4.7 Article

Intensification of ozonation processes in a novel, compact, multi-orifice oscillatory baffled column

期刊

CHEMICAL ENGINEERING JOURNAL
卷 296, 期 -, 页码 335-339

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2016.03.050

关键词

Multi-orifice oscillatory baffled column; Ozonation; p-Hydroxybenzoic acid; Process intensification; Water and wastewater treatment

资金

  1. Enterprise Office
  2. Enterprise Project Group of Loughborough University [EPG55-P4, EPG64-P2]

向作者/读者索取更多资源

A novel approach for the intensification of ozonation of water and wastewater is presented using a highly efficient and compact multi-orifice oscillatory baffled column (MOBC) ozonation contactor. The MOBC uniquely yielded full (i.e. 100%) use of the ozone supplied with a very short (2.25 min) liquid contact time under continuous operation and reducing the need of further gas-liquid contacting equipment downstream from the MOBC. The increased performance of the MOBC ozonation reactor was benchmarked against a bubble column (BC) design and resulted in 20% increase on the rate of p-hydroxybenzoic acid (p-HBA) degradation, 75% increase in the rate of mineralisation of p-HBA per mole of ozone consumed, and 4.5-5.0-fold increase in the rate of mineralisation of p-HBA per mole of ozone supplied. This results from the very small size of bubbles (few hundreds of microns) and enhanced gas-liquid mass transfer and hold-up generated in the presence of small fluid pulsations and orifice baffles. (C) 2016 Elsevier B.V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Multidisciplinary

Antibody Surface Coverage Drives Matrix Interference in Microfluidic Capillary Immunoassays

Ana Barbosa, Alexander D. Edwards, Nuno M. Reis

Summary: This study conducted a systematic analysis using hundreds of actual microfluidic immunoassay fluoropolymer strips to investigate matrix interference in microflow systems. The experiment revealed that the key factor affecting serum matrix interference is capillary antibody surface coverage. A new approach for eliminating and/or minimizing serum matrix interference was proposed, focusing on antibody surface coverage and sample incubation times.

ACS SENSORS (2021)

Article Engineering, Environmental

Selective photocatalytic synthesis of benzaldehyde in microcapillaries with immobilized carbon nitride

Maria J. Lima, Adrian M. T. Silva, Claudia G. Silva, Joaquim L. Faria, Nuno M. Reis

Summary: Photocatalysis on microfluidic reactors offers a more environmentally friendly approach to traditional chemical synthesis, aiming to produce high value-added molecules selectively and efficiently. This study demonstrated the use of a fluoropolymer microcapillary system with an immobilized metal-free thermal modified carbon nitride catalyst for the selective photocatalytic synthesis of Benzaldehyde (BAL). The immobilized catalyst showed similar performance to suspended catalysts, with enhanced efficiency and the ability for reuse, making it a promising strategy for future applications.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Engineering, Environmental

Fast prototyping using 3D printed templates and flexible fluoropolymer microcapillary films offers enhanced micromixing in immobilised (bio) catalytic reactions

Kirandeep K. Gill, Zhengchun Liu, Nuno M. Reis

Summary: This study presents a novel approach in fabricating inexpensive non-linear microstructure prototypes using a flexible fluoropolymer microcapillary film and 3D printed templates, which enhance mass transfer efficiency in microreactors. By evaluating different micromixer structures and experimental validation, significant insights into fluid flow distribution were gained.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Multidisciplinary

Gravity-Driven Microfluidic Siphons: Fluidic Characterization and Application to Quantitative Immunoassays

Nuno M. Reis, Sarah H. Needs, Sophie M. Jegouic, Kirandeep K. Gill, Sirintra Sirivisoot, Scott Howard, Jack Kempe, Shaan Bola, Kareem Al-Hakeem, Ian M. Jones, Tanapan Prommool, Prasit Luangaram, Panisadee Avirutnan, Chunya Puttikhunt, Alexander D. Edwards

Summary: A range of biosensing techniques, including immunoassays, are used for quantitation of analytes in biological samples. High analytical performance is linked to the use of reagent and washing steps, which can be challenging to deliver in point-of-care testing without a high level of fluidic control.

ACS SENSORS (2021)

Article Engineering, Chemical

Treatment of Winery Wastewater with a Combination of Adsorption and Thermocatalytic Processes

Nuno Jorge, Ana R. Teixeira, Vanessa Guimaraes, Marco S. Lucas, Jose A. Peres

Summary: This study investigated a treatment process combining adsorption and thermocatalytic oxidation for winery wastewater. By optimizing the operational conditions, high removal efficiencies of organic carbon, chemical oxygen demand, and polyphenols were achieved. Additionally, the effect of the treatment processes on the germination index of plant seeds was evaluated.

