4.6 Article

Magnetic Tuning of an Anionic CoII-MOF through Deionization of the Framework: Spin-Canting, Spin-Flop, and Easy-Plane Magnetic Anisotropy

期刊

CHEMISTRY-A EUROPEAN JOURNAL
卷 23, 期 4, 页码 767-772

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201604809

关键词

magnetic anisotropy; spin frustration; spin-canting; spin-flop; structural modification

资金

  1. National Basic Research Program of China (973 Program) [2012CB821702]
  2. National Natural Science Foundation of China [21233009, 21503230, 21571175]
  3. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences

向作者/读者索取更多资源

An anionic Co-II-MOF, (Me2NH2)[Co-3(Me2NH)(3)(OH)(SDBA)(3)] (1) (H(2)SDBA=4,4'-sulfonyldibenzoic acid) consisting of highly symmetric Co-3(II)(mu(3)-OH) triangles exhibits spin-canting, spin-flop, and easy-plane magnetic anisotropy. Measurement on a single crystal shows that the ab plane of 1 is the easy magnetization plane. After structural modification through simultaneous removal of the coordinated dimethylamine (DMA) molecule at the Co center and the ionic groups DMA(+) and OH-, the resulting neutral amorphous framework 2 displays an enhanced spin frustration effect. The deionization of 1 does not result in the collapse of the framework, showing the high stability of the backbone structure.

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