期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 142, 期 21, 页码 9763-9771出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.0c02876
关键词
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资金
- National Natural Science Foundation of China [21690063, 21988101, 21801041]
- Shanghai Sailing Program [18YF1402000]
Enabled by the newly developed ligand, Ming-Phos, the first example of palladium-catalyzed highly enantioselective coupling of racemic propargylic benzoates with organoboronic acids for chiral allenes synthesis has been developed. Excellent asymmetric induction has been achieved with a decent substrate scope. Synthetic potentials for the construction of polycyclic compounds with multiple chiral centers have been demonstrated.
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