期刊
CHEMICAL PHYSICS LETTERS
卷 662, 期 -, 页码 152-155出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2016.09.017
关键词
Coordinatively saturated cobalt(III) complex; Molecular catalyst; Proton or water reduction; Hydrogen generation
资金
- National Science Foundation of China [20971045, 21271073]
- Fundamental Research Funds for the Central Universities [2015ZZ046]
As we know, coordinatively unsaturated complexes can catalyze hydrogen generation via an unstable hydride intermediate. In this paper, we report an electrocatalyst based on a water soluble coordinatively saturated complex, [(phen)(2)Co(CN)(2)]center dot NO3 1 that is formed by the reaction of 1,10-phenanthroline (phen), Co(NO3)(2)center dot 6H(2)O and tetracyanoethylene (TCNE). Its structure has been characterized by physics-chemical and spectroscopic methods. Complex 1 can electrocatalyze hydrogen evolution both from acetic acid and aqueous buffer. (C) 2016 Elsevier B.V. All rights reserved.
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