4.8 Article

Suit[4]ane

期刊

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 142, 期 23, 页码 10273-10278

出版社

AMER CHEMICAL SOC
DOI: 10.1021/jacs.0c03408

关键词

-

资金

  1. Northwestern University (NU)
  2. Soft and Hybrid Nanotechnology Experimental (SHyNE) Resource [NSF ECCS-1542205]
  3. MRSEC program at the Materials Research Center [NSF DMR-1720139]
  4. International Institute for Nanotechnology (IIN)
  5. Keck Foundation
  6. State of Illinois, through the IIN

向作者/读者索取更多资源

Suitanes are two-component mechanically interlocked molecules in which one (torso) of the components, with several protruding limbs, is encompassed by another (suit) all-in-one component. This kind of molecular ship-in-a-bottle architecture remains a challenging one to make. Herein, we report a porphyrin-based suit[4]ane, which is composed of a porphyrin with four protruding ligands (two phenyl groups and two bromine atoms) called the limbs that are encompassed by a tricyclic octacationic cyclophane. The suit[4]ane can be obtained by slippage, a mechanism by which the cyclophane is able to open up two of its entrances in order to take up the porphyrin at high temperature and close them down at low temperature, locking the porphyrin inside its binding cavity. Dynamic H-1 NMR spectroscopy reveals that the trapped porphyrin inside the cyclophane rocks back and forth in the suit[4]ane about 1000 times a second.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.8
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Review Chemistry, Multidisciplinary

The Story of the Little Blue Box: A Tribute to Siegfried Hunig

Xiao-Yang Chen, Hongliang Chen, J. Fraser Stoddart

Summary: The tetracationic cyclophane, known as the little blue box, is valuable in constructing stimuli-responsive materials by binding small pi-donors and forming complexes with viologen radical cations. Its significance in the discovery of host-guest complexes and mechanically interlocked molecules is highlighted.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

Article Chemistry, Multidisciplinary

Color-Tunable Upconversion-Emission Switch Based on Cocrystal- to-Cocrystal Transformation

Yu Wang, Huang Wu, Leighton O. Jones, Martin A. Mosquera, Charlotte L. Stern, George C. Schatz, J. Fraser Stoddart

Summary: Cocrystal engineering is a popular strategy for tuning the photophysical properties of crystalline materials. This study reports a color-tunable upconversion-emission switch based on the interconversion between two cocrystals. The research provides a critical example of precise control of cocrystal-to-cocrystal transformation and offers a reference for fabricating color tunable nonlinear optical materials in the solid state.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

Review Nanoscience & Nanotechnology

Reactions in single-molecule junctions

Hongliang Chen, Chuancheng Jia, Xin Zhu, Chen Yang, Xuefeng Guo, J. Fraser Stoddart

Summary: Developing new materials is a long-standing goal in various fields, and understanding single-molecule reactions can deepen our understanding of chemical reactions and provide new frameworks in materials science. This review focuses on state-of-the-art chemical reactions in single-molecule junctions and highlights the advantages of real-time testbeds for studying reaction dynamics, intermediates, transition states, and solvent effects. The behavior of single-molecule reactions is compared with reactions in ensemble states, and the potential of leveraging single-molecule catalysis for large-scale materials production is explored.

NATURE REVIEWS MATERIALS (2023)

Review Polymer Science

Sequence-controlled synthesis of rotaxanes

Han Han, James S. W. Seale, Liang Feng, Yunyan Qiu, J. Fraser Stoddart

Summary: Rotaxanes with well-defined ring sequences are attractive synthetic goals for constructing functional materials. Sequence-controlled synthesis of oligo- and polyrotaxanes is important for developing sequence-defined polymers and dynamic functional materials. This Review discusses the pivotal role of sequence isomerism in rotaxanes and explores different synthetic approaches for constructing sequence-controlled rotaxanes. By comparing the advantages and disadvantages of these approaches, possible synthetic strategies are proposed to predict the future of sequence-controlled synthesis of polyrotaxanes.

JOURNAL OF POLYMER SCIENCE (2023)

Review Chemistry, Multidisciplinary

Porous Organic Cages

Xinchun Yang, Zakir Ullah, J. Fraser Stoddart, Cafer T. Yavuz

Summary: Porous organic cages (POCs) are a new class of low-density crystalline materials that have wide applications in molecular recognition, gas storage and separation, and proton conduction. Compared to other porous structures like MOFs, COFs, and POPs, POCs have the advantages of specific surface areas, porosities, open pore channels, tunable structures, and solubilities in common solvents. This review summarizes recent progress in POCs, including their design, synthesis, characterization, and applications, and discusses future challenges and opportunities in the field.

CHEMICAL REVIEWS (2023)

Article Chemistry, Multidisciplinary

Coherent Vibronic Wavepackets Show Structure-Directed Charge Flow in Host-Guest Donor-Acceptor Complexes

Taeyeon Kim, Yuanning Feng, James P. O'Connor, J. Fraser Stoddart, Ryan M. Young, Michael R. Wasielewski

Summary: Designing and controlling charge transfer pathways in organic semiconductors are crucial for solar energy applications. This study investigates the photoinduced charge transfer and relaxation dynamics in host-guest complexes, and demonstrates that the charge transfer pathway can be controlled by subtle chemical modifications of the acceptor host.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

