[FeFe]-Hydrogenase H-Cluster Mimics with Unique Planar μ-(SCH2)2ER2Linkers (E=Ge and Sn)

Synthesis of Diiron(I) Dithiolato Carbonyl Complexes

(2016) Yulong Li et al.   CHEMICAL REVIEWS

Synthesis, characterization, and H/D exchange of μ-hydride-containing [FeFe]-hydrogenase subsite models formed by protonation reactions of (μ-TDT)Fe2(CO)4(PMe3)2 (TDT = SCH2SCH2S) with protic acids

(2016) Li-Cheng Song et al.   DALTON TRANSACTIONS

Silicon-Heteroaromatic [FeFe] Hydrogenase Model Complexes: Insight into Protonation, Electrochemical Properties, and Molecular Structures

(2015) Roman Goy et al.   CHEMISTRY-A EUROPEAN JOURNAL

Steric effect of the dithiolato linker on the reduction mechanism of [Fe2(CO)6{μ-(XCH2)2CRR′}] hydrogenase models (X = S, Se)

(2015) Ralf Trautwein et al.   DALTON TRANSACTIONS

A sterically stabilized FeI–FeI semi-rotated conformation of [FeFe] hydrogenase subsite model

(2015) Roman Goy et al.   DALTON TRANSACTIONS

Ligand effects on the electrochemical behavior of [Fe2(CO)5(L){μ-(SCH2)2(Ph)PO}] (L = PPh3, P(OEt)3) hydrogenase model complexes

(2015) Laith R. Almazahreh et al.   DALTON TRANSACTIONS

Spectroscopic Characterization of the Bridging Amine in the Active Site of [FeFe] Hydrogenase Using Isotopologues of the H-Cluster

(2015) Agnieszka Adamska-Venkatesh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Structure, and Electrocatalysis of Butterfly [Fe2SP] Cluster Complexes Relevant to [FeFe]-Hydrogenases

(2015) Li-Cheng Song et al.   ORGANOMETALLICS

Hydrogenases

(2014) Wolfgang Lubitz et al.   CHEMICAL REVIEWS

Mimicking hydrogenases: From biomimetics to artificial enzymes

(2014) Trevor R. Simmons et al.   COORDINATION CHEMISTRY REVIEWS

Effects of Alkane Linker Length and Chalcogen Character in [FeFe]-Hydrogenase Inspired Compounds

(2014) Mohammad K. Harb et al.   HETEROATOM CHEMISTRY

A Diferrous Dithiolate as a Model of the Elusive Hoxinact State of the [FeFe] Hydrogenases: An Electrochemical and Theoretical Dissection of Its Redox Chemistry

(2014) Dounia Chouffai et al.   INORGANIC CHEMISTRY

Conformational Mobility and Pendent Base Effects on Electrochemistry of Synthetic Analogues of the [FeFe]-Hydrogenase Active Site

(2014) Danielle J. Crouthers et al.   ORGANOMETALLICS

Crystallographic Characterization of a Fully Rotated, Basic Diiron Dithiolate: Model for the HredState?

(2013) Wenguang Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

New FeI-FeIComplex Featuring a Rotated Conformation Related to the [2 Fe]HSubsite of [Fe-Fe] Hydrogenase

(2013) Sabrina Munery et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reactions of [FeFe]-hydrogenase models involving the formation of hydrides related to proton reduction and hydrogen oxidation

(2013) Ning Wang et al.   DALTON TRANSACTIONS

The Becke Fuzzy Cells Integration Scheme in the Amsterdam Density Functional Program Suite

(2013) Mirko Franchini et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

A Novel [FeFe] Hydrogenase Model with a (SCH2)2P═O Moiety

(2013) Laith R. Almazahreh et al.   ORGANOMETALLICS

The Influence of OH Groups in [Fe(CO)3]2[(μ-ECH2)2C(CH2OH)2] (E = S, Se) Complexes toward the Cathodic Process

(2013) Ralf Trautwein et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

{1,1′-(Dimethylsilylene)bis[methanechalcogenolato]}diiron Complexes [2Fe2E(Si)] (E=S, Se, Te) - [FeFe] Hydrogenase Models

(2012) Ulf-Peter Apfel et al.   HELVETICA CHIMICA ACTA

Structural and Spectroscopic Features of Mixed Valent FeIIFeI Complexes and Factors Related to the Rotated Configuration of Diiron Hydrogenase

(2012) Chung-Hung Hsieh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthetic Models for the Active Site of the [FeFe]-Hydrogenase: Catalytic Proton Reduction and the Structure of the Doubly Protonated Intermediate

(2012) Maria E. Carroll et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Terminal vs Bridging Hydrides of Diiron Dithiolates: Protonation of Fe2(dithiolate)(CO)2(PMe3)4

(2012) Riccardo Zaffaroni et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Comparison of S and Se dichalcogenolato [FeFe]-hydrogenase models with central S and Se atoms in the bridgehead chain

(2012) Mohammad K. Harb et al.   TETRAHEDRON

Isolation, observation, and computational modeling of proposed intermediates in catalyticprotonreductions with the hydrogenase mimic Fe2(CO)6S2C6H4

(2011) Robert J. Wright et al.   DALTON TRANSACTIONS

Spectroscopically characterized intermediates of catalytic H2 formation by [FeFe] hydrogenase models

(2011) Stefanie Tschierlei et al.   Energy & Environmental Science

Effect of the damping function in dispersion corrected density functional theory

(2011) Stefan Grimme et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Directing protonation in [FeFe] hydrogenase active site models by modifications in their second coordination sphere

