Article
Chemistry, Multidisciplinary
Liwei Dong, Shijie Zhong, Botao Yuan, Yaqiang Li, Jipeng Liu, Yuanpeng Ji, Dongjiang Chen, Yuanpeng Liu, Chunhui Yang, Jiecai Han, Weidong He
Summary: To address the short cyclic life issue of conventional anode-free Li-metal batteries (AFLMBs), SrI2 was introduced to effectively suppress dead Li accumulation by reactivating it through reversible I-/I-3(-) redox reaction. Additionally, a dielectric SEI surface with SrF2 and LiF was formed to prevent electrolyte decomposition, and a highly ionic conductive (3.488 mS cm(-1)) inner layer of SEI with abundant LiI enabled efficient Li+ transfer. With the SrI2-modified current collector, the NCM532/CP cell exhibited unprecedented cyclic performances with a capacity of 129.2 mAh g(-1) after 200 cycles.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Anirudha Jena, Zizheng Tong, Behrouz Bazri, Kevin Iputera, Ho Chang, Shu-Fen Hu, Ru-Shi Liu
Summary: Solid Li-ion conductors have the potential to enhance the performance of batteries by widening the cell-potential window and improving safety features. However, the development of all-solid-state batteries (ASSBs) faces challenges such as ion transport, interface reactions, and increased cell resistance. Advanced in situ/operando techniques are being used to explore and address these challenges.
JOURNAL OF PHYSICAL CHEMISTRY C
(2021)
Article
Chemistry, Physical
Xiancheng Wang, Yufang He, Shuibin Tu, Lin Fu, Zihe Chen, Shiyu Liu, Zhao Cai, Li Wang, Xiangming He, Yongming Sun
Summary: Anode-free batteries with high energy density have the issue of fast failure due to poor electrochemical reversibility. To solve this problem, researchers have constructed a stable lithium-metal alloy interphase that improves the stability between lithium deposits and current collector, enhancing the connection of lithium deposits. The technique achieves higher efficiency and stability in lithium plating/stripping cycles by forming a stable lithium-metal alloy during lithium deposition.
ENERGY STORAGE MATERIALS
(2022)
Article
Multidisciplinary Sciences
Can Cui, Hui Yang, Cheng Zeng, Siwei Gui, Jianing Liang, Ping Xiao, Shuhao Wang, Guxin Huang, Mingtao Hu, Tianyou Zhai, Huiqiao Li
Summary: The study investigates the lithium deposition behaviors on different metallic substrates using in situ micro-nano electrochemical scanning electron microscopy (SEM) manipulation platform. The research reveals distinct lithium deposition behaviors and identifies the factors that contribute to homogeneous lithium plating. The findings shed light on the design of solid-state batteries and provide a powerful SEM platform for future investigations.
Article
Biochemistry & Molecular Biology
Jie Chen, Linna Dai, Pei Hu, Zhen Li
Summary: One-step heat treatment of the Cu foil current collectors before cell assembly can improve the anode interphase and cycling stability of the anode-free lithium metal battery (AFLMB), leading to slower Li consumption and enhanced capacity retention.
Article
Engineering, Environmental
Suji Kim, Minjae Lee, Sekwon Oh, Won-Hee Ryu
Summary: In this study, a 3D interconnected porous Cu foam electrode was used to suppress the vertical growth of Li and alleviate the volume change of the cell in an anode-free Li-metal battery. The electrode exhibited facile charge transfer, lower nucleation overpotential, and reduced polarization compared to conventional Cu foil. The Li plating/stripping behaviors and morphology evolution on the unique electrode were investigated through cross-sectional observations and ex-situ characterizations. This work provides a novel strategy for designing porous electrodes to achieve stable and high performance of anode-free Li-metal batteries.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Li-Min Wang, Xiao-Kuan Ban, Zong-Zi Jin, Ran-Ran Peng, Chu-Sheng Chen, Chun-Hua Chen
Summary: By coating copper oxide on a unique biporous copper scaffold, the study achieved stabilization of lithium metal anodes, significantly reducing nucleation barriers and improving coulombic efficiency.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Multidisciplinary
Xiaohong Wu, Ben Niu, Yonglin Tang, Haiyan Luo, Zhengang Li, Xiaoyu Yu, Xin Wang, Chunhai Jiang, Yu Qiao, Shi-Gang Sun
Summary: In this study, a polymer additive called PAMMA was used as a sacrificial agent, which was found to promote the formation of a dense and Li3N-rich SEI film on the Li-metal surface in Li-O-2 batteries. This additive effectively suppressed the shuttle effect from harmful species, leading to improved cycling performance and protection of Li-metal.
