期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 64, 页码 9909-9912出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc03725a
关键词
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资金
- National Basic Research Program of China (973 Program) [2012CB720300]
- International Science & Technology Cooperation Program of China [2014DFE40130]
Here, we demonstrate that merging photoredox catalysis with Lewis acid catalysis provides a fundamentally new activation mode of C-C triple bonds, to achieve the bond-forming reaction of alkynes with weak nucleophiles. Using a synergistic merger of Eosin Y and Cu(OTf)(2), a highly efficient cyclization reaction of arene-ynes was developed.
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