PROCESSES (2022)

Article Environmental Sciences

Food By-Product Valorization by Using Plant-Based Coagulants Combined with AOPs for Agro-Industrial Wastewater Treatment

Rita Beltrao Martins, Nuno Jorge, Marco S. Lucas, Anabela Raymundo, Ana I. R. N. A. Barros, Jose A. Peres

Summary: This study investigates the use of plant by-products as coagulants for treating elderberry wastewater, with promising results obtained after optimization. The combination of plant-based coagulants and the photo-Fenton process provides a potential strategy for effective wastewater treatment.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL RESEARCH AND PUBLIC HEALTH (2022)

Article Chemistry, Applied

Textile Dye Removal by Acacia dealbata Link. Pollen Adsorption Combined with UV-A/NTA/Fenton Process

Ana R. Teixeira, Nuno Jorge, Jose R. Fernandes, Marco S. Lucas, Jose A. Peres

Summary: This study investigated the decolourization of a textile dye and the control of an invasive plant species using a combination of pollen adsorption and UV-A-Fenton process. The results showed that the combination of biosorption and NTA-UV-A-Fenton was the most efficient system, achieving a high decolourization rate and organic carbon removal.

TOPICS IN CATALYSIS (2022)

Article Engineering, Chemical

A microfluidic serial dilutor (MSD): Design optimization and application to tuning of liposome nanoparticle preparation

Huanhuan Shi, Zhihao Xie, Yu Cao, Yali Zhao, Congxuan Zhang, Zhen Chen, Nuno M. Reis, Zhengchun Liu

Summary: This study presents a microfluidic serial dilutor (MSD) capable of generating fast serial dilution of a sample up to 4 orders of magnitude. The design is characterized experimentally and using Computational Fluid Dynamics (CFD), showing simplicity and reliability. The MSD is integrated with a new absorbance measuring device, allowing evaluation of the dilution performance and confirmation of the design effectiveness. The MSD is applied in the synthesis of liposome nanoparticles, enabling precise control of drug and vaccine delivery microcarriers.

CHEMICAL ENGINEERING SCIENCE (2022)

Article Environmental Sciences

Combined organic coagulants and photocatalytic processes for winery wastewater treatment

Nuno Jorge, Ana R. Teixeira, Marco S. Lucas, Jose A. Peres

Summary: Due to the consumers' demand for quality wines, the production of winery wastewater with a high organic content poses potential environmental impacts. This study introduces the production of natural organic coagulants and their application in the coagulation-flocculation-decantation process, accompanied by a photo-Fenton process using hydrogen peroxide and potassium persulfate. The results demonstrate effective removal of turbidity, total suspended solids, and dissolved organic carbon from the wastewater. Furthermore, the combination of the two processes reduces operational costs and ensures compliance with wastewater discharge standards.

JOURNAL OF ENVIRONMENTAL MANAGEMENT (2023)

Article Environmental Sciences

Degradation of Agro-Industrial Wastewater Model Compound by UV-A-Fenton Process: Batch vs. Continuous Mode

Nuno Jorge, Ana R. Teixeira, Jose R. Fernandes, Ivo Oliveira, Marco S. Lucas, Jose A. Peres

Summary: The degradation of caffeic acid in model agro-industrial wastewater was studied using a UV-A-Fenton system. Batch experiments showed that pH 3.0 achieved higher generation of HO center dot and thus higher caffeic acid degradation (>99.5%). The effects of H2O2 and Fe2+ concentrations were evaluated, and a pseudo first-order kinetic model was found to fit the results. Continuous mode experiments were performed at different flow rates, showing that increasing the flow rate resulted in significantly higher removal rates of caffeic acid and dissolved organic carbon (DOC). It is concluded that continuous modes are advantageous for treating real agro-industrial wastewaters.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL RESEARCH AND PUBLIC HEALTH (2023)

Article Environmental Sciences

Enhancement of EDDS-photo-Fenton process with plant-based coagulants for winery wastewater management

Nuno Jorge, Ana R. Teixeira, Marco S. Lucas, Jose A. Peres

Summary: In this study, a physical-chemical process combining plant-based coagulants (PBCs) with advanced oxidation processes (AOPs) was investigated for efficient remediation of winery wastewater (WW) to meet Portuguese legal limits. The combination of Platanus acerif 'olia (P.a.) seeds with polyvinylpolypyrrolidone (PVPP) achieved high turbidity (97.3%) and chemical oxygen demand (COD = 48.2%) removals. Different AOPs were studied, and the photo-Fenton process showed the highest COD removal efficiency (88.0%). Pre-treatment of WW by PBCs followed by EDDS/photo-Fenton further increased COD removal, reaching 95.7% COD removal and improving biodegradability.