(2010) Salah Ezzaher et al.   CHEMICAL COMMUNICATIONS

Synthesis and Characterization of [FeFe]-Hydrogenase Models with Bridging Moieties Containing (S, Se) and (S, Te)

(2010) Mohammad K. Harb et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Models for the Active Site in [FeFe] Hydrogenase with Iron-Bound Ligands Derived from Bis-, Tris-, and Tetrakis(mercaptomethyl)silanes

(2010) Ulf-Peter Apfel et al.   INORGANIC CHEMISTRY

Mechanism of hydrogen production in [Fe–Fe]-hydrogenases: A quantum mechanics/molecular mechanics study

(2010) Steven Trohalaki et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

Toward Consistent Terminology for Cyclohexane Conformers in Introductory Organic Chemistry

(2010) Donna J. Nelson et al.   JOURNAL OF CHEMICAL EDUCATION

Equilibrium Acidities of Superacids

(2010) Agnes Kütt et al.   JOURNAL OF ORGANIC CHEMISTRY

Conformational analysis of 3,3-dimethyl-3-silathiane, 2,3,3-trimethyl-3-silathiane and 2-trimethylsilyl-3,3-dimethyl-3-silathiane-preferred conformers, barriers to ring inversion and substituent effects

(2010) Svetlana V. Kirpichenko et al.   JOURNAL OF PHYSICAL ORGANIC CHEMISTRY

Conformational pathways of simple six-membered rings

(2010) Carlos A. Stortz   JOURNAL OF PHYSICAL ORGANIC CHEMISTRY

Structural and Functional Analogues of the Active Sites of the [Fe]-, [NiFe]-, and [FeFe]-Hydrogenases†

(2009) Cédric Tard et al.   CHEMICAL REVIEWS

Fluorophenyl-substituted Fe-only hydrogenases active site ADT models: different electrocatalytic process for proton reduction in HOAc and HBF4/Et2O

(2009) Wen-Guang Wang et al.   DALTON TRANSACTIONS

Phosphane- and Phosphite-Substituted Diiron Diselenolato Complexes as Models for [FeFe]-Hydrogenases

(2009) Mohammad K. Harb et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Biomimetic Model Featuring the NH Proton and Bridging Hydride Related to a Proposed Intermediate in Enzymatic H2Production by Fe-Only Hydrogenase

(2009) Ming-Hsi Chiang et al.   INORGANIC CHEMISTRY

Review of electrochemical studies of complexes containing the Fe2S2 core characteristic of [FeFe]-hydrogenases including catalysis by these complexes of the reduction of acids to form dihydrogen

(2009) Greg A.N. Felton et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Cyclohexane Isomerization. Unimolecular Dynamics of the Twist-Boat Intermediate†

(2009) Khatuna Kakhiani et al.   JOURNAL OF PHYSICAL CHEMISTRY A

One- to Two-Electron Reduction of an [FeFe]-Hydrogenase Active Site Mimic: The Critical Role of Fluxionality of the [2Fe2S] Core

(2009) Greg A. N. Felton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Characterization of Diiron Diselenolato Complexes Including Iron Hydrogenase Models

(2009) Mohammad K. Harb et al.   ORGANOMETALLICS

Preparation and Characterization of Homologous Diiron Dithiolato, Diselenato, and Ditellurato Complexes: [FeFe]-Hydrogenase Models

(2009) Mohammad K. Harb et al.   ORGANOMETALLICS

Synthetic Support of De Novo Design: Sterically Bulky [FeFe]-Hydrogenase Models

(2008) Michael L. Singleton et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

First insights into the protonation of dissymetrically disubstituted di-iron azadithiolate models of the [FeFe]H2ases active site

(2008) Salah Ezzaher et al.   CHEMICAL COMMUNICATIONS

Small molecule mimics of hydrogenases: hydrides and redox

(2008) Frédéric Gloaguen et al.   CHEMICAL SOCIETY REVIEWS

The effect of bridgehead steric bulk on the ground state and intramolecular exchange processes of (μ-SCH2CR2CH2S)[Fe(CO)3][Fe(CO)2L] complexes

(2008) Michael L. Singleton et al.   COMPTES RENDUS CHIMIE

Electrocatalysis of hydrogen evolution by synthetic diiron units using weak acids as the proton source: Pathways of doubtful relevance to enzymic catalysis by the diiron subsite of [FeFe] hydrogenase

(2008) Stacey J. Borg et al.   COMPTES RENDUS CHIMIE

Electron and proton transfers at diiron dithiolate sites relevant to the catalysis of proton reduction by the [FeFe]-hydrogenases

(2008) Jean-François Capon et al.   COORDINATION CHEMISTRY REVIEWS

Selenium-bridged diiron hexacarbonyl complexes as biomimetic models for the active site of Fe–Fe hydrogenases

(2008) Shang Gao et al.   DALTON TRANSACTIONS

Redox and Structural Properties of Mixed-Valence Models for the Active Site of the [FeFe]-Hydrogenase: Progress and Challenges

(2008) Aaron K. Justice et al.   INORGANIC CHEMISTRY

Terminal Hydride in [FeFe]-Hydrogenase Model Has Lower Potential for H2Production Than the Isomeric Bridging Hydride

(2008) Bryan E. Barton et al.   INORGANIC CHEMISTRY

Visible Light-Driven Electron Transfer and Hydrogen Generation Catalyzed by Bioinspired [2Fe2S] Complexes

(2008) Yong Na et al.   INORGANIC CHEMISTRY

Aza- and Oxadithiolates Are Probable Proton Relays in Functional Models for the [FeFe]-Hydrogenases

(2008) Bryan E. Barton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dithiomethylether as a Ligand in the Hydrogenase H-Cluster

(2008) Arti S. Pandey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY