The Journey toward Low Temperature, Low Pressure Catalytic Nitrogen Fixation

CO2 electrolysis to multicarbon products at activities greater than 1 A cm−2

(2020) F. Pelayo García de Arquer et al.   SCIENCE

Efficient Photocatalytic Nitrogen Fixation over Cu δ + ‐Modified Defective ZnAl‐Layered Double Hydroxide Nanosheets

(2020) Shuai Zhang et al.   Advanced Energy Materials

Ammonia Detection Methods in Photocatalytic and Electrocatalytic Experiments: How to Improve the Reliability of NH3 Production Rates?

(2019) Yunxuan Zhao et al.   Advanced Science

Tuning Oxygen Vacancies in Ultrathin TiO2 Nanosheets to Boost Photocatalytic Nitrogen Fixation up to 700 nm

(2019) Yunxuan Zhao et al.   ADVANCED MATERIALS

A rigorous electrochemical ammonia synthesis protocol with quantitative isotope measurements

(2019) Suzanne Z. Andersen et al.   NATURE

Distinguishing Plasma Contributions to Catalyst Performance in Plasma-Assisted Ammonia Synthesis

(2019) Patrick Barboun et al.   ACS Sustainable Chemistry & Engineering

Enhanced Electrocatalytic N2 Reduction via Partial Anion Substitution in Titanium Oxide-Carbon Composites

(2019) Qing Qin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Doping strain induced bi-Ti3+ pairs for efficient N2 activation and electrocatalytic fixation

(2019) Na Cao et al.   Nature Communications

Plasma catalytic ammonia synthesis: state of the art and future directions

(2019) Maria L Carreon   JOURNAL OF PHYSICS D-APPLIED PHYSICS

Formation of carbon–nitrogen bonds in carbon monoxide electrolysis

(2019) Matthew Jouny et al.   Nature Chemistry

Defect Engineering in Photocatalytic Nitrogen Fixation

(2019) Run Shi et al.   ACS Catalysis

Recent progress towards mild-condition ammonia synthesis

(2019) Qianru Wang et al.   Journal of Energy Chemistry

Efficient Non-dissociative Activation of Dinitrogen to Ammonia over Lithium-Promoted Ruthenium Nanoparticles at Low Pressure

(2019) Jianwei Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Crystal-Phase-Engineering Enabled PdCu Electrocatalyst for Enhanced Ammonia Synthesis

(2019) Xiaoqing Huang   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Greatly Improving Electrochemical N2 Reduction over TiO2 Nanoparticles by Iron Doping

(2019) Tongwei Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Low-Temperature Synthesis of Perovskite Oxynitride-Hydrides as Ammonia Synthesis Catalysts

(2019) Masaaki Kitano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Boosting selective nitrogen reduction to ammonia on electron-deficient copper nanoparticles

(2019) Yun-Xiao Lin et al.   Nature Communications

Plasma-Enhanced Catalytic Synthesis of Ammonia over a Ni/Al2O3 Catalyst at Near-Room Temperature: Insights into the Importance of the Catalyst Surface on the Reaction Mechanism

(2019) Yaolin Wang et al.   ACS Catalysis

Vibrationally Excited Activation of N2 in Plasma-Enhanced Catalytic Ammonia Synthesis: A Kinetic Analysis

(2019) Kevin H. R. Rouwenhorst et al.   ACS Sustainable Chemistry & Engineering

Beyond the Thermal Equilibrium Limit of Ammonia Synthesis with Dual Temperature Zone Catalyst Powered by Solar Light

(2019) Chengliang Mao et al.   Chem

Nitrogenase Bioelectrochemistry for Synthesis Applications

(2019) Ross D. Milton et al.   ACCOUNTS OF CHEMICAL RESEARCH

Wettability controlled photocatalytic reactive oxygen generation and Klebsiella pneumoniae inactivation over triphase systems

(2019) Xuyang Xiong et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Electrolytic CO2 Reduction in a Flow Cell

(2018) David M. Weekes et al.   ACCOUNTS OF CHEMICAL RESEARCH

Promoted Fixation of Molecular Nitrogen with Surface Oxygen Vacancies on Plasmon-Enhanced TiO2 Photoelectrodes

(2018) Chengcheng Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Self-organized Ruthenium-Barium Core-Shell Nanoparticles on a Mesoporous Calcium Amide Matrix for Efficient Low-Temperature Ammonia Synthesis

(2018) Masaaki Kitano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Energy-confined solar thermal ammonia synthesis with K/Ru/TiO 2-x H x

(2018) Chengliang Mao et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

In situ plasma-assisted atmospheric nitrogen fixation using water and spray-type jet plasma