ENVIRONMENTAL RESEARCH (2023)

Review Chemistry, Physical

Bioenergy Production from Agro-Industrial Wastewater Using Advanced Oxidation Processes as Pre-Treatment

Ana Gomes, Amadeu Borges, Jose A. Peres, Marco S. Lucas

Summary: Agro-industrial activities generate large volumes of wastewater, which can cause serious environmental problems if discharged without proper treatment. Advanced oxidation processes (AOPs) have been increasingly used as a pre-treatment in bioenergy production to enhance the biodegradability of wastewater and increase the production of biogas, biodiesel, and bioethanol. Different AOPs, such as wet air oxidation, sonolysis, and ozonation, have shown promise in the pre-treatment of agro-industrial wastewater. However, obstacles such as high energy requirements and chemical reagents costs need to be addressed for the cost-effective application of AOPs in bioenergy production.

CATALYSTS (2023)

Article Environmental Sciences

Winery and olive mill wastewaters treatment using nitrilotriacetic acid/ UV-C/Fenton process: Batch and semi-continuous mode

Ana R. Teixeira, Nuno Jorge, Marco S. Lucas, Jose A. Peres

Summary: In this study, the treatment of red and white winery wastewaters and olive mill wastewater using Fenton-based processes was investigated. The results showed that UV-C/Fenton was the most effective process, and operational conditions such as pH, H2O2 and Fe2+ concentrations played a significant role in dissolved organic carbon (DOC) removal and the energy consumption of the reactor. Addition of nitrilotriacetic acid (NTA) was tested to prevent iron precipitation. Comparative experiments in a semi-continuous reactor demonstrated the potential application of this process on a large scale, with low reagents consumption and reduced energy requirements.

ENVIRONMENTAL RESEARCH (2024)

Article Green & Sustainable Science & Technology

Agro-Industrial Wastewater Treatment with Acacia dealbata Coagulation/Flocculation and Photo-Fenton-Based Processes

Nuno Jorge, Ana R. Teixeira, Marco S. Lucas, Jose A. Peres

Summary: This study evaluated the removal of dissolved organic carbon (DOC) and total polyphenols (TPh) from agro-industrial wastewater using coagulation-flocculation-decantation (CFD) and Fenton-based processes. The results showed that both CFD and Fenton-based processes achieved high removal efficiencies. The combination of both processes achieved near complete removal of TPh and DOC with high energy efficiency.

RECYCLING (2022)

Article Biochemical Research Methods

Label-free 1D microfluidic dipstick counting of microbial colonies and bacteriophage plaques

Sultan Ilayda Donmez, Sarah H. Needs, Helen M. I. Osborn, Nuno M. Reis, Alexander D. Edwards

Summary: Counting viable bacterial cells and functional bacteriophage is crucial in microbiology research and applications. This study presents a rapid and simple method for counting colony forming units (CFU) and plaque forming units (PFU) using dip-stick microfluidic strips combined with digital imaging. The results obtained using this method showed full quantitative agreement with traditional solid agar Petri dish counting, but with a significantly reduced time. The innovation of 1-dimensional colony counting in microfluidics provides new insights into colony growth and has potential applications in microbial analysis.

LAB ON A CHIP (2022)

Article Engineering, Environmental

A metal-phenolic network-assembled nanotrigger evokes lethal ferroptosis via self-supply loop-based cytotoxic reactions

Xinping Zhang, Yuxin Guo, Xiaoyang Liu, Shun-Yu Wu, Ya-Xuan Zhu, Shao-Zhe Wang, Qiu-Yi Duan, Ke-Fei Xu, Zi-Heng Li, Xiao-Yu Zhu, Guang-Yu Pan, Fu-Gen Wu

Summary: This study develops a nanotrigger HCFT for simultaneous photodynamic therapy and light-triggered ferroptosis therapy. The nanotrigger can relieve tumor hypoxia, induce enhanced photodynamic reaction, and facilitate the continuation of Fenton reaction, ultimately leading to lethal ferroptosis in tumor cells.

CHEMICAL ENGINEERING JOURNAL (2024)

Article Engineering, Environmental

XAS and DFT investigation of atomically dispersed Cu/Co alloyed Pt local structures under selective hydrogenation of acetylene to ethylene

Olumide Bolarinwa Ayodele, Toyin Daniel Shittu, Olayinka S. Togunwa, Dan Yu, Zhen-Yu Tian

Summary: This study focused on the semihydrogenation of acetylene in an ethylene-rich stream using two alloyed Pt catalysts PtCu and PtCo. The PtCu catalyst showed higher activity and ethylene yield compared to PtCo due to its higher unoccupied Pt d-orbital density. This indicates that alloying Pt with Cu is more promising for industrial relevant SHA catalyst.

