期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 47, 页码 17027-17034出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201603212
关键词
gold; nanoparticles; porphyrinoids; reduction; supported catalysts
资金
- National Natural Science Foundation of China [21276105]
- Fundamental Research Funds for the Central Universities [JUSRP51314B, JUSRP51513]
- project for Jiangsu scientific and technological innovation team
A hexagonal porphyrin-based porous organic polymer, namely, CPF-1, was constructed by 3+2 ketoenamine condensation of the C2-symmetric porphyrin diamine 5,15-bis(4-aminophenyl)-10,20-diphenylporphyrin and 1,3,5-triformylphloroglucinol. This material exhibits permanent porosity and excellent thermal and chemical stability. CPF-1 can be employed as a superior supporting substrate to immobilize Au nanoparticles (NPs) as a result of the strong interactions between Au NPs and the CPF support. An Au@CPF-1 hybrid was synthesized by an interfacial solution infiltration method with NaBH4 as reducing agent. Au NPs (5 nm) grew on CPF-1 and were distributed without aggregation. Moreover, Au@CPF-1 exhibits superior catalytic activity compared to many other reported Au-based catalysts for the reduction of 4-nitrophenol in the presence of NaBH4. In addition, Au@CPF-1 has excellent stability and recyclability, and it can be reused for three successive reaction cycles without loss of activity. The dense distribution of phenyl rings on the channel walls of the CPF support can reasonably be regarded as the active sites that adsorb the 4-nitrophenol molecule through hydrogen-bonding and C-H center dot center dot center dot pi interactions, as was confirmed by the X-ray structure of model compound DAPP-Benz.
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