To rebound or dissociate? This is the mechanistic question in C–H hydroxylation by heme and nonheme metal–oxo complexes

Interplay of Experiment and Theory in Elucidating Mechanisms of Oxidation Reactions by a Nonheme RuIVO Complex

(2015) Sunder N. Dhuri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic insight into the hydroxylation of alkanes by a nonheme iron(v)–oxo complex

(2014) Eunji Kwon et al.   CHEMICAL COMMUNICATIONS

How and Why Do Cluster Size, Charge State, and Ligands Affect the Course of Metal-Mediated Gas-Phase Activation of Methane?

(2014) Helmut Schwarz   ISRAEL JOURNAL OF CHEMISTRY

Formation of a Room Temperature Stable FeV(O) Complex: Reactivity Toward Unactivated C–H Bonds

(2014) Munmun Ghosh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Insights into the C–H Bond Activation of Hydrocarbons by Chromium(IV) Oxo and Chromium(III) Superoxo Complexes

(2013) Kyung-Bin Cho et al.   INORGANIC CHEMISTRY

Theoretical Investigations into C–H Bond Activation Reaction by Nonheme MnIVO Complexes: Multistate Reactivity with No Oxygen Rebound

(2012) Kyung-Bin Cho et al.   Journal of Physical Chemistry Letters

A Chromium(III)–Superoxo Complex in Oxygen Atom Transfer Reactions as a Chemical Model of Cysteine Dioxygenase

(2012) Jaeheung Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evidence for an Alternative to the Oxygen Rebound Mechanism in C–H Bond Activation by Non-Heme FeIVO Complexes

(2012) Kyung-Bin Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Modeling the cis-Oxo-Labile Binding Site Motif of Non-Heme Iron Oxygenases: Water Exchange and Oxidation Reactivity of a Non-Heme Iron(IV)-Oxo Compound Bearing a Tripodal Tetradentate Ligand

(2011) Anna Company et al.   CHEMISTRY-A EUROPEAN JOURNAL

Modeling C–H Abstraction Reactivity of Nonheme Fe(IV)O Oxidants with Alkanes: What Role Do Counter Ions Play?

(2011) Deepa Janardanan et al.   Journal of Physical Chemistry Letters

Formation of a Ruthenium(IV)-Oxo Complex by Electron-Transfer Oxidation of a Coordinatively Saturated Ruthenium(II) Complex and Detection of Oxygen-Rebound Intermediates in C–H Bond Oxygenation

(2011) Takahiko Kojima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Reactive Mononuclear Non-Heme Manganese(IV)–Oxo Complex That Can Activate the Strong C–H Bonds of Alkanes

(2011) Xiujuan Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nonheme oxo-iron(IV) intermediates form an oxyl radical upon approaching the C-H bond activation transition state

(2011) S. Ye et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Manganese Catalysts for C−H Activation: An Experimental/Theoretical Study Identifies the Stereoelectronic Factor That Controls the Switch between Hydroxylation and Desaturation Pathways

(2010) Jonathan F. Hull et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exchange-enhanced reactivity in bond activation by metal–oxo enzymes and synthetic reagents

(2010) Sason Shaik et al.   Nature Chemistry

Cytochrome P450 Compound I: Capture, Characterization, and C-H Bond Activation Kinetics

(2010) J. Rittle et al.   SCIENCE

P450 Enzymes: Their Structure, Reactivity, and Selectivity—Modeled by QM/MM Calculations

(2009) Sason Shaik et al.   CHEMICAL REVIEWS

Hydrogen-Atom Abstraction Reactions by Manganese(V)- and Manganese(IV)-Oxo Porphyrin Complexes in Aqueous Solution

(2009) Chellaiah Arunkumar et al.   CHEMISTRY-A EUROPEAN JOURNAL