CHEMICAL ENGINEERING JOURNAL (2024)

Article Engineering, Environmental

A multifunctional emitter with synergistical adjustment of rigidity and flexibility for high-performance data-recording and organic light-emitting devices with hot exciton channel

Guowei Chen, Wen-Cheng Chen, Yaozu Su, Ruicheng Wang, Jia-Ming Jin, Hui Liang, Bingxue Tan, Dehua Hu, Shaomin Ji, Hao-Li Zhang, Yanping Huo, Yuguang Ma

Summary: This study proposes an intramolecular dual-locking design for organic luminescent materials, achieving high luminescence efficiency and performance for deep-blue organic light-emitting diodes. The material also exhibits unique mechanochromic luminescence behavior and strong fatigue resistance.

CHEMICAL ENGINEERING JOURNAL (2024)

Article Engineering, Environmental

Cobalt/nickel purification by solvent extraction with ionic liquids in millifluidic reactors: From single-channel to numbered-up configuration with solvent recycle

Joren van Stee, Gregory Hermans, Jinu Joseph John, Koen Binnemans, Tom Van Gerven

Summary: This work presents a continuous solvent extraction method for the separation of cobalt and nickel in a millifluidic system using Cyphos IL 101 (C101) as the extractant. The optimal conditions for extraction performance and solvent properties were determined by investigating the effects of channel length, flow rate, and temperature. The performance of a developed manifold structure was compared to a single-channel system, and excellent separation results were achieved. The continuous separation process using the manifold structure resulted in high purity cobalt and nickel products.

CHEMICAL ENGINEERING JOURNAL (2024)

Article Engineering, Environmental

Environment-triggered nanoagent with programmed gas release performance for accelerating diabetic infected wound healing

Yan Xu, Jingai Jiang, Xinyi Lv, Hui Li, Dongliang Yang, Wenjun Wang, Yanling Hu, Longcai Liu, Xiaochen Dong, Yu Cai

Summary: A programmed gas release nanoparticle was developed to address the challenges in treating diabetic infected wounds. It effectively removes drug-resistant pathogens and remodels the wound microenvironment using NO and H2S. The nanoparticle can eliminate bacteria and promote wound healing through antibacterial and anti-inflammatory effects.

CHEMICAL ENGINEERING JOURNAL (2024)

Article Engineering, Environmental

Synergistic dopa-reinforced fluid hydrosol as highly efficient coal dust suppressant

Tong Xia, Zhilin Xi, Lianquan Suo, Chen Wang

Summary: This study investigated a highly efficient coal dust suppressant with low initial viscosity and high adhesion-solidification properties. The results demonstrated that the dust suppressant formed a network of multiple hydrogen bonding cross-linking and achieved effective adhesion and solidification of coal dust through various chemical reactions.

CHEMICAL ENGINEERING JOURNAL (2024)

Article Engineering, Environmental

First principle-based rate equation theory for the carbonation kinetics of CaO with CO2 in calcium looping

Jinzhi Cai, Zhenshan Li

Summary: A density functional theory-based rate equation was developed to predict the gas-solid reaction kinetics of CaO carbonation with CO2 in calcium looping. The negative activation energy of CaO carbonation close to equilibrium was accurately predicted through experimental validation.

CHEMICAL ENGINEERING JOURNAL (2024)

Article Engineering, Environmental

Significant enhancement of high-temperature capacitive energy storage in dielectric films through surface self-assembly of BNNS coatings

Jianxiong Chen, Fuhao Ren, Ningning Yin, Jie Mao

Summary: This study presents an economically efficient and easily implementable surface modification approach to enhance the high-temperature electrical insulation and energy storage performance of polymer dielectrics. The self-assembly of high-insulation-performance boron nitride nanosheets (BNNS) on the film surface through electrostatic interactions effectively impedes charge injection from electrodes while promoting charge dissipation and heat transfer.

CHEMICAL ENGINEERING JOURNAL (2024)

Article Engineering, Environmental

Medium entropy metal oxide induced *OH species targeted transfer strategy for efficient polyethylene terephthalate plastic recycling

Zijian Li, Zhaohui Yang, Shao Wang, Hongxia Luo, Zhimin Xue, Zhenghui Liu, Tiancheng Mu

Summary: This study reports a strategy for upgrading polyester plastics into value-added chemicals using electrocatalytic methods. By inducing the targeted transfer of *OH species, polyethylene terephthalate was successfully upgraded into potassium diformate with high purity. This work not only develops an excellent electrocatalyst, but also provides guidance for the design of medium entropy metal oxides.