(2018) Peng Peng et al.   CHEMICAL COMMUNICATIONS

Excitation of H2O at the plasma/water interface by UV irradiation for the elevation of ammonia production

(2018) Tatsuya Sakakura et al.   GREEN CHEMISTRY

Morphology Effect of Ceria on the Catalytic Performances of Ru/CeO2 Catalysts for Ammonia Synthesis

(2018) Bingyu Lin et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

A review on the non-thermal plasma-assisted ammonia synthesis technologies

(2018) Peng Peng et al.   JOURNAL OF CLEANER PRODUCTION

A Spectroscopic Study on the Nitrogen Electrochemical Reduction Reaction on Gold and Platinum Surfaces

(2018) Yao Yao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pyrene hydrogel for promoting direct bioelectrochemistry: ATP-independent electroenzymatic reduction of N2

(2018) David P. Hickey et al.   Chemical Science

Efficient ammonia synthesis over a Ru/La0.5Ce0.5O1.75 catalyst pre-reduced at high temperature

(2018) Yuta Ogura et al.   Chemical Science

A Review of Electrocatalytic Reduction of Dinitrogen to Ammonia under Ambient Conditions

(2018) Xiaoyang Cui et al.   Advanced Energy Materials

Progress toward Commercial Application of Electrochemical Carbon Dioxide Reduction

(2018) Chi Chen et al.   Chem

Intermetallic Electride Catalyst as a Platform for Ammonia Synthesis

(2018) Jiazhen Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pothole-rich Ultrathin WO3 Nanosheets that Trigger N≡N Bond Activation of Nitrogen for Direct Nitrate Photosynthesis

(2018) Youwen Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkali and Alkaline Earth Hydrides-Driven N2 Activation and Transformation over Mn Nitride Catalyst

(2018) Fei Chang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Dependent Support Effects of Oxyhydride-Supported Ru, Fe, Co Catalysts for Ammonia Synthesis

(2018) Ya Tang et al.   Advanced Energy Materials

Atmospheric Plasma-Assisted Ammonia Synthesis Enhanced via Synergistic Catalytic Absorption

(2018) Peng Peng et al.   ACS Sustainable Chemistry & Engineering

Nonthermal Plasma Synthesis of Ammonia over Ni-MOF-74

(2018) Javishk Shah et al.   ACS Sustainable Chemistry & Engineering

Nitrogen Fixation by Ru Single-Atom Electrocatalytic Reduction

(2018) Hengcong Tao et al.   Chem

Electrocatalytic Reduction of Nitrogen: From Haber-Bosch to Ammonia Artificial Leaf

(2018) Antonio José Martín et al.   Chem

Ammonia synthesis from N2 and H2O using a lithium cycling electrification strategy at atmospheric pressure

(2017) Joshua M. McEnaney et al.   Energy & Environmental Science

Process Intensification in Ammonia Synthesis Using Novel Coassembled Supported Microporous Catalysts Promoted by Nonthermal Plasma

(2017) Galip Akay et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Ru-based multifunctional mesoporous catalyst for low-pressure and non-thermal plasma synthesis of ammonia

(2017) Peng Peng et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

In situ/Operando studies of electrocatalysts using hard X-ray spectroscopy

(2017) Benedikt Lassalle-Kaiser et al.   JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA

Ammonia Electrosynthesis with High Selectivity under Ambient Conditions via a Li+ Incorporation Strategy

(2017) Gao-Feng Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photocatalytic Conversion of Nitrogen to Ammonia with Water on Surface Oxygen Vacancies of Titanium Dioxide

(2017) Hiroaki Hirakawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Surface Single-Cluster Catalyst for N2-to-NH3 Thermal Conversion

(2017) Xue-Lu Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enhanced Photocatalytic Reaction at Air–Liquid–Solid Joint Interfaces

(2017) Xia Sheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ru-Loaded C12A7:e– Electride as a Catalyst for Ammonia Synthesis

(2017) Michikazu Hara et al.   ACS Catalysis

Barium Hydride-Mediated Nitrogen Transfer and Hydrogenation for Ammonia Synthesis: A Case Study of Cobalt

(2017) Wenbo Gao et al.   ACS Catalysis

Ammonia Synthesis on Wool-Like Au, Pt, Pd, Ag, or Cu Electrode Catalysts in Nonthermal Atmospheric-Pressure Plasma of N2 and H2

(2017) Masakazu Iwamoto et al.   ACS Catalysis

Photon-Driven Nitrogen Fixation: Current Progress, Thermodynamic Considerations, and Future Outlook

