期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 142, 期 12, 页码 5504-5508出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.0c00459
关键词
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资金
- Noguchi Institute
- [19H05461]
- [19K15581]
We synthesized a double-walled knotted cage from a flexible tripodal ligand. The characteristic double-walled structure provided a unique adaptive behavior of the cavity upon inclusion of organic molecules, which was evidenced by NMR and X-ray measurements. The semiflexible host framework, restricted by the knotted topology, enabled kinetic molecular recognition revealing the sequential binding of two different guests from their mixture.
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