CHEMICAL ENGINEERING JOURNAL (2024)

Article Engineering, Environmental

A novel environmental friendly and sustainable process for textile dyeing with sulphur dyes for cleaner production

Navneet Singh Shekhawat, Surendra Kumar Patra, Ashok Kumar Patra, Bamaprasad Bag

Summary: This study primarily focuses on developing a sulphur dyeing process at room temperature using bacterial Lysate, which is environmentally friendly, energy and cost effective, and sustainable. The process shows promising improvements in dye uptake and fastness properties.

CHEMICAL ENGINEERING JOURNAL (2024)

Article Engineering, Environmental

Highly efficient and sustainable cationic polyvinyl chloride nanofibrous membranes for removal of E. coli and Cr (VI): Filtration and adsorption

Dengjia Shen, Hongyang Ma, Madani Khan, Benjamin S. Hsiao

Summary: This study developed cationic PVC nanofibrous membranes with high filtration and adsorption capability for the removal of bacteria and hexavalent chromium ions from wastewater. The membranes demonstrated remarkable performance in terms of filtration efficiency and maximum adsorption capacity. Additionally, modified nanofibrous membranes were produced using recycled materials and showed excellent retention rates in dynamic adsorption processes.

CHEMICAL ENGINEERING JOURNAL (2024)

Article Engineering, Environmental

Concerted proton-coupled electron transfer promotes NiCoP nanowire arrays for efficient overall water splitting at industrial-level current density

Xiaoyan Wang, Zhikun Wang, Ben Jia, Chunling Li, Shuangqing Sun, Songqing Hu

Summary: Inspired by photosystem II, self-supported Fe-doped NiCoP nanowire arrays modified with carboxylate were constructed to boost industrial-level overall water splitting by employing the concerted proton-coupled electron transfer mechanism. The introduction of Fe and carboxyl ligand led to improved catalytic activity for HER and OER, and NCFCP@NF exhibited long-term durability for overall water splitting.

CHEMICAL ENGINEERING JOURNAL (2024)

Article Engineering, Environmental

Self-limiting growth of thin dense LTA membranes boosts H2 gas separation performance

Pengyao Yu, Ge Yang, Yongming Chai, Lubomira Tosheva, Chunzheng Wang, Heqing Jiang, Chenguang Liu, Hailing Guo

Summary: Thin LTA zeolite membranes were prepared through secondary growth of nano LTA seeds in a highly reactive gel, resulting in membranes with superior permeability and selectivity in gas separation applications.

CHEMICAL ENGINEERING JOURNAL (2024)

Article Engineering, Environmental

Prediction of phosphate adsorption amount, capacity and kinetics via machine learning: A generally physical-based process and proposed strategy of using descriptive text messages to enrich datasets

Baiqin Zhou, Huiping Li, Ziyu Wang, Hui Huang, Yujun Wang, Ruichun Yang, Ranran Huo, Xiaoyan Xu, Ting Zhou, Xiaochen Dong

Summary: The use of machine learning to predict the performance of specific adsorbents in phosphate adsorption shows great promise in saving time and revealing underlying mechanisms. However, the small size of the dataset and insufficient detailed information limits the model training process and the accuracy of results. To address this, the study employs a fuzzing strategy that replaces detailed numeric information with descriptive text messages on the physiochemical properties of adsorbents. This strategy allows the recovery of discarded samples with limited information, leading to accurate prediction of adsorption amount, capacity, and kinetics. The study also finds that phosphate uptake by adsorbents is generally through physisorption, with some involvement of chemisorption. The framework established in this study provides a practical approach for quickly predicting phosphate adsorption performance in urgent scenarios, using easily accessible information.

CHEMICAL ENGINEERING JOURNAL (2024)

Article Engineering, Environmental

Absorption of hydrophobic volatile organic compounds in renewable vegetable oils and esterified fatty acids: Determination of gas-liquid partitioning coefficients as a function of temperature

Paula Alejandra Lamprea Pineda, Joren Bruneel, Kristof Demeestere, Lisa Deraedt, Tex Goetschalckx, Herman Van Langenhove, Christophe Walgraeve

Summary: This study evaluates the use of four esterified fatty acids and three vegetable oils as absorption liquids for hydrophobic VOCs. The experimental results show that isopropyl myristate is the most efficient liquid for absorbing the target VOCs.

CHEMICAL ENGINEERING JOURNAL (2024)