(2017) Andrew J. Medford et al.   ACS Catalysis

Electrochemical Reduction of N2under Ambient Conditions for Artificial N2Fixation and Renewable Energy Storage Using N2/NH3Cycle

(2016) Di Bao et al.   ADVANCED MATERIALS

Remarkable catalysis of a wool-like copper electrode for NH3 synthesis from N2 and H2 in non-thermal atmospheric plasma

(2016) Keigo Aihara et al.   CHEMICAL COMMUNICATIONS

Non-catalyzed one-step synthesis of ammonia from atmospheric air and water

(2016) Tetsuya Haruyama et al.   GREEN CHEMISTRY

Conversion of Dinitrogen to Ammonia by FeN3-Embedded Graphene

(2016) Xiao-Fei Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Water Durable Electride Y5Si3: Electronic Structure and Catalytic Activity for Ammonia Synthesis

(2016) Yangfan Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facet-dependent solar ammonia synthesis of BiOCl nanosheets via a proton-assisted electron transfer pathway

(2016) Hao Li et al.   Nanoscale

Breaking scaling relations to achieve low-temperature ammonia synthesis through LiH-mediated nitrogen transfer and hydrogenation

(2016) Peikun Wang et al.   Nature Chemistry

Scalable water splitting on particulate photocatalyst sheets with a solar-to-hydrogen energy conversion efficiency exceeding 1%

(2016) Qian Wang et al.   NATURE MATERIALS

Atmospheric-pressure nonthermal plasma synthesis of ammonia over ruthenium catalysts

(2016) Hyun-Ha Kim et al.   Plasma Processes and Polymers

Light-driven dinitrogen reduction catalyzed by a CdS:nitrogenase MoFe protein biohybrid

(2016) K. A. Brown et al.   SCIENCE

Essential role of hydride ion in ruthenium-based ammonia synthesis catalysts

(2016) Masaaki Kitano et al.   Chemical Science

Efficient and Stable Ammonia Synthesis by Self-Organized Flat Ru Nanoparticles on Calcium Amide

(2016) Yasunori Inoue et al.   ACS Catalysis

Plasma N2-fixation: 1900–2014

(2015) B.S. Patil et al.   CATALYSIS TODAY

The Challenge of Electrochemical Ammonia Synthesis: A New Perspective on the Role of Nitrogen Scaling Relations

(2015) Joseph H. Montoya et al.   ChemSusChem

From the Sabatier principle to a predictive theory of transition-metal heterogeneous catalysis

(2015) Andrew J. Medford et al.   JOURNAL OF CATALYSIS

Efficient Visible Light Nitrogen Fixation with BiOBr Nanosheets of Oxygen Vacancies on the Exposed {001} Facets

(2015) Hao Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electride support boosts nitrogen dissociation over ruthenium catalyst and shifts the bottleneck in ammonia synthesis

(2015) Masaaki Kitano et al.   Nature Communications

Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

(2014) Brian M. Hoffman et al.   CHEMICAL REVIEWS

Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts

(2014) J. Luo et al.   SCIENCE

Ammonia synthesis by N2 and steam electrolysis in molten hydroxide suspensions of nanoscale Fe2O3

(2014) S. Licht et al.   SCIENCE

Photo-illuminated diamond as a solid-state source of solvated electrons in water for nitrogen reduction

(2013) Di Zhu et al.   NATURE MATERIALS

Nitrate formation from atmospheric nitrogen and oxygen photocatalysed by nano-sized titanium dioxide

(2013) Shi-Jie Yuan et al.   Nature Communications

Ammonia synthesis over ruthenium catalyst supported on perovskite type BaTiO3

(2012) Ziqing Wang et al.   CATALYSIS COMMUNICATIONS

Ammonia synthesis using a stable electride as an electron donor and reversible hydrogen store

(2012) Masaaki Kitano et al.   Nature Chemistry

The Evolution and Future of Earth’s Nitrogen Cycle

(2010) Donald E. Canfield et al.   SCIENCE

Nitrogen Cycle Electrocatalysis

(2009) Victor Rosca et al.   CHEMICAL REVIEWS

Water Splitting on Semiconductor Catalysts under Visible-Light Irradiation

(2009) Rufino M. Navarro Yerga et al.   ChemSusChem

Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum: Theory versus Experiment

(2008) Richard R. Schrock   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterogeneous photocatalyst materials for water splitting

(2008) Akihiko Kudo et al.   CHEMICAL SOCIETY REVIEWS

How a century of ammonia synthesis changed the world

(2008) Jan Willem Erisman et al.   Nature Geoscience