期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 8, 期 16, 页码 6479-6487出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.0c01047
关键词
biobased vitrimers; glycyrrhizic acid; transesterification; shape memory polymers; recyclable adhesives
资金
- NSFC [21604085]
- National Key R&D Program of China [2017YFD0200302]
Vitrimers are covalent polymer networks that can change their topology through thermally activated bond exchange reactions. In this work, fully biobased and recyclable vitrimers were developed from epoxidized soybean oil (ESO) and natural glycyrrhizic acid (GL) as it was without additional chemical modification, which avoided the use of nonrenewable petroleum resources and resolved the disposal problems of materials. Because of the unique rigid skeleton of GL, ESO/GL vitrimers showed good thermal stability and mechanical properties. Driven by the transesterification-induced topological network rearrangements, these ESO/GL vitrimers exhibited high performance of welding, repairing, and shape memory. They were also recyclable and chemically degradable by ethylene glycol. More importantly, these vitrimers could be used as repairable and recyclable adhesives.
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