Article
Chemistry, Physical
Junghwan Kim, Gyeong Ryul Lee, Roy Byung Kyu Chung, Patrick Joohyun Kim, Junghyun Choi
Summary: In order to enhance the electrochemical stability and high-rate performance of Li-metal batteries (LMBs), we studied the effect of surface-modified current collectors on the morphology of Li deposition. The results showed that the lithiatable layer improved the wetting ability of the electrolyte, reduced the interfacial resistance between the electrode and the electrolyte, and induced homogeneous Li nucleation, leading to uniform Li deposition on the surface of the current collector. As a result, the anode-free cells with surface-modified current collectors exhibited excellent cycle stability compared to those with conventional Cu current collectors.
ENERGY STORAGE MATERIALS
(2023)
Article
Engineering, Environmental
Kejin Jiao, Shujie Liu, Yanyan Ma, Shuo Chen, Liying Wei, Jianhua Yan
Summary: In this article, we report a dual strategy of using electronic conductive black TiO2-x nanofiber films to construct composite Li-metal anodes with stable 3D networks and applying an in-situ polymerized ionic conductive gel-electrolyte to construct efficient quasi-solid-state Li-batteries (QSSLBs). The 3D nanofibrous Li-anode shows a stable and small nucleation barrier and can run stably (>1600 h) at a high current density of 10 mA/cm(2). The QSSLBs exhibit excellent long-term cycling stability (>500 cycles) and high-rate capability (>1 C) when matched with high-loading cathodes of LiFePO4, showing potential commercial prospects.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Chemical
Tianbiao Zeng, Weishan Tang, Zihan Song, Li Zeng, Dan Luo, Hanna He, Chuhong Zhang
Summary: In this study, a high mass loading electrode of an in situ grown GeP nanobar array on carbon cloth was fabricated for flexible lithium/sodium ion batteries using an innovative vacuum melting-vapor deposition method. The electrode exhibited excellent electrochemical performance, with high ion diffusion, fast electron transfer, and sufficient electrolyte infiltration, as well as effectively alleviating the volume change and aggregation of GeP during cycling.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Chemistry, Physical
S. Y. Zhu, Y. F. Yuan, P. F. Du, M. Zhu, Y. B. Chen, S. Y. Guo
Summary: This study focuses on improving the lithium storage performance of MnS by addressing its low conductivity and volume variation issues through a novel synthesis strategy and composite structure. The composite material consists of alpha-MnS nanoparticles grown within a 3D macroporous honeycomb carbon framework. The composite demonstrates enhanced specific capacity, cycling durability, and rate capability, as well as excellent kinetics properties, thanks to the smart design of the confined alpha-MnS nanoparticles.
APPLIED SURFACE SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Jingbo Wang, Li Cao, Songyuan Li, Jiejie Xu, Rongshi Xiao, Ting Huang
Summary: In this study, a femtosecond laser was used to texture Cu foils, successfully reducing the peeling and cracking phenomenon in Si anodes and mitigating volume expansion. The hierarchical structure reduced interfacial resistance and promoted electron transfer, leading to improved cycling stability and rate capability of the Si anode.
Article
Chemistry, Multidisciplinary
Hansen Wang, Zhiao Yu, Xian Kong, William Huang, Zewen Zhang, David G. Mackanic, Xinyi Huang, Jian Qin, Zhenan Bao, Yi Cui
Summary: Novel electrolyte designs, including fluorinated 1,6-dimethoxyhexane and 1,2-dimethoxyethane as solvent molecules, along with lithium bis(fluorosulfonyl)imide, enable high-performance lithium metal batteries with improved stability and ionic conductivity. The use of a dual-solvent system contributes to the anion-derived solid-electrolyte interphase and enhances the overall battery performance.
