期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 14, 页码 4713-4716出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201600186
关键词
ionic liquids; self-assembly; silsesquioxane; thiol-ene reaction; vesicles
资金
- National Natural Science Foundation of China [21274081, 21574075]
Three new hybrid ionic liquids (ILs) based on cage silsesquioxane (SQ) were rapidly prepared in high yields from octa(mercaptopropyl)silsesquioxane and 1-allyl-3-methylimidazolium salts (Br-, BF4-, PF6-) through the photochemical thiol-ene reaction. These SQ-based ILs exhibited low glass transition temperatures and good thermal stability. The unique amphiphilic nature of these hybrid ILs cause them to self-assemble into perfect vesicles with yolk-shell structures, in which cages formed the yolk due to their aggregation and outer anions formed the shell.
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