Article Chemistry, Multidisciplinary

Triplet-Triplet Annihilation Upconversion in a Porphyrinic Molecular Container

Hongliang Chen, Indranil Roy, Michele S. Myong, James S. W. Seale, Kang Cai, Yang Jiao, Wenqi Liu, Bo Song, Long Zhang, Xingang Zhao, Yuanning Feng, Fangjun Liu, Ryan M. Young, Michael R. Wasielewski, J. Fraser Stoddart

Summary: Triplet-triplet annihilation-based molecular photon upconversion (TTA-UC) was achieved by incorporating two porphyrinic sensitizers and encapsulating two perylene emitters inside a molecular container. The design of the container, with a suitable cavity size and ππ distance between the sensitizers and annihilators, allowed for efficient photon upconversion. This study provides new opportunities for addressing issues associated with supramolecular photon upconversion and has implications for biological imaging applications.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

Article Chemistry, Multidisciplinary

Soluble and Processable Single-Crystalline Cationic Polymers

Yang Liu, Xin-Ru Guan, Duan-Chao Wang, J. Fraser Stoddart, Qing-Hui Guo

Summary: Single-crystal-to-single-crystal (SCSC) polymerization is an effective method for environmentally friendly preparation of polymer single crystals (PSCs) with high crystallinity and molecular weights. Solubility and solution processibility are major challenges for practical applications of PSCs, but this study successfully synthesized soluble and processable PSCs with rigid polycationic backbones. The resulting polymeric crystals have excellent solubility, crystallinity and rheological properties, and can be characterized using various techniques.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

Editorial Material Multidisciplinary Sciences

Making chiral molecular knots and links stereospecifically

Huang Wu, Chun Tang, Long Zhang, J. Fraser Stoddart

NATIONAL SCIENCE REVIEW (2023)

Article Chemistry, Multidisciplinary

Robust Single-Supermolecule Switches Operating in Response to Two Different Noncovalent Interactions

Ping Zhou, Yanjun Fu, Maolin Wang, Renhui Qiu, Yuwei Wang, J. Fraser Stoddart, Yuping Wang, Hongliang Chen

Summary: Supramolecular electronics use noncovalent interactions like π-π and hydrogen bonding to introduce molecular assemblies into electronic devices. This research demonstrates a strategy for building electronically robust switches using two different noncovalent interactions. By compressing the junction, the single-supermolecule switch is turned ON through π-π interactions dominating the transport. Stretching the junction to form hydrogen-bonded dimers turns the switch OFF, resulting in a dramatic decrease in conductance. The study shows the potential for designing robust bistable mechanoresponsive devices for integrated circuits in microelectromechanical systems.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

Article Chemistry, Multidisciplinary

Photosalience and Thermal Phase Transitions of Azobenzene- and Crown Ether-Based Complexes in Polymorphic Crystals

Chi-Hsien Wang, Yi-Chia Lin, Surojit Bhunia, Yuanning Feng, Pramita Kundu, Charlotte L. Stern, Pei-Lin Chen, J. Fraser Stoddart, Masaki Horie

Summary: In this study, stimuli-responsive molecular crystals with distinct thermal phase transitions, photoinduced deformations, and mechanical behavior were reported. The understanding of the correlation between structure-thermomechanical and structure-photomechanical properties was advanced for the development of multi-stimulus-responsive materials.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

Article Chemistry, Multidisciplinary

Quantum Sensing of Electric Fields Using Spin-Correlated Radical Ion Pairs

Fangbai Xie, Haochuan Mao, Chenjian Lin, Yuanning Feng, J. Fraser Stoddart, Ryan M. Young, Michael R. Wasielewski

Summary: This study demonstrates that a photogenerated spin-correlated radical ion pair can be used to sense an electric field change through molecular recognition. The experiment shows that the distance between the two charges decreases when a certain molecule encapsulates one of the charges, indicating that the system can function as a quantum sensor to detect electric field changes.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

Review Chemistry, Multidisciplinary

Applications of macrocycle-based solid-state host-guest chemistry

Huangtianzhi Zhu, Liya Chen, Bin Sun, Mengbin Wang, Hao Li, J. Fraser Stoddart, Feihe Huang

Summary: Macrocyclic molecules have broad applications due to their guest binding properties. Extending host-guest chemistry from solution to the solid state enables the formation of more stable and processable complexes. Solid-state host-guest chemistry can encapsulate guests with higher affinities, which is crucial for applications in separation science and devices.

NATURE REVIEWS CHEMISTRY (2023)

Article Chemistry, Physical

Harnessing ion-dipole interactions: a simple and effective approach to high-performance lithium receptors

Chengkai Xu, Quy Tran, Lukasz Wojtas, Wenqi Liu

Summary: The growing demand for lithium, especially in lithium-ion batteries, necessitates the development of efficient extraction and purification methods. This study proposes a simple and effective approach to high-performance lithium receptors using ion-dipole interactions for lithium binding. The findings show significantly enhanced binding affinity and Li+/Na+ selectivity compared to conventional receptors, as well as the discovery of a new building block for augmented lithium-binding capacity.

JOURNAL OF MATERIALS CHEMISTRY A (2023)

Article Chemistry, Multidisciplinary

Color-Tunable Upconversion-Emission Switch Based on Cocrystal-to-Cocrystal Transformation

Yu Wang, Huang Wu, Leighton O. Jones, Martin A. Mosquera, Charlotte L. Stern, George C. Schatz, J. Fraser Stoddart

Summary: Cocrystal engineering is a popular strategy for tuning the photophysical properties of crystalline materials. This research presents a color-tunable upconversion-emission switch based on the interconversion between two cocrystals, demonstrating the reversible transformation and color change mechanism between cocrystals.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

暂无数据