ADVANCED MATERIALS
(2021)
Article
Polymer Science
Mir Waqas Alam, Amal BaQais, Mohammed M. Rahman, Muhammad Aamir, Alaaedeen Abuzir, Shehla Mushtaq, Muhammad Nasir Amin, Muhammad Shuaib Khan
Summary: In this study, carbon-coated ZnFe2O4 was successfully synthesized and the results showed that carbon coating can effectively alleviate the volume expansion problem of ZnFe2O4 during charging and discharging, thus improving the electrochemical performance of the battery.
Article
Chemistry, Multidisciplinary
Hsinhan Tsai, Shreetu Shrestha, Lei Pan, Hsin-Hsiang Huang, Joseph Strzalka, Darrick Williams, Leeyih Wang, Lei R. Cao, Wanyi Nie
Summary: The authors report a solution method to produce high-quality quasi-2D perovskite crystalline layers and detectors suitable for X-ray imaging. The photodiodes built with the quasi-2D layers exhibit low dark current and stable operation, and the detector shows a high sensitivity to X-ray. High-resolution images can be obtained using a single pixel device.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Physical
Zhenghuan Tang, Junbin Choi, Jose L. Lorie Lopez, Anne C. Co, Christopher J. Brooks, Jay R. Sayre, Jung-Hyun Kim
Summary: In this study, a systematic experimental design was used to optimize the synthesis parameters for a lithium borate (LBO) interlayer, aiming to address potential issues in garnet-based solid-state lithium metal batteries (SSLBs). The results showed that the LBO interlayer enhanced lithium metal wetting, increased interfacial conductivity, and improved the performance and safety of SSLBs.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Inorganic & Nuclear
Qiao Liu, Nicole Hoefer, Grant Berkbigler, Zhihao Cui, Tianyu Liu, Anne C. Co, David W. McComb, Casey R. Wade
Summary: A novel Zn benzotriazolate metal-organic framework with strong CO2 adsorption capacity has been synthesized and characterized. The framework exhibits high desorption temperature.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Qiao Liu, Sung Gu Cho, Jordon Hilliard, Ting-Yuan Wang, Szu-Chia Chien, Li-Chiang Lin, Anne C. Co, Casey R. Wade
Summary: The metal-organic framework MFU-4 shows remarkable performance in CO2/C2H2 separation, allowing the generation of high purity C2H2 and reversible selectivity with an analogue MFU-4-F. MFU-4-F also exhibits high C2H2 adsorption capacity, enabling the harvest of fuel grade C2H2 from C2H2/CO2 mixtures by room temperature desorption.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Multidisciplinary Sciences
Jacqueline M. M. Anderson, Amber A. A. Boardman, Rhiannon Bates, Xunchang Zou, Wei Huang, Lei Cao
Summary: Enriched environment (EE) improves metabolic and behavioral outcomes in BTBR mice, potentially through the BDNF-TrkB signaling pathway. Overexpression of TrkB.FL BDNF receptor in the hypothalamus of BTBR mice improves metabolic phenotypes but does not affect behavioral deficits.
Article
Nuclear Science & Technology
Carol Smidts, Gustavo Reyes, Cassiano Endres de Oliveira, Lei Raymond Cao
Summary: This paper discusses the research challenges of nuclear security and safeguards posed by nuclear fission batteries, which are easily transportable and deployable nuclear systems. It analyzes the impact on domestic and international safeguards and security and identifies gaps in technology development for practical deployment. The study highlights the need for comprehensive cyber tools and security considerations from the design phase.
