期刊
THERMOCHIMICA ACTA
卷 690, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.tca.2020.178650
关键词
Bulk metallic glasses; High entropy alloys; Crystallization kinetics; Activation energies; Local Avrami exponent
资金
- Hubei Provincial Natural Science Foundation of China [2018CFB576, 2018CFA003]
- National Science Foundation for Distinguished Young Scholars of China [51725504]
- Fundamental Research Funds for the Central Universities, HUST [2018KFYRCPT001]
- National Natural Science Foundation of China [51601063]
The crystallization kinetics of TiZrHfBe(Cu, Ni) high entropy bulk metallic glasses have been studied using differential scanning calorimetry. Each alloy possesses a complex multi-step crystallization process due to the high entropy effect. It was found that substitution of Cu by Ni significantly improves the glass-forming ability but deteriorates the thermal stability of the TiZrHfBeCu alloy. The activation energies of glass transition and crystallization together with the fragility parameter for the Ni-free and Ni-containing alloys have been calculated. According to the calculated values of local Avrami exponent, the first crystallization event for the studied TiZrHfBe(Cu, Ni) alloys is dominated by a direct growth of crystal nuclei. Substitution of Cu by Ni favors the precipitation of Ni-containing intermetallic compounds and inhibits the formation of CuHf2 phase, resulting in the improvement of glass-forming ability.
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