating scalable biphilic surfaces via nanoscale structure variation and atmosphere-mediated surface modification, but also provides insights into the role of wetting contrast on droplet dynamics.
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