PROGRESS IN NUCLEAR ENERGY
(2023)
Article
Chemistry, Multidisciplinary
Matthew Ferree, Seval Gunduz, Jaesung Kim, Raymond LaRosa, Yehia Khalifa, Anne C. Co, Umit S. Ozkan
Summary: Electrochemical routes for ammonia synthesis offer benefits such as improved efficiency and compatibility with renewable energy sources. In this study, a composite cathode was fabricated and studied for its ability to produce ammonia through the nitrogen reduction reaction. The composite cathode exhibited significantly enhanced activity compared to pure phase electrodes, and the relevant properties of the composite were characterized through various techniques.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Chemistry, Physical
Ruiyang Lyu, Zhihao Cui, Jocelyn Elgin, Anne C. Co, Yiying Wu
Summary: In this study, a stable unprotected photoelectrode, methylviologen lead iodide (MVPb2I6), was used in the semiconductor photoelectrochemistry (PEC) system of organic-inorganic halide perovskites (OIHPs) in polar solvents. The MVPb2I6 exhibits stability and suitable solar absorber band gap for PEC reactions in polar solution. The energetic properties of MVPb2I6 were determined by cyclic voltammetry, and the degradation mechanism due to photoreduction was studied using SEM and RRDE techniques.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Materials Science, Multidisciplinary
Hsinhan Tsai, Lei Pan, Xinxin Li, Jinkyoung Yoo, Sergei Tretiak, Xuedan Ma, Lei R. Cao, Wanyi Nie
Summary: The study reports a perovskite polycrystalline thin film detector fabricated by solution method, which is a low-cost, scalable technology for radiation imaging. However, the thin volume of the detector limits its sensing efficiency for high-energy X-ray photons. Detailed characterizations reveal that a charge multiplication effect is responsible for the observed high gain. The study also identifies that the use of butylamine spacers in the 2D perovskite thin film leads to a larger efficiency gain compared to phenylethylamines.
ADVANCED OPTICAL MATERIALS
(2023)
Proceedings Paper
Optics
Daryl Giglio, Sha Xue, Katie Hoffman, Praneeth Kandlakunta, Herny Spitz, Vasil Hlinka, Lei R. Cao
Summary: In this study, SiC Schottky diodes fabricated in-house were used to investigate the durability and radiation damage of the devices through electrodeposition of alpha emitting actinide Am-241. The results showed a degradation in the alpha particles' energy spectrum, which could be reversed by optical excitation. In addition, device performance was simulated using Allpix(2). This research provides insights into the potential use of 4H-SiC as an energy converter and its survivability in harsh environments.
HARD X-RAY, GAMMA-RAY, AND NEUTRON DETECTOR PHYSICS XXIV
(2022)
Proceedings Paper
Optics
Ibrahim Oksuz, Matt Bisbee, Nerine Cherepy, Joe Tringe, Andrew Townsend, James Hall, Lei Cao
Summary: Neutron radiography and computed tomography are effective tools for nondestructive investigation of internal structures of complex multi-material objects. Thermal neutrons are more effective at producing high-contrast radiographs of objects composed of elements with relatively low atomic numbers.
HARD X-RAY, GAMMA-RAY, AND NEUTRON DETECTOR PHYSICS XXIV
(2022)
Meeting Abstract
Biotechnology & Applied Microbiology
Nicholas J. Queen, Jacqueline M. Anderson, Wei Huang, Xunchang Zou, Bhavya Appana, Suraj Komatineni, Rhiannon Bates, Lei Cao
Meeting Abstract
Biotechnology & Applied Microbiology
Lluis Samaranch, Allison Clark, Matthew Rocco, Meika Travis, Wei Huang, Piotr Hadaczek, Victor Van Laar, Lei Cao, Krystof Bankiewicz
Meeting Abstract
Biotechnology & Applied Microbiology
Asad S. Akhter, Lluis Samaranch, Matthew Rocco, Allison Clark, Meika Travis, Wei Huang, Piotr Hadeczek, Victor Van Laar, Lei Cao, Krystof Bankiewicz
Meeting Abstract
Biotechnology & Applied Microbiology
Piotr Hadaczek, Wei Huang, Lluis Samaranch, Meika Travis, Allison Clark, Matthew Rocco, Victor Van Laar, Lei Cao, Krystof Bankiewicz